GB1269680A - Improvements in washing compositions - Google Patents
Improvements in washing compositionsInfo
- Publication number
- GB1269680A GB1269680A GB6241869A GB6241869A GB1269680A GB 1269680 A GB1269680 A GB 1269680A GB 6241869 A GB6241869 A GB 6241869A GB 6241869 A GB6241869 A GB 6241869A GB 1269680 A GB1269680 A GB 1269680A
- Authority
- GB
- United Kingdom
- Prior art keywords
- alkali metal
- sodium
- biguanide
- acids
- compositions
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000203 mixture Substances 0.000 title abstract 6
- 238000005406 washing Methods 0.000 title abstract 3
- -1 C1-C4 alkyl biguanide Chemical compound 0.000 abstract 8
- 229910052783 alkali metal Inorganic materials 0.000 abstract 6
- 229940123208 Biguanide Drugs 0.000 abstract 5
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 abstract 4
- 239000003599 detergent Substances 0.000 abstract 4
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 abstract 3
- 150000001875 compounds Chemical class 0.000 abstract 3
- 230000003287 optical effect Effects 0.000 abstract 3
- 150000003839 salts Chemical class 0.000 abstract 3
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 abstract 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 abstract 2
- 239000002253 acid Substances 0.000 abstract 2
- 150000007513 acids Chemical class 0.000 abstract 2
- 150000001340 alkali metals Chemical class 0.000 abstract 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 abstract 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 abstract 2
- 239000007788 liquid Substances 0.000 abstract 2
- 229910052938 sodium sulfate Inorganic materials 0.000 abstract 2
- 235000011152 sodium sulphate Nutrition 0.000 abstract 2
- 239000002904 solvent Substances 0.000 abstract 2
- 239000004753 textile Substances 0.000 abstract 2
- 102000013142 Amylases Human genes 0.000 abstract 1
- 108010065511 Amylases Proteins 0.000 abstract 1
- XNCOSPRUTUOJCJ-UHFFFAOYSA-N Biguanide Chemical group NC(N)=NC(N)=N XNCOSPRUTUOJCJ-UHFFFAOYSA-N 0.000 abstract 1
- 229920003043 Cellulose fiber Polymers 0.000 abstract 1
- 102000004190 Enzymes Human genes 0.000 abstract 1
- 108090000790 Enzymes Proteins 0.000 abstract 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract 1
- 102000004882 Lipase Human genes 0.000 abstract 1
- 108090001060 Lipase Proteins 0.000 abstract 1
- 239000004367 Lipase Substances 0.000 abstract 1
- 102000035195 Peptidases Human genes 0.000 abstract 1
- 108091005804 Peptidases Proteins 0.000 abstract 1
- 239000004952 Polyamide Substances 0.000 abstract 1
- 229920000388 Polyphosphate Polymers 0.000 abstract 1
- 239000004365 Protease Substances 0.000 abstract 1
- 239000004115 Sodium Silicate Substances 0.000 abstract 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 abstract 1
- 239000012190 activator Substances 0.000 abstract 1
- 125000004442 acylamino group Chemical group 0.000 abstract 1
- 125000003545 alkoxy group Chemical group 0.000 abstract 1
- 125000003282 alkyl amino group Chemical group 0.000 abstract 1
- 235000019418 amylase Nutrition 0.000 abstract 1
- 229940025131 amylases Drugs 0.000 abstract 1
- 125000000129 anionic group Chemical group 0.000 abstract 1
- 230000000844 anti-bacterial effect Effects 0.000 abstract 1
- 239000002518 antifoaming agent Substances 0.000 abstract 1
- 239000003899 bactericide agent Substances 0.000 abstract 1
- 235000010290 biphenyl Nutrition 0.000 abstract 1
- 239000004305 biphenyl Substances 0.000 abstract 1
- 125000006267 biphenyl group Chemical group 0.000 abstract 1
- 239000007844 bleaching agent Substances 0.000 abstract 1
- 150000001642 boronic acid derivatives Chemical class 0.000 abstract 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 abstract 1
- 239000001913 cellulose Substances 0.000 abstract 1
- 229920002678 cellulose Polymers 0.000 abstract 1
- 239000000975 dye Substances 0.000 abstract 1
- 229940088598 enzyme Drugs 0.000 abstract 1
- 239000000945 filler Substances 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 150000002367 halogens Chemical class 0.000 abstract 1
- 150000004679 hydroxides Chemical class 0.000 abstract 1
- 125000002768 hydroxyalkyl group Chemical group 0.000 abstract 1
- 239000004615 ingredient Substances 0.000 abstract 1
- 239000004310 lactic acid Substances 0.000 abstract 1
- 235000014655 lactic acid Nutrition 0.000 abstract 1
- 235000019421 lipase Nutrition 0.000 abstract 1
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 abstract 1
- 239000000391 magnesium silicate Substances 0.000 abstract 1
- 229910052919 magnesium silicate Inorganic materials 0.000 abstract 1
- 235000019792 magnesium silicate Nutrition 0.000 abstract 1
- 239000000155 melt Substances 0.000 abstract 1
- 125000001624 naphthyl group Chemical group 0.000 abstract 1
- 150000004967 organic peroxy acids Chemical class 0.000 abstract 1
- 239000006072 paste Substances 0.000 abstract 1
- 239000002304 perfume Substances 0.000 abstract 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 1
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 abstract 1
- 229920002647 polyamide Polymers 0.000 abstract 1
- 239000001205 polyphosphate Substances 0.000 abstract 1
- 235000011176 polyphosphates Nutrition 0.000 abstract 1
- 239000000843 powder Substances 0.000 abstract 1
- 235000003441 saturated fatty acids Nutrition 0.000 abstract 1
- 150000004671 saturated fatty acids Chemical class 0.000 abstract 1
- 229910052708 sodium Inorganic materials 0.000 abstract 1
- 239000011734 sodium Substances 0.000 abstract 1
- 239000011780 sodium chloride Substances 0.000 abstract 1
- 235000002639 sodium chloride Nutrition 0.000 abstract 1
- 229960001922 sodium perborate Drugs 0.000 abstract 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 abstract 1
- 229910052911 sodium silicate Inorganic materials 0.000 abstract 1
- 235000019794 sodium silicate Nutrition 0.000 abstract 1
- YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 abstract 1
- 239000007787 solid Substances 0.000 abstract 1
- 238000001694 spray drying Methods 0.000 abstract 1
- 239000003381 stabilizer Substances 0.000 abstract 1
- FDDDEECHVMSUSB-UHFFFAOYSA-N sulfanilamide Chemical compound NC1=CC=C(S(N)(=O)=O)C=C1 FDDDEECHVMSUSB-UHFFFAOYSA-N 0.000 abstract 1
- 229940124530 sulfonamide Drugs 0.000 abstract 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-N sulfonic acid Chemical compound OS(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-N 0.000 abstract 1
- 229920001059 synthetic polymer Polymers 0.000 abstract 1
- 238000005979 thermal decomposition reaction Methods 0.000 abstract 1
- 239000001226 triphosphate Substances 0.000 abstract 1
- 235000011178 triphosphate Nutrition 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/40—Dyes ; Pigments
- C11D3/42—Brightening agents ; Blueing agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3902—Organic or inorganic per-compounds combined with specific additives
- C11D3/3937—Stabilising agents
- C11D3/394—Organic compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
1,269,680. Detergents for washing textiles. HENKEL & CIE G.m.b.H. 22 Dec., 1969 [21 Dec., 1968], No. 62418/69. Heading C5D. A composition for washing textile fibres especially polyamide and cellulose fibres comprises (A) 0.001 to 5% of C1-C4 alkyl biguanide especially methyl biguanide, (B) 0À1 to 30% of at least one compound from alkali metal, NH 4 or organic NH 4 salts of aminopolycarboxylic acids and aminopolyphosphonic acids, (C) 0.001 to 1.5% of an optical brightener which is a 1,3- diarylpyrazoline, (D) at least one compound from anionic, non-ionic and amphoteric detergents, (E) one or more inorganic builder salts. Optical brighteners (C) have the formula in which Ar and Ar<SP>1</SP> each represent phenyl, diphenyl or naphthyl which may be substituted by OH, alkoxy, hydroxyalkyl, NH 2 , alkylamino, acylamino, carboxyl, sulphonic acid, sulphonamide or halogen. Other optical brighteners may be present. Builder salts (E) comprise alkali metal triphosphates and polyphosphates, sodium silicate, sodium sulphate, sodium chloride, alkali metal bicarbonates, carbonates, borates and hydroxides, lactic acid, citric acid. The pH of the compositions may be from 6 to 12. The compositions may comprise 5-40% of a per compound or mixture thereof with a bleaching agent activator or stabilizer e.g. magnesium silicate. Sodium perborate, alkali metal percarbonates, alkali metal perphosphates, urea perhydrate, organic per-acids and hydrogen peroxide are suitable. Optional ingredients are (a) enzymes e.g. proteases, lipases and amylases; (b) antifoaming agents e.g. saturated fatty acids and their alkali metal salts; (c) sodium cellulose glycollate; (d) synthetic polymers containing free carboxyl groups; (e) solution aids; (f) fillers, dyes, perfumes and bactericides. The compositions may be liquid, pastes or solids. The methyl biguanide may be dissolved or dispersed in a solvent and sprayed on to the spray-dried powder or part thereof in order to prevent thermal decomposition of the biguanide during spray-drying. The solvent may be water, an aqueous detergent solution or a liquid non- ionic detergent. Alternatively, the methyl biguanide may be dissolved in a melt of sodium sulphate.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19681816347 DE1816347A1 (en) | 1968-12-21 | 1968-12-21 | Detergent for textiles made from synthetic fibers |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1269680A true GB1269680A (en) | 1972-04-06 |
Family
ID=5717063
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB6241869A Expired GB1269680A (en) | 1968-12-21 | 1969-12-22 | Improvements in washing compositions |
Country Status (8)
| Country | Link |
|---|---|
| AT (1) | AT295710B (en) |
| BE (1) | BE743348A (en) |
| CH (1) | CH510108A (en) |
| DE (1) | DE1816347A1 (en) |
| ES (1) | ES374776A1 (en) |
| FR (1) | FR2026792A1 (en) |
| GB (1) | GB1269680A (en) |
| NL (1) | NL6917579A (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3795625A (en) * | 1971-06-03 | 1974-03-05 | Monsanto Co | Bleaching compositions |
| FI64639C (en) * | 1978-09-27 | 1983-12-12 | Unilever Nv | BLEKNINGS- OCH RENGOERINGSKOMPOSITION |
-
1968
- 1968-12-21 DE DE19681816347 patent/DE1816347A1/en active Pending
-
1969
- 1969-11-21 NL NL6917579A patent/NL6917579A/xx unknown
- 1969-12-18 BE BE743348D patent/BE743348A/xx unknown
- 1969-12-19 FR FR6944066A patent/FR2026792A1/fr not_active Withdrawn
- 1969-12-19 CH CH1894769A patent/CH510108A/en not_active IP Right Cessation
- 1969-12-19 AT AT1187569A patent/AT295710B/en not_active IP Right Cessation
- 1969-12-20 ES ES374776A patent/ES374776A1/en not_active Expired
- 1969-12-22 GB GB6241869A patent/GB1269680A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| DE1816347A1 (en) | 1970-06-25 |
| BE743348A (en) | 1970-06-18 |
| AT295710B (en) | 1972-01-10 |
| CH510108A (en) | 1971-07-15 |
| ES374776A1 (en) | 1973-03-16 |
| FR2026792A1 (en) | 1970-09-18 |
| NL6917579A (en) | 1970-06-23 |
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