GB1263172A - Preparation of mixed cellulose ethers - Google Patents
Preparation of mixed cellulose ethersInfo
- Publication number
- GB1263172A GB1263172A GB757969A GB757969A GB1263172A GB 1263172 A GB1263172 A GB 1263172A GB 757969 A GB757969 A GB 757969A GB 757969 A GB757969 A GB 757969A GB 1263172 A GB1263172 A GB 1263172A
- Authority
- GB
- United Kingdom
- Prior art keywords
- cellulose
- carboxymethyl
- hydroxide
- carbon atoms
- base
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920003086 cellulose ether Polymers 0.000 title abstract 4
- 150000008044 alkali metal hydroxides Chemical class 0.000 abstract 4
- 239000002585 base Substances 0.000 abstract 4
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 abstract 3
- 125000004432 carbon atom Chemical group C* 0.000 abstract 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 2
- 229910001854 alkali hydroxide Inorganic materials 0.000 abstract 2
- 125000002947 alkylene group Chemical group 0.000 abstract 2
- 125000004181 carboxyalkyl group Chemical group 0.000 abstract 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 abstract 2
- 125000002057 carboxymethyl group Chemical group [H]OC(=O)C([H])([H])[*] 0.000 abstract 2
- 229920002678 cellulose Polymers 0.000 abstract 2
- 239000001913 cellulose Substances 0.000 abstract 2
- 125000002768 hydroxyalkyl group Chemical group 0.000 abstract 2
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Inorganic materials [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 abstract 2
- GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 abstract 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 abstract 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 abstract 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract 1
- NDKBVBUGCNGSJJ-UHFFFAOYSA-M benzyltrimethylammonium hydroxide Chemical compound [OH-].C[N+](C)(C)CC1=CC=CC=C1 NDKBVBUGCNGSJJ-UHFFFAOYSA-M 0.000 abstract 1
- 239000012267 brine Substances 0.000 abstract 1
- 239000001768 carboxy methyl cellulose Substances 0.000 abstract 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 abstract 1
- 229920003090 carboxymethyl hydroxyethyl cellulose Polymers 0.000 abstract 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 abstract 1
- 150000002170 ethers Chemical class 0.000 abstract 1
- TWNIBLMWSKIRAT-VFUOTHLCSA-N levoglucosan Chemical group O[C@@H]1[C@@H](O)[C@H](O)[C@H]2CO[C@@H]1O2 TWNIBLMWSKIRAT-VFUOTHLCSA-N 0.000 abstract 1
- 150000003856 quaternary ammonium compounds Chemical class 0.000 abstract 1
- 125000001453 quaternary ammonium group Chemical group 0.000 abstract 1
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 abstract 1
- 125000001424 substituent group Chemical group 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/60—Compositions for stimulating production by acting on the underground formation
- C09K8/62—Compositions for forming crevices or fractures
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
- C08B11/00—Preparation of cellulose ethers
- C08B11/193—Mixed ethers, i.e. ethers with two or more different etherifying groups
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Biochemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Polysaccharides And Polysaccharide Derivatives (AREA)
Abstract
1,263,172. Preparation of mixed cellulose ethers. DOW CHEMICAL CO. 12 Feb., 1969, No. 7579/69. Heading C3A. [Also in Division E1] Mixed carboxyalkylhydroxyalkyl cellulose ethers, wherein the carboxyalkyl and hydroxyalkyl groups each contain from 2 to 3 carbon atoms, having a carboxyalkyl M.S. (i.e. the average number of moles of that substituent attached, directly or indirectly through a side chain, to each anhydro-glucose residue unit of the ether) of 0À2 to 1À2 and a hydroxyalkyl M.S. of 1À5 to 5, are prepared by reacting cellulose with, in order of addition, an alkali hydroxide (i.e. an alkali metal hydroxide or quaternary ammonium base), a chlorinated carboxylic acid having from 2 to 3 carbon atoms and an alkylene oxide having from 2 to 3 carbon atoms to form the cellulose ether, which is dried in the presence of from 0À1 to 3% of base, based on the weight of the reaction mass, at a temperature less than 200‹ F. A portion of the total chlorinated carboxylic acid used may be reacted with the alkalized cellulose prior to the addition of the alkylene oxide to provide an intermediate carboxymethyl cellulose with a carboxymethyl M.S. of 0À05 to 0À2. The alkali hydroxide used may be sodium or potassium hydroxide or trimethyl benzyl ammonium hydroxide. When too little base remains in the reaction mass, additional base (e.g. an alkali metal hydroxide or carbonate or quaternary ammonium compound) is incorporated at the end of the reaction. A preferred product is a carboxymethyl hydroxyethyl cellulose having a carboxymethyl M.S. of 0À3 to 0À5 and a hydroxyethyl M.S. of 1À8 to 3. The ethers are soluble in water and brine and are non-thermogelling.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB757969A GB1263172A (en) | 1969-02-12 | 1969-02-12 | Preparation of mixed cellulose ethers |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB757969A GB1263172A (en) | 1969-02-12 | 1969-02-12 | Preparation of mixed cellulose ethers |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1263172A true GB1263172A (en) | 1972-02-09 |
Family
ID=9835852
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB757969A Expired GB1263172A (en) | 1969-02-12 | 1969-02-12 | Preparation of mixed cellulose ethers |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB1263172A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3909070A1 (en) * | 1989-03-20 | 1990-09-27 | Aqualon Gmbh | Additive for gypsum-containing and cement-containing compositions |
| CN102666777A (en) * | 2009-10-30 | 2012-09-12 | 艾伯塔创新技术未来公司 | Water flooding method for secondary hydrocarbon recovery |
-
1969
- 1969-02-12 GB GB757969A patent/GB1263172A/en not_active Expired
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3909070A1 (en) * | 1989-03-20 | 1990-09-27 | Aqualon Gmbh | Additive for gypsum-containing and cement-containing compositions |
| DE3909070C2 (en) * | 1989-03-20 | 1998-12-17 | Aqualon Gmbh | Additive for gypsum and cement-containing masses and their use |
| CN102666777A (en) * | 2009-10-30 | 2012-09-12 | 艾伯塔创新技术未来公司 | Water flooding method for secondary hydrocarbon recovery |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| GB1451412A (en) | Hydroxypropyl methylcellulose ethers and method of preparation | |
| GB1251019A (en) | ||
| ES432123A1 (en) | Process for the production of water-adsorbing but water-insoluble cellulose ethers | |
| ES431916A1 (en) | Process for the production of water adsorbing but water-insoluble cellulose ethers | |
| ES8401990A1 (en) | Process for preparing water-soluble cellulose ethers with dimethoxyethane as a dispersing agent. | |
| KR890005151A (en) | Carboxymethyl hydrophobically modified hydroxyethyl cellulose (CMHMHEC) and its use in protective coating compositions | |
| GB1487859A (en) | Water soluble ternary cellulose ethers | |
| GB1453382A (en) | ||
| GB1139637A (en) | Process for the manufacture of low viscosity water-soluble cellulose ethers | |
| US4298728A (en) | Method of preparing hydroxyethyl ethers of cellulose | |
| GB1510131A (en) | Preparation and purification of cellulose ethers | |
| KR840008375A (en) | Process for preparing water-soluble ternary cellulose ether | |
| GB1263172A (en) | Preparation of mixed cellulose ethers | |
| GB1235801A (en) | A process for the manufacture of rapidly-disintegrating solid dosage unit forms | |
| ES8404378A1 (en) | Process for preparing alkali metal salt of carboxymethyl cellulose | |
| US3033853A (en) | Preparation of hydroxyalkyl starches | |
| GB1363834A (en) | Sodium aluminium borate and preparation thereof | |
| DE3164454D1 (en) | Water-soluble mixed cellulose ethers with a phosphonomethyl substituent, and a process for their preparation | |
| GB1464689A (en) | Process for preparing 3-trichloromethyl-5-ethoxy-1,2,4- thiadiazole from trichloroacetonitrile | |
| GB1156220A (en) | Cationic Starch | |
| ES427715A2 (en) | Complexes of a-6-deoxy-5-hydroxy tetracycline and their preparation | |
| JPS56143201A (en) | Etherification of carboxymethyl cellulose | |
| GB1253726A (en) | Manufacture of carboxymethyl hydroxyalkyl mixed cellulose ethers | |
| GB1315377A (en) | Solid fire-extinguishing compositions | |
| GB1307967A (en) | Explosive compositions |