GB1208144A - Process for the hydration of olefins to produce alcohols and ethers - Google Patents
Process for the hydration of olefins to produce alcohols and ethersInfo
- Publication number
- GB1208144A GB1208144A GB2471968A GB2471968A GB1208144A GB 1208144 A GB1208144 A GB 1208144A GB 2471968 A GB2471968 A GB 2471968A GB 2471968 A GB2471968 A GB 2471968A GB 1208144 A GB1208144 A GB 1208144A
- Authority
- GB
- United Kingdom
- Prior art keywords
- olefins
- hydration
- sulphonic acid
- ethers
- divinyl benzene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 150000001336 alkenes Chemical class 0.000 title abstract 3
- 230000036571 hydration Effects 0.000 title abstract 3
- 238000006703 hydration reaction Methods 0.000 title abstract 3
- 150000001298 alcohols Chemical class 0.000 title abstract 2
- 150000002170 ethers Chemical class 0.000 title abstract 2
- 238000000034 method Methods 0.000 title 1
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 abstract 4
- ZGHFDIIVVIFNPS-UHFFFAOYSA-N 3-Methyl-3-buten-2-one Chemical compound CC(=C)C(C)=O ZGHFDIIVVIFNPS-UHFFFAOYSA-N 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- BDHFUVZGWQCTTF-UHFFFAOYSA-N sulfonic acid Chemical compound OS(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-N 0.000 abstract 2
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 abstract 1
- 239000003729 cation exchange resin Substances 0.000 abstract 1
- 239000007795 chemical reaction product Substances 0.000 abstract 1
- 229920001577 copolymer Polymers 0.000 abstract 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 abstract 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 abstract 1
- NLVXSWCKKBEXTG-UHFFFAOYSA-N vinylsulfonic acid Chemical compound OS(=O)(=O)C=C NLVXSWCKKBEXTG-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/06—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing polymers
- B01J31/08—Ion-exchange resins
- B01J31/10—Ion-exchange resins sulfonated
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/03—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by addition of hydroxy groups to unsaturated carbon-to-carbon bonds, e.g. with the aid of H2O2
- C07C29/04—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by addition of hydroxy groups to unsaturated carbon-to-carbon bonds, e.g. with the aid of H2O2 by hydration of carbon-to-carbon double bonds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
- B01J2231/32—Addition reactions to C=C or C-C triple bonds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
1,208,144. Hydration of olefins. RHEINPREUSSEN A.G. 23 May, 1968 [14 June, 1967], No. 24719/68. Heading C2C. [Also in Division C3] Alcohols and ethers are produced by direct hydration of olefins in the presence of a sulphonic acid cation exchange resin, in which the sulphonic acid groups are bound to non- aromatic carbon atoms, as a catalyst. In the example propylene is hydrated in the presence of (a) a copolymer of methyl isopropenyl ketone with 8% divinyl benzene, treated with H 2 S and oxidized with H 2 O 2 or (b) a reaction product of 4 mols vinyl sulphonic acid and 1 mol divinyl benzene, as catalysts under various conditions of temperature and pressure.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DER46245A DE1291729B (en) | 1967-06-14 | 1967-06-14 | Process for the hydration of lower olefins to alcohols and ethers |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1208144A true GB1208144A (en) | 1970-10-07 |
Family
ID=7407943
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB2471968A Expired GB1208144A (en) | 1967-06-14 | 1968-05-23 | Process for the hydration of olefins to produce alcohols and ethers |
Country Status (7)
| Country | Link |
|---|---|
| AT (1) | AT284804B (en) |
| BE (1) | BE716619A (en) |
| CH (1) | CH500147A (en) |
| DE (1) | DE1291729B (en) |
| FR (1) | FR1570877A (en) |
| GB (1) | GB1208144A (en) |
| NL (1) | NL6807638A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4281206A (en) * | 1974-01-30 | 1981-07-28 | Deutsche Texaco Aktiengesellschaft | Method of conducting reactions in a trickle-type reactor |
| US4469905A (en) * | 1981-11-04 | 1984-09-04 | Union Oil Company Of California | Process for producing and extracting C2 to C6 alcohols |
| EP0728721A3 (en) * | 1995-02-24 | 1997-01-22 | Mitsui Toatsu Chemicals | Process for the production of isopropyl alcohol |
| EP1477468A4 (en) * | 2002-01-24 | 2006-04-05 | Japan Science & Tech Agency | PROCESS FOR PRODUCING 1,2-DIOL |
| CN115569615A (en) * | 2022-10-31 | 2023-01-06 | 厦门大学 | A reaction device for preparing terpineol from limonene and its synthesis method |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2040501C3 (en) * | 1970-08-14 | 1984-01-05 | Basf Ag, 6700 Ludwigshafen | Process for carrying out exothermic reactions between a gas and a liquid |
| DE3628007C1 (en) * | 1986-08-19 | 1987-11-05 | Deutsche Texaco Ag, 2000 Hamburg, De |
-
1967
- 1967-06-14 DE DER46245A patent/DE1291729B/en active Pending
-
1968
- 1968-04-29 CH CH635768A patent/CH500147A/en not_active IP Right Cessation
- 1968-05-02 AT AT422468A patent/AT284804B/en not_active IP Right Cessation
- 1968-05-23 GB GB2471968A patent/GB1208144A/en not_active Expired
- 1968-05-30 NL NL6807638A patent/NL6807638A/xx unknown
- 1968-06-14 FR FR1570877D patent/FR1570877A/fr not_active Expired
- 1968-06-14 BE BE716619D patent/BE716619A/xx unknown
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4281206A (en) * | 1974-01-30 | 1981-07-28 | Deutsche Texaco Aktiengesellschaft | Method of conducting reactions in a trickle-type reactor |
| US4469905A (en) * | 1981-11-04 | 1984-09-04 | Union Oil Company Of California | Process for producing and extracting C2 to C6 alcohols |
| EP0728721A3 (en) * | 1995-02-24 | 1997-01-22 | Mitsui Toatsu Chemicals | Process for the production of isopropyl alcohol |
| US5763693A (en) * | 1995-02-24 | 1998-06-09 | Mitsui Chemicals, Inc. | Process for producing isopropyl alcohol |
| CN1063421C (en) * | 1995-02-24 | 2001-03-21 | 三井化学株式会社 | Process for producing isopropyl alcohol |
| EP1477468A4 (en) * | 2002-01-24 | 2006-04-05 | Japan Science & Tech Agency | PROCESS FOR PRODUCING 1,2-DIOL |
| US7385096B2 (en) | 2002-01-24 | 2008-06-10 | Japan Science And Technology Agency | Process for producing 1,2-diol |
| CN115569615A (en) * | 2022-10-31 | 2023-01-06 | 厦门大学 | A reaction device for preparing terpineol from limonene and its synthesis method |
Also Published As
| Publication number | Publication date |
|---|---|
| AT284804B (en) | 1970-09-25 |
| FR1570877A (en) | 1969-06-13 |
| DE1291729B (en) | 1969-04-03 |
| CH500147A (en) | 1970-12-15 |
| BE716619A (en) | 1968-12-16 |
| NL6807638A (en) | 1968-12-16 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed | ||
| PLNP | Patent lapsed through nonpayment of renewal fees |