GB1266829A - - Google Patents
Info
- Publication number
- GB1266829A GB1266829A GB1266829DA GB1266829A GB 1266829 A GB1266829 A GB 1266829A GB 1266829D A GB1266829D A GB 1266829DA GB 1266829 A GB1266829 A GB 1266829A
- Authority
- GB
- United Kingdom
- Prior art keywords
- rosin
- polyamine
- water
- emulsion
- emulsions
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 abstract 8
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 abstract 8
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 abstract 8
- 239000000839 emulsion Substances 0.000 abstract 5
- 239000000463 material Substances 0.000 abstract 3
- 229920000768 polyamine Polymers 0.000 abstract 3
- 125000002091 cationic group Chemical group 0.000 abstract 2
- 239000000725 suspension Substances 0.000 abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 2
- QAIGYXWRIHZZAA-UHFFFAOYSA-M 1-methylpyridin-1-ium;chloride Chemical compound [Cl-].C[N+]1=CC=CC=C1 QAIGYXWRIHZZAA-UHFFFAOYSA-M 0.000 abstract 1
- 229920002873 Polyethylenimine Polymers 0.000 abstract 1
- 229920002472 Starch Polymers 0.000 abstract 1
- 150000007513 acids Chemical class 0.000 abstract 1
- 229940037003 alum Drugs 0.000 abstract 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 abstract 1
- 239000005018 casein Substances 0.000 abstract 1
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 abstract 1
- 235000021240 caseins Nutrition 0.000 abstract 1
- 239000003995 emulsifying agent Substances 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- -1 polyvinylamine Polymers 0.000 abstract 1
- 229920002717 polyvinylpyridine Polymers 0.000 abstract 1
- 229920005989 resin Polymers 0.000 abstract 1
- 239000011347 resin Substances 0.000 abstract 1
- 238000004513 sizing Methods 0.000 abstract 1
- 235000019698 starch Nutrition 0.000 abstract 1
- 239000008107 starch Substances 0.000 abstract 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/62—Rosin; Derivatives thereof
Landscapes
- Paper (AREA)
Abstract
1,266,829. Sizing paper. HERCULES Inc. 24 June, 1970, No. 30727/70. Headings D2A and D2B. 0.15-2% of a rosin emulsion size (which term includes emulsions of rosin adducts), having an amount of unsaponified rosin (represented as a percentage of available carboxyl groups that have not been saponified), of 80- 98%; from 0.15-0.5% alum; and from 0.01- 0.25% of a water-soluble cationic polyamine having a molecular weight in excess of 1000 are added to an aqueous pulp suspension at a consistency of 1.5-3% and pH 6-7.5, the pH maintained at this figure, and the pulp sheeted. The rosin emulsion is preferably added before the polyamine. The rosin emulsion may be 70-55% water, and 30-45% rosinbase material, which material comprises 0- 95% rosin and 100-5% of an adduct of rosin and an acidic compound containing the -#C=#C-#C=O group. The polyamine may be a polymer having -CH 2 CH 2 NH- linkages e.g. polyethyleneimine, cationic starch, polyvinylamine, polyvinylpyridine, poly-N-methyl pyridinium chloride, urea-formaldehyde-polyalkylenepolyamines, and thermosettable aminopolyamide-epichlorohydrin resins. The rosin emulsions may contain an emulsifier e.g. casein. The pulp suspension may be diluted with white water after addition of the above materials and then screened, e.g. by centrifugal cleaners or conventional screens.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19702031293 DE2031293B2 (en) | 1970-06-24 | 1970-06-24 | METHOD OF SIZING PAPER |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1266829A true GB1266829A (en) | 1972-03-15 |
Family
ID=5774860
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB1266829D Expired GB1266829A (en) | 1970-06-24 | 1970-06-24 |
Country Status (7)
| Country | Link |
|---|---|
| AU (1) | AU433656B2 (en) |
| BE (1) | BE752361A (en) |
| CH (1) | CH511329A (en) |
| DE (1) | DE2031293B2 (en) |
| FR (1) | FR2094462A5 (en) |
| GB (1) | GB1266829A (en) |
| NL (1) | NL148667B (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4857149A (en) * | 1986-09-08 | 1989-08-15 | Weyerhaeuser Company | Method and products for sizing paper and similar materials |
| US5912306A (en) * | 1992-12-30 | 1999-06-15 | Hercules Incorporated | Cationic compounds useful as drainage aids and stabilizers for rosin-based sizing agents |
| US6033526A (en) * | 1994-12-28 | 2000-03-07 | Hercules Incorporated | Rosin sizing at neutral to alkaline pH |
| US6273997B1 (en) | 1994-12-28 | 2001-08-14 | Hercules Incorporated | Rosin/hydrocarbon resin size for paper |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1444751A (en) * | 1973-01-22 | 1976-08-04 | Tenneco Chem | Paper sizing |
| EP0112525B1 (en) * | 1982-12-08 | 1987-03-18 | Giulini Chemie GmbH | Agent and process for neutral sizing |
-
1970
- 1970-06-22 BE BE752361D patent/BE752361A/en not_active IP Right Cessation
- 1970-06-23 AU AU16678/70A patent/AU433656B2/en not_active Expired
- 1970-06-23 FR FR7023051A patent/FR2094462A5/fr not_active Expired
- 1970-06-23 NL NL7009215A patent/NL148667B/en not_active IP Right Cessation
- 1970-06-24 CH CH956470A patent/CH511329A/en not_active IP Right Cessation
- 1970-06-24 GB GB1266829D patent/GB1266829A/en not_active Expired
- 1970-06-24 DE DE19702031293 patent/DE2031293B2/en not_active Ceased
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4857149A (en) * | 1986-09-08 | 1989-08-15 | Weyerhaeuser Company | Method and products for sizing paper and similar materials |
| US5912306A (en) * | 1992-12-30 | 1999-06-15 | Hercules Incorporated | Cationic compounds useful as drainage aids and stabilizers for rosin-based sizing agents |
| US6033526A (en) * | 1994-12-28 | 2000-03-07 | Hercules Incorporated | Rosin sizing at neutral to alkaline pH |
| US6228219B1 (en) | 1994-12-28 | 2001-05-08 | Hercules Incorporated | Rosin sizing at neutral to alkaline pH |
| US6273997B1 (en) | 1994-12-28 | 2001-08-14 | Hercules Incorporated | Rosin/hydrocarbon resin size for paper |
Also Published As
| Publication number | Publication date |
|---|---|
| NL7009215A (en) | 1971-12-27 |
| AU1667870A (en) | 1972-01-06 |
| BE752361A (en) | 1970-12-22 |
| CH511329A (en) | 1971-08-15 |
| DE2031293B2 (en) | 1976-08-12 |
| AU433656B2 (en) | 1973-03-13 |
| NL148667B (en) | 1976-02-16 |
| DE2031293A1 (en) | 1971-12-30 |
| FR2094462A5 (en) | 1972-02-04 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed | ||
| PE20 | Patent expired after termination of 20 years |