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GB1216271A - Process for the production of unsaturated alcohols from olefins and formaldehyde - Google Patents

Process for the production of unsaturated alcohols from olefins and formaldehyde

Info

Publication number
GB1216271A
GB1216271A GB8840/68A GB884068A GB1216271A GB 1216271 A GB1216271 A GB 1216271A GB 8840/68 A GB8840/68 A GB 8840/68A GB 884068 A GB884068 A GB 884068A GB 1216271 A GB1216271 A GB 1216271A
Authority
GB
United Kingdom
Prior art keywords
formaldehyde
alcohols
unsaturated
feb
olefins
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB8840/68A
Inventor
Gordon Foster
George Henry Revett Aston
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BP PLC
Original Assignee
BP PLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BP PLC filed Critical BP PLC
Priority to GB8840/68A priority Critical patent/GB1216271A/en
Priority to NL6902628A priority patent/NL6902628A/xx
Priority to BE728780D priority patent/BE728780A/xx
Priority to FR6904554A priority patent/FR2002526A1/fr
Priority to DE19691909047 priority patent/DE1909047A1/en
Publication of GB1216271A publication Critical patent/GB1216271A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/36—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring increasing the number of carbon atoms by reactions with formation of hydroxy groups, which may occur via intermediates being derivatives of hydroxy, e.g. O-metal
    • C07C29/38—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring increasing the number of carbon atoms by reactions with formation of hydroxy groups, which may occur via intermediates being derivatives of hydroxy, e.g. O-metal by reaction with aldehydes or ketones
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00—Aliphatic unsaturated hydrocarbons
    • C07C11/12—Alkadienes
    • C07C11/173—Alkadienes with five carbon atoms
    • C07C11/18—Isoprene

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

1,216,271. Unsaturated alcohols. BRITISH PETROLEUM CO. Ltd. 11 Feb., 1969 [23 Feb., 1968], No. 8840/68. Heading C2C. [Also in Division C5] Unsaturated primary alcohols are prepared by reacting an olefin showing chain branching at the double bond with gaseous formaldehyde in the presence of some, but less than 0-1 moles per mole of formaldehyde of a boron halide at 0-150‹ C. An inert solvent, e.g. a chlorinated hydrocarbon, may be used and the formaldehyde preferably contains less than 30% water. Examples prepare unsaturated C 9 alcohols from α-di-isobutylene. 2-Methylpentene-1 and -2, and 2-ethylhexene-1 are also specified as starting materials.
GB8840/68A 1968-02-23 1968-02-23 Process for the production of unsaturated alcohols from olefins and formaldehyde Expired GB1216271A (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
GB8840/68A GB1216271A (en) 1968-02-23 1968-02-23 Process for the production of unsaturated alcohols from olefins and formaldehyde
NL6902628A NL6902628A (en) 1968-02-23 1969-02-19
BE728780D BE728780A (en) 1968-02-23 1969-02-21
FR6904554A FR2002526A1 (en) 1968-02-23 1969-02-21
DE19691909047 DE1909047A1 (en) 1968-02-23 1969-02-22 Process for the production of unsaturated primary alcohols

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB8840/68A GB1216271A (en) 1968-02-23 1968-02-23 Process for the production of unsaturated alcohols from olefins and formaldehyde

Publications (1)

Publication Number Publication Date
GB1216271A true GB1216271A (en) 1970-12-16

Family

ID=9860240

Family Applications (1)

Application Number Title Priority Date Filing Date
GB8840/68A Expired GB1216271A (en) 1968-02-23 1968-02-23 Process for the production of unsaturated alcohols from olefins and formaldehyde

Country Status (5)

Country Link
BE (1) BE728780A (en)
DE (1) DE1909047A1 (en)
FR (1) FR2002526A1 (en)
GB (1) GB1216271A (en)
NL (1) NL6902628A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4261901A (en) 1979-09-10 1981-04-14 E. I. Du Pont De Nemours And Company Synthesis of tetrahydrofuran
US4288374A (en) 1979-09-10 1981-09-08 E. I. Du Pont De Nemours And Company Synthesis of 3-buten-1-ol, 3,4-dichlorobutan-1-ol and 3-chlorotetrahydrofuran

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4261901A (en) 1979-09-10 1981-04-14 E. I. Du Pont De Nemours And Company Synthesis of tetrahydrofuran
US4288374A (en) 1979-09-10 1981-09-08 E. I. Du Pont De Nemours And Company Synthesis of 3-buten-1-ol, 3,4-dichlorobutan-1-ol and 3-chlorotetrahydrofuran

Also Published As

Publication number Publication date
DE1909047A1 (en) 1969-09-04
FR2002526A1 (en) 1969-10-17
BE728780A (en) 1969-08-21
NL6902628A (en) 1969-08-26

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