GB1252858A - - Google Patents
Info
- Publication number
- GB1252858A GB1252858A GB1252858DA GB1252858A GB 1252858 A GB1252858 A GB 1252858A GB 1252858D A GB1252858D A GB 1252858DA GB 1252858 A GB1252858 A GB 1252858A
- Authority
- GB
- United Kingdom
- Prior art keywords
- examples
- binder
- contain
- microcapsules
- granules
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000011230 binding agent Substances 0.000 abstract 5
- 239000003094 microcapsule Substances 0.000 abstract 5
- 229920002472 Starch Polymers 0.000 abstract 4
- 239000008187 granular material Substances 0.000 abstract 4
- 239000000463 material Substances 0.000 abstract 4
- 239000008107 starch Substances 0.000 abstract 4
- 235000019698 starch Nutrition 0.000 abstract 4
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 abstract 3
- 239000011248 coating agent Substances 0.000 abstract 3
- 238000000576 coating method Methods 0.000 abstract 3
- 239000000203 mixture Substances 0.000 abstract 2
- 229920002451 polyvinyl alcohol Polymers 0.000 abstract 2
- 239000002243 precursor Substances 0.000 abstract 2
- 229920005989 resin Polymers 0.000 abstract 2
- 239000011347 resin Substances 0.000 abstract 2
- 229920002134 Carboxymethyl cellulose Polymers 0.000 abstract 1
- IPAJDLMMTVZVPP-UHFFFAOYSA-N Crystal violet lactone Chemical compound C1=CC(N(C)C)=CC=C1C1(C=2C=CC(=CC=2)N(C)C)C2=CC=C(N(C)C)C=C2C(=O)O1 IPAJDLMMTVZVPP-UHFFFAOYSA-N 0.000 abstract 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 abstract 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 abstract 1
- 239000004372 Polyvinyl alcohol Substances 0.000 abstract 1
- ZKURGBYDCVNWKH-UHFFFAOYSA-N [3,7-bis(dimethylamino)phenothiazin-10-yl]-phenylmethanone Chemical compound C12=CC=C(N(C)C)C=C2SC2=CC(N(C)C)=CC=C2N1C(=O)C1=CC=CC=C1 ZKURGBYDCVNWKH-UHFFFAOYSA-N 0.000 abstract 1
- 230000002378 acidificating effect Effects 0.000 abstract 1
- 125000006267 biphenyl group Chemical group 0.000 abstract 1
- 239000001768 carboxy methyl cellulose Substances 0.000 abstract 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 abstract 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 abstract 1
- 229940105329 carboxymethylcellulose Drugs 0.000 abstract 1
- 239000005018 casein Substances 0.000 abstract 1
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 abstract 1
- 235000021240 caseins Nutrition 0.000 abstract 1
- 238000005354 coacervation Methods 0.000 abstract 1
- UFULAYFCSOUIOV-UHFFFAOYSA-N cysteamine Chemical compound NCCS UFULAYFCSOUIOV-UHFFFAOYSA-N 0.000 abstract 1
- WSFSSNUMVMOOMR-UHFFFAOYSA-N formaldehyde Substances O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 abstract 1
- 229940071826 hydroxyethyl cellulose Drugs 0.000 abstract 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 abstract 1
- 229920000609 methyl cellulose Polymers 0.000 abstract 1
- 239000001923 methylcellulose Substances 0.000 abstract 1
- 229960002900 methylcellulose Drugs 0.000 abstract 1
- 235000010981 methylcellulose Nutrition 0.000 abstract 1
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 abstract 1
- 230000002028 premature Effects 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/124—Duplicating or marking methods; Sheet materials for use therein using pressure to make a masked colour visible, e.g. to make a coloured support visible, to create an opaque or transparent pattern, or to form colour by uniting colour-forming components
- B41M5/1243—Inert particulate additives, e.g. protective stilt materials
Landscapes
- Color Printing (AREA)
- Laminated Bodies (AREA)
Abstract
1,252,858. Colour-reactive record sheets. NATIONAL CASH REGISTER CO. 12 March, 1970 [8 April, 1969], No. 11823/70. Heading D2B. [Also in Division C3] Pressure-sensitive record material comprises a supporting sheet having a coating on one surface, which coating includes starch granules, preferably ungelatinized, and pressure-rupturable micro-capsules containing a solution of a colourless basic chromogenic material that develops colour when reacted with an acidic material. The coating may also contain a binder, e.g. of gelatinised starch. The starch granules are preferably larger than the microcapsules and protect them from premature rupture. Other binders referred to are poly (vinyl alcohol), hydroxyethyl-cellulose, methylcellulose, carboxymethyl-cellulose, casein and ethylene-vinyl acetate copolymers. The microcapsules used in the Examples are of gelatingum arabic produced by coacervation and contain a mixture of chlorinated diphenyl and oil having dispersed therein, 3,3-bis(paradimethylaminophenyl)-6-dimethylaminophthalide alone or with benzoyl-leuco methylene blue. In Examples 1-4 the microcapsules contain the two dye-precursors, the granules may be from any of seven different plant sources or may be hypochlorite-modified, and the binder is a gelatinized hydroxyethylated starch. Example 5 uses polyvinyl alcohol solution as binder; Example 6 applies the granules separately and Example 7 applies the binder separately, but these three are otherwise similar to Examples 1-4. In Examples 8 and 9 the microcapsules contain only the first dye-precursor, but the compositions are otherwise similar to Examples 1-4. In Example 8, the coreactive material is applied as a solution of paraphenylphenolformaldehyde resin and parachlorophenolparaoctylphenol-formaldehyde resin in toluene.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US81433669A | 1969-04-08 | 1969-04-08 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1252858A true GB1252858A (en) | 1971-11-10 |
Family
ID=25214754
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB1252858D Expired GB1252858A (en) | 1969-04-08 | 1970-03-12 |
Country Status (15)
| Country | Link |
|---|---|
| JP (1) | JPS4833204B1 (en) |
| AT (1) | AT303765B (en) |
| BE (1) | BE748429A (en) |
| BR (1) | BR7018024D0 (en) |
| CA (1) | CA989255A (en) |
| CH (1) | CH539520A (en) |
| DE (1) | DE2016483C2 (en) |
| DK (1) | DK125538B (en) |
| ES (1) | ES378121A1 (en) |
| FR (1) | FR2038318A1 (en) |
| GB (1) | GB1252858A (en) |
| NL (1) | NL146751B (en) |
| NO (1) | NO126840B (en) |
| SE (1) | SE362610B (en) |
| ZA (1) | ZA702136B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4280718A (en) | 1975-03-24 | 1981-07-28 | Henkel Corporation | Pressure sensitive recording sheet containing size classified cereal starch granules |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE790166A (en) * | 1971-10-18 | 1973-04-16 | Wiggins Teape Res Dev | SHEETS OR TABLECLOTHS WITH CAPSULES |
| JPS5835479B2 (en) * | 1978-12-18 | 1983-08-02 | 三島製紙株式会社 | pressure sensitive recording material |
| EP0620121A3 (en) | 1993-04-15 | 1995-11-15 | Minnesota Mining & Mfg | Legume starch stilting material for carbonless papers used in offset printing presses and in copier/duplicators. |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL170725B (en) * | 1951-08-24 | Chevron Res | METHOD FOR CONVERTING WASTE MATERIAL WITH STEAM, WHEN THE PRESENCE OF SODIUM AND/OR POTASSIUM CARBONATE. |
-
1970
- 1970-03-12 GB GB1252858D patent/GB1252858A/en not_active Expired
- 1970-03-20 CA CA078,016A patent/CA989255A/en not_active Expired
- 1970-03-31 ZA ZA702136A patent/ZA702136B/en unknown
- 1970-04-01 AT AT295270A patent/AT303765B/en not_active IP Right Cessation
- 1970-04-01 ES ES378121A patent/ES378121A1/en not_active Expired
- 1970-04-03 BE BE748429D patent/BE748429A/en not_active IP Right Cessation
- 1970-04-06 BR BR218024/70A patent/BR7018024D0/en unknown
- 1970-04-07 NO NO01280/70A patent/NO126840B/no unknown
- 1970-04-07 SE SE04727/70A patent/SE362610B/xx unknown
- 1970-04-07 FR FR7012450A patent/FR2038318A1/fr active Pending
- 1970-04-07 DK DK172070AA patent/DK125538B/en not_active IP Right Cessation
- 1970-04-07 DE DE2016483A patent/DE2016483C2/en not_active Expired
- 1970-04-08 NL NL707005045A patent/NL146751B/en not_active IP Right Cessation
- 1970-04-08 JP JP45030067A patent/JPS4833204B1/ja active Pending
- 1970-04-08 CH CH528070A patent/CH539520A/en not_active IP Right Cessation
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4280718A (en) | 1975-03-24 | 1981-07-28 | Henkel Corporation | Pressure sensitive recording sheet containing size classified cereal starch granules |
Also Published As
| Publication number | Publication date |
|---|---|
| FR2038318A1 (en) | 1971-01-08 |
| BE748429A (en) | 1970-09-16 |
| NL7005045A (en) | 1970-10-12 |
| CH539520A (en) | 1973-07-31 |
| ES378121A1 (en) | 1972-05-16 |
| DE2016483C2 (en) | 1986-08-28 |
| ZA702136B (en) | 1971-01-27 |
| SE362610B (en) | 1973-12-17 |
| DE2016483A1 (en) | 1970-10-15 |
| AT303765B (en) | 1972-12-11 |
| NO126840B (en) | 1973-04-02 |
| DK125538B (en) | 1973-03-05 |
| BR7018024D0 (en) | 1973-01-18 |
| CA989255A (en) | 1976-05-18 |
| NL146751B (en) | 1975-08-15 |
| JPS4833204B1 (en) | 1973-10-12 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed | ||
| 429A | Application made for amendment of specification (sect. 29/1949) | ||
| 433D | Application made for revocation (sect. 33/1949) | ||
| 433B | Case decided by the comptroller ** patent revoked (sect. 33/1949) |