GB1281265A - A catalytic composition for the conversion of petroleum hydrocarbons - Google Patents
A catalytic composition for the conversion of petroleum hydrocarbonsInfo
- Publication number
- GB1281265A GB1281265A GB1661270A GB1661270A GB1281265A GB 1281265 A GB1281265 A GB 1281265A GB 1661270 A GB1661270 A GB 1661270A GB 1661270 A GB1661270 A GB 1661270A GB 1281265 A GB1281265 A GB 1281265A
- Authority
- GB
- United Kingdom
- Prior art keywords
- pore
- aluminosilicate
- catalyst
- april
- catalytic composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000203 mixture Substances 0.000 title abstract 3
- 230000003197 catalytic effect Effects 0.000 title abstract 2
- 238000006243 chemical reaction Methods 0.000 title 1
- 229930195733 hydrocarbon Natural products 0.000 title 1
- 150000002430 hydrocarbons Chemical class 0.000 title 1
- 239000003208 petroleum Substances 0.000 title 1
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract 5
- 239000011148 porous material Substances 0.000 abstract 5
- 229910000323 aluminium silicate Inorganic materials 0.000 abstract 4
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 abstract 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 abstract 3
- 239000003054 catalyst Substances 0.000 abstract 3
- 229910052759 nickel Inorganic materials 0.000 abstract 2
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 abstract 2
- 229910052721 tungsten Inorganic materials 0.000 abstract 2
- 239000010937 tungsten Substances 0.000 abstract 2
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 abstract 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- 229910052783 alkali metal Inorganic materials 0.000 abstract 1
- 150000001340 alkali metals Chemical class 0.000 abstract 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 1
- 238000005336 cracking Methods 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 1
- 229910052809 inorganic oxide Inorganic materials 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 239000011159 matrix material Substances 0.000 abstract 1
- 150000003568 thioethers Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
- C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
- C10G47/10—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used with catalysts deposited on a carrier
- C10G47/12—Inorganic carriers
- C10G47/16—Crystalline alumino-silicate carriers
- C10G47/20—Crystalline alumino-silicate carriers the catalyst containing other metals or compounds thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
- B01J29/16—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J29/166—Y-type faujasite
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
- C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
- C10G45/12—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Crystallography & Structural Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Catalysts (AREA)
Abstract
1281265 Cracking catalyst STANDARD OIL CO 8 April 1970 [8 April 1969] 16612/70 Heading B1E [Also in Division C5] A catalytic composition comprises (i) elemental nickel and elemental tungsten, their oxides, their sulphides or mixtures thereof, and (ii) a support comprising a large-pore crystalline aluminosilicate material and a refractory inorganic oxide. By large-pore it is meant that the pores are of a sufficient size to permit the passage thereinto of benzene molecules, e.g. 9 to 10Š or above. Suitably, the large-pore aluminosilicate is an ultrastable, large-pore crystalline aluminosilicate of max. cubic unit cell dimension of 24-55Š, hydroxyl IR bands near 3700 cm<SP>-1</SP> and near 3625cm<SP>-1</SP> and an alkali metal content of less than 1 per cent. The specified refractory oxide is silica-alumina, preferably in the form of a matrix for the aluminosilicate. The quantity of nickel and tungsten present are 0.03 to 0.20 gm-mole of NiO and WO 3 per 100 gms of catalyst with a W/Ni ratio of 0.6 to 12.0. The catalyst may be pretreated before use with a stream of hydrogen optionally containing a little hydrogen sulphide.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US81435669A | 1969-04-08 | 1969-04-08 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1281265A true GB1281265A (en) | 1972-07-12 |
Family
ID=25214819
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB1661270A Expired GB1281265A (en) | 1969-04-08 | 1970-04-08 | A catalytic composition for the conversion of petroleum hydrocarbons |
Country Status (6)
| Country | Link |
|---|---|
| BE (1) | BE748685A (en) |
| CA (1) | CA970346A (en) |
| DE (1) | DE2016774A1 (en) |
| FR (1) | FR2043108A5 (en) |
| GB (1) | GB1281265A (en) |
| NL (1) | NL7005010A (en) |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0038140A1 (en) * | 1980-04-14 | 1981-10-21 | Mobil Oil Corporation | Catalytic hydrocracking |
| EP0044631A1 (en) * | 1980-07-18 | 1982-01-27 | Mobil Oil Corporation | Hydrocarbon cracking process |
| WO2011091203A3 (en) * | 2010-01-21 | 2012-08-09 | Shell Oil Company | Hydrocarbon composition |
| US8562818B2 (en) | 2010-01-21 | 2013-10-22 | Shell Oil Company | Hydrocarbon composition |
| US8597499B2 (en) | 2010-01-21 | 2013-12-03 | Shell Oil Company | Process for treating a hydrocarbon-containing feed |
| US8597498B2 (en) | 2010-01-21 | 2013-12-03 | Shell Oil Company | Process for treating a hydrocarbon-containing feed |
| US8679319B2 (en) | 2010-01-21 | 2014-03-25 | Shell Oil Company | Hydrocarbon composition |
| CN104588081A (en) * | 2013-11-03 | 2015-05-06 | 中国石油化工股份有限公司 | Preparation method of hydrocracking catalyst containing rare earth |
| RU2600448C1 (en) * | 2015-10-20 | 2016-10-20 | Федеральное государственное бюджетное учреждение науки Институт химии нефти Сибирского отделения Российской академии наук (ИХН СО РАН) | Method of processing natural bitumen |
| CN104588119B (en) * | 2013-11-03 | 2017-01-25 | 中国石油化工股份有限公司 | Preparation method for hydrocracking catalyst containing heteropoly acid |
-
1970
- 1970-04-07 CA CA079,433A patent/CA970346A/en not_active Expired
- 1970-04-08 DE DE19702016774 patent/DE2016774A1/en active Pending
- 1970-04-08 NL NL7005010A patent/NL7005010A/xx unknown
- 1970-04-08 GB GB1661270A patent/GB1281265A/en not_active Expired
- 1970-04-08 BE BE748685D patent/BE748685A/en not_active IP Right Cessation
- 1970-04-08 FR FR7012762A patent/FR2043108A5/fr not_active Expired
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0038140A1 (en) * | 1980-04-14 | 1981-10-21 | Mobil Oil Corporation | Catalytic hydrocracking |
| EP0044631A1 (en) * | 1980-07-18 | 1982-01-27 | Mobil Oil Corporation | Hydrocarbon cracking process |
| WO2011091203A3 (en) * | 2010-01-21 | 2012-08-09 | Shell Oil Company | Hydrocarbon composition |
| US8562818B2 (en) | 2010-01-21 | 2013-10-22 | Shell Oil Company | Hydrocarbon composition |
| US8597499B2 (en) | 2010-01-21 | 2013-12-03 | Shell Oil Company | Process for treating a hydrocarbon-containing feed |
| US8597498B2 (en) | 2010-01-21 | 2013-12-03 | Shell Oil Company | Process for treating a hydrocarbon-containing feed |
| US8679319B2 (en) | 2010-01-21 | 2014-03-25 | Shell Oil Company | Hydrocarbon composition |
| CN104588081A (en) * | 2013-11-03 | 2015-05-06 | 中国石油化工股份有限公司 | Preparation method of hydrocracking catalyst containing rare earth |
| CN104588081B (en) * | 2013-11-03 | 2016-11-23 | 中国石油化工股份有限公司 | The preparation method of the hydrocracking catalyst containing rare earth |
| CN104588119B (en) * | 2013-11-03 | 2017-01-25 | 中国石油化工股份有限公司 | Preparation method for hydrocracking catalyst containing heteropoly acid |
| RU2600448C1 (en) * | 2015-10-20 | 2016-10-20 | Федеральное государственное бюджетное учреждение науки Институт химии нефти Сибирского отделения Российской академии наук (ИХН СО РАН) | Method of processing natural bitumen |
Also Published As
| Publication number | Publication date |
|---|---|
| BE748685A (en) | 1970-09-06 |
| CA970346A (en) | 1975-07-01 |
| FR2043108A5 (en) | 1971-02-12 |
| DE2016774A1 (en) | 1970-10-15 |
| NL7005010A (en) | 1970-10-12 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 414F | Notice of opposition given (sect. 14/1949) | ||
| 414A | Case decided by the comptroller ** specification amended (sect. 14/1949) | ||
| PS | Patent sealed | ||
| PCNP | Patent ceased through non-payment of renewal fee |