GB1243959A - Method of extracting diolefins - Google Patents
Method of extracting diolefinsInfo
- Publication number
- GB1243959A GB1243959A GB1004670A GB1004670A GB1243959A GB 1243959 A GB1243959 A GB 1243959A GB 1004670 A GB1004670 A GB 1004670A GB 1004670 A GB1004670 A GB 1004670A GB 1243959 A GB1243959 A GB 1243959A
- Authority
- GB
- United Kingdom
- Prior art keywords
- solvent
- hydrocarbons
- extraction
- zone
- dienic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 150000001993 dienes Chemical class 0.000 title abstract 2
- 229930195733 hydrocarbon Natural products 0.000 abstract 12
- 150000002430 hydrocarbons Chemical class 0.000 abstract 12
- 239000002904 solvent Substances 0.000 abstract 12
- 238000000605 extraction Methods 0.000 abstract 11
- 239000012071 phase Substances 0.000 abstract 7
- 239000004215 Carbon black (E152) Substances 0.000 abstract 4
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 abstract 3
- 239000000203 mixture Substances 0.000 abstract 3
- YEJRWHAVMIAJKC-UHFFFAOYSA-N 4-Butyrolactone Chemical compound O=C1CCCO1 YEJRWHAVMIAJKC-UHFFFAOYSA-N 0.000 abstract 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 abstract 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 abstract 2
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 abstract 2
- 238000004064 recycling Methods 0.000 abstract 2
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 abstract 1
- GSNUFIFRDBKVIE-UHFFFAOYSA-N DMF Natural products CC1=CC=C(C)O1 GSNUFIFRDBKVIE-UHFFFAOYSA-N 0.000 abstract 1
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 abstract 1
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 abstract 1
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 abstract 1
- 238000009835 boiling Methods 0.000 abstract 1
- 229930188620 butyrolactone Natural products 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- CCAFPWNGIUBUSD-UHFFFAOYSA-N diethyl sulfoxide Chemical compound CCS(=O)CC CCAFPWNGIUBUSD-UHFFFAOYSA-N 0.000 abstract 1
- 229960001760 dimethyl sulfoxide Drugs 0.000 abstract 1
- 229940113088 dimethylacetamide Drugs 0.000 abstract 1
- 238000004821 distillation Methods 0.000 abstract 1
- XPFVYQJUAUNWIW-UHFFFAOYSA-N furfuryl alcohol Chemical compound OCC1=CC=CO1 XPFVYQJUAUNWIW-UHFFFAOYSA-N 0.000 abstract 1
- 239000007791 liquid phase Substances 0.000 abstract 1
- LYGJENNIWJXYER-UHFFFAOYSA-N nitromethane Chemical compound C[N+]([O-])=O LYGJENNIWJXYER-UHFFFAOYSA-N 0.000 abstract 1
- 239000012188 paraffin wax Substances 0.000 abstract 1
- 230000001737 promoting effect Effects 0.000 abstract 1
- 238000010992 reflux Methods 0.000 abstract 1
- 238000000926 separation method Methods 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C7/00—Purification; Separation; Use of additives
- C07C7/10—Purification; Separation; Use of additives by extraction, i.e. purification or separation of liquid hydrocarbons with the aid of liquids
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Analytical Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Water Supply & Treatment (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Extraction Or Liquid Replacement (AREA)
Abstract
1,243,959. Extracting diolefins. INSTITUT FRANCAIS DU PETROLE DES CARBURANTE ET LUBRIFIANTS.- 3 March, 1970 [3 March, 1969], No. 10046/70. Heading C5E. A method of extraction in liquid phase to isolate butadiene and/or isoprene from a mixture of hydrocarbons having 4 and/or 5 carbon atoms, of various degrees of saturation, comprising the introduction of said feedstock into a counter-current extraction zone, at at least one intermediate point of said zone, the introduction of a polar extraction solvent with the addition of from 0 to 20% of its weight of water, at a first end of said zone in extractive contact with said feedstock, the introduction of an apolar auxiliary solvent incapable of dissolving a substantial amount of extractive solvent, being of a density lower than said solvent, and having a boiling point higher than that of the mixture of hydrocarbons to be separated, promoting reflux, at the other end of said extraction zone, so as to form a first extract phase containing a greater amount of the dienic hydrocarbon or hydrocarbons and a first refined phase containing a reduced amount of dienic hydrocarbons, bringing into countercurrent contact in a second extraction zone, the first extract phase with the auxiliary solvent which is capable of dissolving the dienic hydrocarbon or hydrocarbons and incapable of dissolving a substantial amount of the extraction solvent, so as to form a second extract phase containing an increased amount of dienic hydrocarbon or hydrocarbons and a second refined phase containing a reduced amount of dienic hydrocarbons and an increased amount of extraction solvent, the separation by distillation of the dienic hydrocarbon or hydrocarbons and the auxiliary solvent present in the second extract phase, the recycling of the recuperated auxiliary solvent to one or both of the two extraction zones and the recycling of the second refined phase to the first extraction zone as first extraction solvent. The polar extraction solvent may be N-methylpyrrolidone, butyrolactone, DMF, acetonitrile, dimethyl acetamide, furfurol, nitromethane, diethyl sulphoxide or, preferably, dimethylsulphoxide. The apolar auxiliary solvent may be a C 5 -C 10 paraffin or cycloparaffin or mixture thereof, preferably cyclohexane.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR6905753A FR2036057A5 (en) | 1969-03-03 | 1969-03-03 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1243959A true GB1243959A (en) | 1971-08-25 |
Family
ID=9029967
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB1004670A Expired GB1243959A (en) | 1969-03-03 | 1970-03-03 | Method of extracting diolefins |
Country Status (5)
| Country | Link |
|---|---|
| JP (1) | JPS4941165B1 (en) |
| DE (1) | DE2009177A1 (en) |
| FR (1) | FR2036057A5 (en) |
| GB (1) | GB1243959A (en) |
| NL (1) | NL7003039A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0023370A1 (en) * | 1979-07-18 | 1981-02-04 | Shell Internationale Researchmaatschappij B.V. | Process for the recovery of isoprene, and isoprene so recovered |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5874815U (en) * | 1981-11-16 | 1983-05-20 | カシオ計算機株式会社 | Watch band mounting structure |
| FR3014098B1 (en) * | 2013-11-29 | 2018-08-10 | IFP Energies Nouvelles | PROCESS FOR EXTRACTING AND PURIFYING THE DIOLEFINS CONTAINED IN A MIXTURE OF HYDROCARBONS |
| FR3143602B1 (en) | 2022-12-20 | 2024-11-15 | Ifp Energies Now | Conversion of a hydrocarbon feedstock from biomass to produce adipic acid |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2441827A (en) * | 1943-10-27 | 1948-05-18 | Union Oil Co | Extraction process |
| US3050573A (en) * | 1957-12-06 | 1962-08-21 | Shell Oil Co | Extractive distillation |
| US3038016A (en) * | 1959-08-17 | 1962-06-05 | Phillips Petroleum Co | Isoprene separation |
-
1969
- 1969-03-03 FR FR6905753A patent/FR2036057A5/fr not_active Expired
-
1970
- 1970-02-27 DE DE19702009177 patent/DE2009177A1/en active Pending
- 1970-03-03 NL NL7003039A patent/NL7003039A/xx unknown
- 1970-03-03 GB GB1004670A patent/GB1243959A/en not_active Expired
- 1970-03-03 JP JP1770670A patent/JPS4941165B1/ja active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0023370A1 (en) * | 1979-07-18 | 1981-02-04 | Shell Internationale Researchmaatschappij B.V. | Process for the recovery of isoprene, and isoprene so recovered |
Also Published As
| Publication number | Publication date |
|---|---|
| FR2036057A5 (en) | 1970-12-24 |
| NL7003039A (en) | 1970-09-07 |
| DE2009177A1 (en) | 1970-09-10 |
| JPS4941165B1 (en) | 1974-11-07 |
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