GB1261609A - Improvements in or relating to the removal of acid gases from gaseous hydrocarbon-containing effluents - Google Patents
Improvements in or relating to the removal of acid gases from gaseous hydrocarbon-containing effluentsInfo
- Publication number
- GB1261609A GB1261609A GB5010769A GB5010769A GB1261609A GB 1261609 A GB1261609 A GB 1261609A GB 5010769 A GB5010769 A GB 5010769A GB 5010769 A GB5010769 A GB 5010769A GB 1261609 A GB1261609 A GB 1261609A
- Authority
- GB
- United Kingdom
- Prior art keywords
- hydrocarbon
- dienes
- withdrawn
- line
- acid gases
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229930195733 hydrocarbon Natural products 0.000 title abstract 14
- 150000002430 hydrocarbons Chemical class 0.000 title abstract 14
- 239000004215 Carbon black (E152) Substances 0.000 title abstract 11
- 239000007789 gas Substances 0.000 title abstract 9
- 239000002253 acid Substances 0.000 title abstract 7
- 150000001993 dienes Chemical class 0.000 abstract 6
- 150000001412 amines Chemical class 0.000 abstract 4
- 239000002904 solvent Substances 0.000 abstract 4
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 abstract 3
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 abstract 2
- WGQKYBSKWIADBV-UHFFFAOYSA-N benzylamine Chemical compound NCC1=CC=CC=C1 WGQKYBSKWIADBV-UHFFFAOYSA-N 0.000 abstract 2
- PAFZNILMFXTMIY-UHFFFAOYSA-N cyclohexylamine Chemical compound NC1CCCCC1 PAFZNILMFXTMIY-UHFFFAOYSA-N 0.000 abstract 2
- 238000010992 reflux Methods 0.000 abstract 2
- XFNJVJPLKCPIBV-UHFFFAOYSA-N trimethylenediamine Chemical compound NCCCN XFNJVJPLKCPIBV-UHFFFAOYSA-N 0.000 abstract 2
- BMVXCPBXGZKUPN-UHFFFAOYSA-N 1-hexanamine Chemical compound CCCCCCN BMVXCPBXGZKUPN-UHFFFAOYSA-N 0.000 abstract 1
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 abstract 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 abstract 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Natural products CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 abstract 1
- BHHGXPLMPWCGHP-UHFFFAOYSA-N Phenethylamine Chemical compound NCCC1=CC=CC=C1 BHHGXPLMPWCGHP-UHFFFAOYSA-N 0.000 abstract 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 abstract 1
- MZVQCMJNVPIDEA-UHFFFAOYSA-N [CH2]CN(CC)CC Chemical group [CH2]CN(CC)CC MZVQCMJNVPIDEA-UHFFFAOYSA-N 0.000 abstract 1
- NISGSNTVMOOSJQ-UHFFFAOYSA-N cyclopentanamine Chemical compound NC1CCCC1 NISGSNTVMOOSJQ-UHFFFAOYSA-N 0.000 abstract 1
- WEHWNAOGRSTTBQ-UHFFFAOYSA-N dipropylamine Chemical compound CCCNCCC WEHWNAOGRSTTBQ-UHFFFAOYSA-N 0.000 abstract 1
- 235000019441 ethanol Nutrition 0.000 abstract 1
- 239000012535 impurity Substances 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 230000004048 modification Effects 0.000 abstract 1
- 238000012986 modification Methods 0.000 abstract 1
- DNWSSZXZTVMPKC-UHFFFAOYSA-N n,n-dihydroxypropan-1-amine Chemical compound CCCN(O)O DNWSSZXZTVMPKC-UHFFFAOYSA-N 0.000 abstract 1
- 239000001294 propane Substances 0.000 abstract 1
- AOHJOMMDDJHIJH-UHFFFAOYSA-N propylenediamine Chemical compound CC(N)CN AOHJOMMDDJHIJH-UHFFFAOYSA-N 0.000 abstract 1
- 238000000197 pyrolysis Methods 0.000 abstract 1
- 238000011084 recovery Methods 0.000 abstract 1
- 238000004064 recycling Methods 0.000 abstract 1
- 238000000926 separation method Methods 0.000 abstract 1
- -1 triaminopropane Chemical compound 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
- B01D53/1456—Removing acid components
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/48—Sulfur compounds
- B01D53/52—Hydrogen sulfide
- B01D53/526—Mixtures of hydrogen sulfide and carbon dioxide
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C7/00—Purification; Separation; Use of additives
- C07C7/11—Purification; Separation; Use of additives by absorption, i.e. purification or separation of gaseous hydrocarbons with the aid of liquids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/02—Polycondensates containing more than one epoxy group per molecule
- C08G59/12—Polycondensates containing more than one epoxy group per molecule of polycarboxylic acids with epihalohydrins or precursors thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
- C10K1/00—Purifying combustible gases containing carbon monoxide
- C10K1/08—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors
- C10K1/10—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with aqueous liquids
- C10K1/12—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with aqueous liquids alkaline-reacting including the revival of the used wash liquors
- C10K1/14—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with aqueous liquids alkaline-reacting including the revival of the used wash liquors organic
- C10K1/143—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with aqueous liquids alkaline-reacting including the revival of the used wash liquors organic containing amino groups
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Health & Medical Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Biomedical Technology (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
1,261,609. Separating acid gases from hydrocarbons. LUMMUS CO. 13 Oct., 1969 [17 Oct., 1968], No. 50107/69. Heading BIL. In removing acid gases from a gaseous hydrocarbon-containing effluent containing acid gases and dienes as impurities e.g. obtained from the pyrolysis of ethane, propane, naphtha or gas oil, the hydrocarbon effluent is fed via line 10 into absorbing tower 11 where it contacts countercurrently with an aqueous amine solution, e.g. hexylamine, dipropylamine, propylene diamine, trimethylenediamine, ethylene diamine, triaminopropane, triethanolamine, dihydroxypropylamine, diethylamino ethyl alcohol, monoethanolamine, benzylamine, phenylethylamine, cyclohexylamine or cyclopentylamine, fed via line 12. The acid gases and dienes are absorbed into the amine and acid gas free hydrocarbon is withdrawn at 13. A hydrocarbon solvent, e.g. toluene or a low molecular weight naphtha, is added via line 14 and the resulting mixture led off at 15 and via mixer 17, and coalescer 19 to a settling chamber 21 maintained at a lower pressure than the absorbing tower 11 by a control valve 20. An aqueous amine phase essentially free of hydrocarbons is withdrawn through line 23, through heat exchanger 24 to a regenerator 25 where acid gas is withdrawn at 26 whilst the purified amine is recycled to line 12. The hydrocarbon phase is skimmed from the settler 21 and passed to a low pressure still 32 via heat exchanger 31. Gases released from the settler 21 are introduced via line 34 into the still 32 to aid in the recovery of the dienes. A diene overhead is withdrawn through 35 passed to condenser 36 and reflux drum 37. The liquid portion separated in reflux 37 is recycled to the still 32 whilst the gaseous portion is withdrawn by a steam ejector 41 or vacuum pump. A hydrocarbon solvent bottoms essentially free of dienes is then passed via 43 and the heat exchanger 31 into line 14 for recycling. In a modification Fig. 2 (not shown) wherein heavier hydrocarbons are to be removed in addition to dienes an initial separation of the heavier hydrocarbon phase may be effected before the addition of the hydrocarbon solvent. The separated hydrocarbon phase is added to the hydrocarbon phase formed after the addition of the solvent.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH1456068A CH508614A (en) | 1968-09-30 | 1968-09-30 | Process for the preparation of new diglycidyl esters of aliphatic dicarboxylic acids and their use in curable mixtures |
| US76830368A | 1968-10-17 | 1968-10-17 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1261609A true GB1261609A (en) | 1972-01-26 |
Family
ID=25714723
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB5010769A Expired GB1261609A (en) | 1968-09-30 | 1969-09-25 | Improvements in or relating to the removal of acid gases from gaseous hydrocarbon-containing effluents |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB1261609A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2240858C1 (en) * | 2003-08-13 | 2004-11-27 | Казанское открытое акционерное общество "Органический синтез" | Gas treatment absorbent |
| US20130055895A1 (en) * | 2010-01-05 | 2013-03-07 | Thyssenkrupp Uhde Gmbh | Removal of co2 from gases of low co2 partial pressures by means of 1,2 diaminopropane |
-
1969
- 1969-09-25 GB GB5010769A patent/GB1261609A/en not_active Expired
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2240858C1 (en) * | 2003-08-13 | 2004-11-27 | Казанское открытое акционерное общество "Органический синтез" | Gas treatment absorbent |
| US20130055895A1 (en) * | 2010-01-05 | 2013-03-07 | Thyssenkrupp Uhde Gmbh | Removal of co2 from gases of low co2 partial pressures by means of 1,2 diaminopropane |
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