GB1299078A - Distillation process - Google Patents
Distillation processInfo
- Publication number
- GB1299078A GB1299078A GB2208469A GB2208469A GB1299078A GB 1299078 A GB1299078 A GB 1299078A GB 2208469 A GB2208469 A GB 2208469A GB 2208469 A GB2208469 A GB 2208469A GB 1299078 A GB1299078 A GB 1299078A
- Authority
- GB
- United Kingdom
- Prior art keywords
- reaction mixture
- temperature
- reaction
- water
- acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2/00—Processes or devices for granulating materials, e.g. fertilisers in general; Rendering particulate materials free flowing in general, e.g. making them hydrophobic
- B01J2/02—Processes or devices for granulating materials, e.g. fertilisers in general; Rendering particulate materials free flowing in general, e.g. making them hydrophobic by dividing the liquid material into drops, e.g. by spraying, and solidifying the drops
- B01J2/04—Processes or devices for granulating materials, e.g. fertilisers in general; Rendering particulate materials free flowing in general, e.g. making them hydrophobic by dividing the liquid material into drops, e.g. by spraying, and solidifying the drops in a gaseous medium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D1/00—Evaporating
- B01D1/16—Evaporating by spraying
- B01D1/18—Evaporating by spraying to obtain dry solids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/08—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides with the hydroxy or O-metal group of organic compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Vaporization, Distillation, Condensation, Sublimation, And Cold Traps (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
1299078 Esters IMPERIAL CHEMICAL INDUSTRIES Ltd 13 April 1970 [30 April 1969] 22084/69 Heading C2C Esters of orthophthalic acid are produced by heating the acid, or phthalic anhydride, with a C 4 to C 14 alkanol, removing water-vapour from the reaction mixture and, at least during the later stages of the reaction, withdrawing part of the reaction mixture and introducing it in the form of a spray of small droplets to the vapour space above the reaction mixture. The hourly circulation rate is preferably 4 to 10 times the volume of the reaction mixture. The liquid which is withdrawn may be heated to a temperature 50‹ C. higher than the temperature of the bulk of the reaction mixture. An example relates to the production of dioctyl phthalate by heating phthalic anhydride with excess iso-octanol and a catalytic amount of sulphuric acid in a lead-lined distillation pot enclosed by a steam jacket. Towards the end of the esterification, when the temperature is 145‹ C. and nearly all the reaction-water has been distilled off by azeotropic distillation with refluxing iso-octanol, the circulation pump is started and batch distillation is carried out to remove the last traces of water.
Priority Applications (6)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US830555*A US3519054A (en) | 1969-01-06 | 1969-01-06 | Process for producing a particulate product |
| GB2208469A GB1299078A (en) | 1969-04-30 | 1969-04-30 | Distillation process |
| US29654A US3681434A (en) | 1969-01-06 | 1970-04-17 | Batch distillation of phthalate esters with recycle and spraying |
| DE19702020551 DE2020551B2 (en) | 1969-04-30 | 1970-04-27 | Method and device for batch distillation of a liquid |
| FR7015731A FR2040465A1 (en) | 1969-04-30 | 1970-04-29 | |
| NL7006280A NL7006280A (en) | 1969-04-30 | 1970-04-29 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB2208469A GB1299078A (en) | 1969-04-30 | 1969-04-30 | Distillation process |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1299078A true GB1299078A (en) | 1972-12-06 |
Family
ID=10173668
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB2208469A Expired GB1299078A (en) | 1969-01-06 | 1969-04-30 | Distillation process |
Country Status (4)
| Country | Link |
|---|---|
| DE (1) | DE2020551B2 (en) |
| FR (1) | FR2040465A1 (en) |
| GB (1) | GB1299078A (en) |
| NL (1) | NL7006280A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5324853A (en) * | 1993-01-19 | 1994-06-28 | Exxon Chemical Patents Inc. | Process for the production of plasticizer and polyolesters |
-
1969
- 1969-04-30 GB GB2208469A patent/GB1299078A/en not_active Expired
-
1970
- 1970-04-27 DE DE19702020551 patent/DE2020551B2/en not_active Withdrawn
- 1970-04-29 NL NL7006280A patent/NL7006280A/xx unknown
- 1970-04-29 FR FR7015731A patent/FR2040465A1/fr not_active Withdrawn
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5324853A (en) * | 1993-01-19 | 1994-06-28 | Exxon Chemical Patents Inc. | Process for the production of plasticizer and polyolesters |
Also Published As
| Publication number | Publication date |
|---|---|
| DE2020551A1 (en) | 1970-11-05 |
| DE2020551B2 (en) | 1975-03-06 |
| FR2040465A1 (en) | 1971-01-22 |
| NL7006280A (en) | 1970-11-03 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed | ||
| PLNP | Patent lapsed through nonpayment of renewal fees |