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GB1211973A - Polymerization with zeolitic catalysts - Google Patents

Polymerization with zeolitic catalysts

Info

Publication number
GB1211973A
GB1211973A GB00061/69A GB1006169A GB1211973A GB 1211973 A GB1211973 A GB 1211973A GB 00061/69 A GB00061/69 A GB 00061/69A GB 1006169 A GB1006169 A GB 1006169A GB 1211973 A GB1211973 A GB 1211973A
Authority
GB
United Kingdom
Prior art keywords
pentene
polymerization
butene
zeolite
propylenetetramer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB00061/69A
Inventor
William Harry Lang
Werner Otto Haag
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mobil Oil AS
Original Assignee
Mobil Oil AS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mobil Oil AS filed Critical Mobil Oil AS
Publication of GB1211973A publication Critical patent/GB1211973A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C08G65/2642—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
    • C08G65/2645—Metals or compounds thereof, e.g. salts
    • C08G65/2654—Aluminium or boron; Compounds thereof
    • C08G65/2657—Aluminosilicates; Clays; Zeolites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7011—MAZ-type, e.g. Mazzite, Omega, ZSM-4 or LZ-202
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/12—Catalytic processes with crystalline alumino-silicates or with catalysts comprising molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/42—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons homo- or co-oligomerisation with ring formation, not being a Diels-Alder conversion
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/68—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the catalysts used
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2602/00—Systems containing two condensed rings
    • C07C2602/02—Systems containing two condensed rings the rings having only two atoms in common
    • C07C2602/04—One of the condensed rings being a six-membered aromatic ring
    • C07C2602/08—One of the condensed rings being a six-membered aromatic ring the other ring being five-membered, e.g. indane

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Polymerization Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Catalysts (AREA)

Abstract

1,211,973. Oligomerizing unsaturated hydrocarbons. MOBIL OIL CORP. 25 Feb., 1969 [18 April, 1968], No. 10061/69. Addition to 1,117,568. Heading C5E. [Also in Division C3] A hydrocarbon containing a carbon-tocarbon multiple bond is polymerized with a catalyst comprising a crystalline synthetic aluminosilicate zeolite having the X-ray powder diffraction pattern given in the parent Specification 1,117,568. The zeolite known as Z5M-4 has the composition M 2 O/n: Al 2 O 3 :6- 15 SiO 2 : 0-5 H 2 O wherein M is a cation other than an alkali metal, e.g. one or more of H, NH 4 , rare earth metal, Zn and Mg, and n is the valence of M. The polymerization may be effected at -150‹ to +660‹ F. and 0À25-1000 atmospheres. Examples describe the oligomerization of 1-butene, a mixed butane-butene stream, 1-decene, propylenetetramer, 2,4,4, trimethyl - 1 - pentene and α - methyl styrene. Other monomers mentioned are isobutene, propene, a pentene, conjugated diolefins, allenes, triolefins, cyclopentene, methylcyclohexene, cyclooctadiene, vinylcyclohexene and acetylenes.
GB00061/69A 1968-04-18 1969-02-25 Polymerization with zeolitic catalysts Expired GB1211973A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US72215568A 1968-04-18 1968-04-18

Publications (1)

Publication Number Publication Date
GB1211973A true GB1211973A (en) 1970-11-11

Family

ID=24900725

Family Applications (1)

Application Number Title Priority Date Filing Date
GB00061/69A Expired GB1211973A (en) 1968-04-18 1969-02-25 Polymerization with zeolitic catalysts

Country Status (6)

Country Link
JP (1) JPS5129121B1 (en)
CH (1) CH515282A (en)
DE (1) DE1915117A1 (en)
FR (1) FR2006457A1 (en)
GB (1) GB1211973A (en)
NL (1) NL6906091A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0030431A1 (en) * 1979-12-05 1981-06-17 Mobil Oil Corporation Oligomerization of olefins
US4424401A (en) 1980-08-12 1984-01-03 The Broken Hill Proprietary Company Limited Aromatization of acetylene
RU2349567C1 (en) * 2007-08-29 2009-03-20 Институт нефтехимии и катализа РАН Method of producing linear styrene dimers
RU2349568C1 (en) * 2007-09-03 2009-03-20 Институт нефтехимии и катализа РАН Method of producing linear styrene dimers
RU2350591C1 (en) * 2007-08-29 2009-03-27 Институт нефтехимии и катализа РАН Method of linear sterol dimer

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5541346A (en) * 1992-10-21 1996-07-30 E. I. Du Pont De Nemours And Company Polymerization of, and depolymerization to, cyclic ethers using selected metal compound catalysts
ES2139088T3 (en) * 1993-07-16 2000-02-01 Du Pont POLYMERIZATION OF CYCLE ETERES USING HETEROGENEOUS CATALYSTS.

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0030431A1 (en) * 1979-12-05 1981-06-17 Mobil Oil Corporation Oligomerization of olefins
US4424401A (en) 1980-08-12 1984-01-03 The Broken Hill Proprietary Company Limited Aromatization of acetylene
RU2349567C1 (en) * 2007-08-29 2009-03-20 Институт нефтехимии и катализа РАН Method of producing linear styrene dimers
RU2350591C1 (en) * 2007-08-29 2009-03-27 Институт нефтехимии и катализа РАН Method of linear sterol dimer
RU2349568C1 (en) * 2007-09-03 2009-03-20 Институт нефтехимии и катализа РАН Method of producing linear styrene dimers

Also Published As

Publication number Publication date
DE1915117A1 (en) 1969-10-23
FR2006457A1 (en) 1969-12-26
JPS5129121B1 (en) 1976-08-24
NL6906091A (en) 1969-10-21
CH515282A (en) 1971-11-15

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Legal Events

Date Code Title Description
PS Patent sealed
PE Patent expired