GB1268208A - Stabilization of polymeric compositions - Google Patents
Stabilization of polymeric compositionsInfo
- Publication number
- GB1268208A GB1268208A GB07839/69A GB1783969A GB1268208A GB 1268208 A GB1268208 A GB 1268208A GB 07839/69 A GB07839/69 A GB 07839/69A GB 1783969 A GB1783969 A GB 1783969A GB 1268208 A GB1268208 A GB 1268208A
- Authority
- GB
- United Kingdom
- Prior art keywords
- maleate
- bis
- dibutyltin
- acid
- isooctyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000203 mixture Substances 0.000 title abstract 2
- 230000006641 stabilisation Effects 0.000 title abstract 2
- 238000011105 stabilization Methods 0.000 title abstract 2
- 239000002253 acid Substances 0.000 abstract 8
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 abstract 7
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 abstract 5
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 abstract 4
- AYOHIQLKSOJJQH-UHFFFAOYSA-N dibutyltin Chemical compound CCCC[Sn]CCCC AYOHIQLKSOJJQH-UHFFFAOYSA-N 0.000 abstract 4
- VLQWDCKTDZZUSU-KKUWAICFSA-L dibutyltin(2+);(z)-4-(6-methylheptoxy)-4-oxobut-2-enoate Chemical compound CC(C)CCCCCOC(=O)\C=C/C(=O)O[Sn](CCCC)(CCCC)OC(=O)\C=C/C(=O)OCCCCCC(C)C VLQWDCKTDZZUSU-KKUWAICFSA-L 0.000 abstract 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 2
- 239000005864 Sulphur Substances 0.000 abstract 2
- -1 alkarylene Chemical group 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- TUALPPJDVFLVNQ-KUAKSMGGSA-L dibutyltin(2+);(z)-4-oxo-4-phenylmethoxybut-2-enoate Chemical compound C=1C=CC=CC=1COC(=O)\C=C/C(=O)O[Sn](CCCC)(CCCC)OC(=O)\C=C/C(=O)OCC1=CC=CC=C1 TUALPPJDVFLVNQ-KUAKSMGGSA-L 0.000 abstract 2
- HGQSXVKHVMGQRG-UHFFFAOYSA-N dioctyltin Chemical compound CCCCCCCC[Sn]CCCCCCCC HGQSXVKHVMGQRG-UHFFFAOYSA-N 0.000 abstract 2
- 229910052736 halogen Inorganic materials 0.000 abstract 2
- 150000002367 halogens Chemical class 0.000 abstract 2
- 229940097413 isopropyl maleate Drugs 0.000 abstract 2
- 229920000642 polymer Polymers 0.000 abstract 2
- ZBBLRPRYYSJUCZ-GRHBHMESSA-L (z)-but-2-enedioate;dibutyltin(2+) Chemical compound [O-]C(=O)\C=C/C([O-])=O.CCCC[Sn+2]CCCC ZBBLRPRYYSJUCZ-GRHBHMESSA-L 0.000 abstract 1
- YABTYYUIWFCMDW-DYNMZUSMSA-L (z)-but-2-enedioate;tributylstannanylium Chemical compound CCCC[Sn](CCCC)(CCCC)OC(=O)\C=C/C(=O)O[Sn](CCCC)(CCCC)CCCC YABTYYUIWFCMDW-DYNMZUSMSA-L 0.000 abstract 1
- NJMGRJLQRLFQQX-HYXAFXHYSA-N 2-isopropylmaleic acid Chemical compound CC(C)C(\C(O)=O)=C\C(O)=O NJMGRJLQRLFQQX-HYXAFXHYSA-N 0.000 abstract 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 abstract 1
- 229920002433 Vinyl chloride-vinyl acetate copolymer Polymers 0.000 abstract 1
- 125000004450 alkenylene group Chemical group 0.000 abstract 1
- 125000002877 alkyl aryl group Chemical group 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 125000006270 aryl alkenylene group Chemical group 0.000 abstract 1
- 125000003710 aryl alkyl group Chemical group 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- 125000000732 arylene group Chemical group 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- PZGVVCOOWYSSGB-UHFFFAOYSA-L but-2-enedioate;dioctyltin(2+) Chemical compound CCCCCCCC[Sn]1(CCCCCCCC)OC(=O)C=CC(=O)O1 PZGVVCOOWYSSGB-UHFFFAOYSA-L 0.000 abstract 1
- 125000005724 cycloalkenylene group Chemical group 0.000 abstract 1
- 125000000753 cycloalkyl group Chemical group 0.000 abstract 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 abstract 1
- PWEVMPIIOJUPRI-UHFFFAOYSA-N dimethyltin Chemical compound C[Sn]C PWEVMPIIOJUPRI-UHFFFAOYSA-N 0.000 abstract 1
- 229920001519 homopolymer Polymers 0.000 abstract 1
- 238000010348 incorporation Methods 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 239000003381 stabilizer Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/56—Organo-metallic compounds, i.e. organic compounds containing a metal-to-carbon bond
- C08K5/57—Organo-tin compounds
- C08K5/58—Organo-tin compounds containing sulfur
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/56—Organo-metallic compounds, i.e. organic compounds containing a metal-to-carbon bond
- C08K5/57—Organo-tin compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Abstract
1,268,208. Stabilization of halogen containing polymers. M. & T. INTERNATIONAL N.V. 8 April, 1969 [8 April, 1968], No. 17839/69. Heading C3P. Halogen containing polymers are stabilized against heat by incorporation of (a) a compound of the formula (RSnX 1.5 ) n wherein X is sulphur or a mixture of 1-10 parts of oxygen and 10-1 parts of sulphur and n is an integer 2-1000, and (b) a compound of the formula wherein R and R<SP>1</SP> are independently C 1-20 alkyl, aryl, aralkyl, alkaryl or cycloalkyl; Y is OOCR<SP>1</SP>COOR or OOCR<SP>11</SP>COO or and g = 4, a = 1-3, b # 1 and m = 2 or 3 except when Y is OOCR<SP>11</SP>COO when g = 3 and a = 2, and R<SP>11</SP> = alkenylene, arylene, alkarylene, arylalkenylene or cycloalkenylene. Examples describe the treatment of vinyl chloride homopolymer with (a) butylthiostannoic acid and (b) dibutyltin maleate, bis-(tributyltin)- maleate, dibutyltin bis-(iso octyl maleate), din-octyltin maleate, dibutyltin bis-(isopropylmaleate), bis-(dibutyltin laurate) maleate, dibutyltin bis-(benzyl maleate) or dibutyltin bis- (cyclohexyl maleate); and the treatment of vinylchloride-vinyl acetate copolymer with (a) butylthiostannoic acid and (b) dibutyltin bis- (isooctylmaleate), di-n-octyltin maleate, dibutyltin bis.(isopropylmaleate), bis-(dibutyltin laurate)-maleate, dibutyltin bis-(benzyl maleate) or dibutyltin bis-(cyolohexyl maleate). Other specified stabilizer systems are (1) butyl thiostannoic acid and dibutyltin bis-(isooctyl maleate), (2) butyl thiostannoic acid and di-noctyltin bis-(isooctyl maleate), (3) butyl thiostannoic acid and dimethyl tin bis-(isooctyl maleate), (4) butyl thiostannoic acid and di-noctyltin bis-(isooctyl maleate), (5) octylthiostannoic acid di-n-octyltin bis-(isooctyl maleate) and (6) cyclohexyl thiostannoic acid and di-n - octyltin bis-(iso-octyl maleate):
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US71972368A | 1968-04-08 | 1968-04-08 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1268208A true GB1268208A (en) | 1972-03-22 |
Family
ID=24891100
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB07839/69A Expired GB1268208A (en) | 1968-04-08 | 1969-04-08 | Stabilization of polymeric compositions |
Country Status (8)
| Country | Link |
|---|---|
| AT (1) | AT307053B (en) |
| BE (1) | BE731165A (en) |
| CH (1) | CH512530A (en) |
| DE (1) | DE1917847A1 (en) |
| FR (1) | FR2005803A1 (en) |
| GB (1) | GB1268208A (en) |
| NL (1) | NL6905375A (en) |
| SE (1) | SE380031B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN119775683A (en) * | 2024-12-26 | 2025-04-08 | 金发科技股份有限公司 | A high whiteness PVC composition and its preparation method and application |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1552774A (en) * | 1975-11-25 | 1979-09-19 | Akzo Nv | Organotin stabilizer compositions and polyvinyl resins stabilized therewith |
-
1969
- 1969-04-08 BE BE731165D patent/BE731165A/xx not_active IP Right Cessation
- 1969-04-08 AT AT341769A patent/AT307053B/en not_active IP Right Cessation
- 1969-04-08 GB GB07839/69A patent/GB1268208A/en not_active Expired
- 1969-04-08 FR FR6910742A patent/FR2005803A1/fr active Pending
- 1969-04-08 SE SE6904905A patent/SE380031B/xx unknown
- 1969-04-08 NL NL6905375A patent/NL6905375A/xx unknown
- 1969-04-08 CH CH529069A patent/CH512530A/en not_active IP Right Cessation
- 1969-04-08 DE DE19691917847 patent/DE1917847A1/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN119775683A (en) * | 2024-12-26 | 2025-04-08 | 金发科技股份有限公司 | A high whiteness PVC composition and its preparation method and application |
Also Published As
| Publication number | Publication date |
|---|---|
| NL6905375A (en) | 1969-10-10 |
| BE731165A (en) | 1969-09-15 |
| DE1917847A1 (en) | 1969-11-06 |
| AT307053B (en) | 1973-05-10 |
| FR2005803A1 (en) | 1969-12-19 |
| SE380031B (en) | 1975-10-27 |
| CH512530A (en) | 1971-09-15 |
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