GB1130245A - An improved process for the preparation of vinyl esters - Google Patents
An improved process for the preparation of vinyl estersInfo
- Publication number
- GB1130245A GB1130245A GB1518267A GB1518267A GB1130245A GB 1130245 A GB1130245 A GB 1130245A GB 1518267 A GB1518267 A GB 1518267A GB 1518267 A GB1518267 A GB 1518267A GB 1130245 A GB1130245 A GB 1130245A
- Authority
- GB
- United Kingdom
- Prior art keywords
- vinyl esters
- acids
- april
- aluminium
- iron
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920001567 vinyl ester resin Polymers 0.000 title abstract 3
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 title abstract 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract 4
- 150000001735 carboxylic acids Chemical class 0.000 abstract 3
- 239000002841 Lewis acid Substances 0.000 abstract 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 abstract 2
- 239000004411 aluminium Substances 0.000 abstract 2
- 229910052782 aluminium Inorganic materials 0.000 abstract 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract 2
- 229910052742 iron Inorganic materials 0.000 abstract 2
- 150000007517 lewis acids Chemical class 0.000 abstract 2
- 239000007791 liquid phase Substances 0.000 abstract 2
- 229910052751 metal Inorganic materials 0.000 abstract 2
- 239000002184 metal Substances 0.000 abstract 2
- 229910052725 zinc Inorganic materials 0.000 abstract 2
- 239000011701 zinc Substances 0.000 abstract 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 abstract 1
- 229910052684 Cerium Inorganic materials 0.000 abstract 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 abstract 1
- 229910000722 Didymium Inorganic materials 0.000 abstract 1
- 241000224487 Didymium Species 0.000 abstract 1
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 abstract 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 abstract 1
- 229910019142 PO4 Inorganic materials 0.000 abstract 1
- 229910052770 Uranium Inorganic materials 0.000 abstract 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 abstract 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 abstract 1
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 abstract 1
- 150000001559 benzoic acids Chemical class 0.000 abstract 1
- 229910052790 beryllium Inorganic materials 0.000 abstract 1
- ATBAMAFKBVZNFJ-UHFFFAOYSA-N beryllium atom Chemical compound [Be] ATBAMAFKBVZNFJ-UHFFFAOYSA-N 0.000 abstract 1
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 238000009835 boiling Methods 0.000 abstract 1
- 229910052796 boron Inorganic materials 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 abstract 1
- 229910052804 chromium Inorganic materials 0.000 abstract 1
- 239000011651 chromium Substances 0.000 abstract 1
- 125000002534 ethynyl group Chemical group [H]C#C* 0.000 abstract 1
- 229910052733 gallium Inorganic materials 0.000 abstract 1
- 150000004820 halides Chemical class 0.000 abstract 1
- 150000002531 isophthalic acids Chemical class 0.000 abstract 1
- 229910052744 lithium Inorganic materials 0.000 abstract 1
- 150000002739 metals Chemical class 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 229910052763 palladium Inorganic materials 0.000 abstract 1
- IPCSVZSSVZVIGE-UHFFFAOYSA-N palmitic acid group Chemical group C(CCCCCCCCCCCCCCC)(=O)O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 abstract 1
- 235000021317 phosphate Nutrition 0.000 abstract 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 abstract 1
- 238000003786 synthesis reaction Methods 0.000 abstract 1
- JFALSRSLKYAFGM-UHFFFAOYSA-N uranium(0) Chemical compound [U] JFALSRSLKYAFGM-UHFFFAOYSA-N 0.000 abstract 1
- 150000003751 zinc Chemical class 0.000 abstract 1
- -1 zinc carboxylate Chemical class 0.000 abstract 1
- 229910052726 zirconium Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/04—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/06—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of zinc, cadmium or mercury
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
Abstract
1,130,245. Vinyl esters. SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ N.V. 3 April, 1967 [5 April, 1966], No. 15182/67. Heading C2C. [Also in Division B1] Vinyl esters of carboxylic acids are prepared by reacting the carboxylic acid in the liquid phase with acetylene at between 200‹ and 300‹ C. in the presence of a zinc salt of the carboxylic acid and a metal-containing Lewis acid as catalysts. The liquid phase may be molten zinc carboxylate or a high-boiling solvent and the Lewis acids may be the halides, sulphates or phosphates of metals such as lithium, beryllium, zinc, palladium, boron, aluminium, gallium, cerium, iron, chromium, zirconium, or uranium, iron, aluminium and didymium or mixtures thereof. Acetic, propionic, isobutyric, pivalic, palmitic, stearic, benzoic, and isophthalic acids and those prepared by Koch synthesis (5-9 C) may be vinylated.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DES103040A DE1283228B (en) | 1966-04-05 | 1966-04-05 | Process for the preparation of vinyl esters |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1130245A true GB1130245A (en) | 1968-10-09 |
Family
ID=7524878
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB1518267A Expired GB1130245A (en) | 1966-04-05 | 1967-04-03 | An improved process for the preparation of vinyl esters |
Country Status (4)
| Country | Link |
|---|---|
| BE (1) | BE696487A (en) |
| DE (1) | DE1283228B (en) |
| GB (1) | GB1130245A (en) |
| NL (1) | NL157588B (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5430179A (en) * | 1994-07-28 | 1995-07-04 | Union Carbide Chemicals & Plastics Technology | Homogeneous process for the ruthenium catalyzed addition of carboxylic acids to alkynes |
| WO2010129029A3 (en) * | 2009-05-07 | 2011-01-13 | Celanese International Corporation | Vinyl ester production from acetylene and carboxylic acid utilizing heterogeneous catalyst |
| US8173830B2 (en) | 2009-05-07 | 2012-05-08 | Celanese International Corporation | Vinyl ester production from acetylene and carboxylic acid utilizing homogeneous catalyst |
| WO2019147515A1 (en) * | 2018-01-29 | 2019-08-01 | Exxonmobil Chemical Patents Inc. | Anaerobically biodegradable fluids for drilling applications |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2228365A (en) * | 1938-08-13 | 1941-01-14 | Gen Aniline & Film Corp | Process of producing vinyl esters |
| GB998648A (en) * | 1962-07-10 | 1965-07-21 | Shell Int Research | Process for the preparation of vinyl esters |
| DE1237557B (en) * | 1962-07-10 | 1967-03-30 | Shell Int Research | Process for the preparation of vinyl esters of saturated aliphatic monocarboxylic acids |
-
1966
- 1966-04-05 DE DES103040A patent/DE1283228B/en active Pending
-
1967
- 1967-04-03 BE BE696487D patent/BE696487A/xx unknown
- 1967-04-03 NL NL6704693A patent/NL157588B/en unknown
- 1967-04-03 GB GB1518267A patent/GB1130245A/en not_active Expired
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5430179A (en) * | 1994-07-28 | 1995-07-04 | Union Carbide Chemicals & Plastics Technology | Homogeneous process for the ruthenium catalyzed addition of carboxylic acids to alkynes |
| WO2010129029A3 (en) * | 2009-05-07 | 2011-01-13 | Celanese International Corporation | Vinyl ester production from acetylene and carboxylic acid utilizing heterogeneous catalyst |
| US7982065B2 (en) | 2009-05-07 | 2011-07-19 | Celanese International Corporation | Vinyl ester production from acetylene and carboxylic acid utilizing heterogeneous catalyst |
| CN102421743A (en) * | 2009-05-07 | 2012-04-18 | 塞拉尼斯国际公司 | Vinyl ester production from acetylene and carboxylic acid utilizing heterogeneous catalyst |
| US8173830B2 (en) | 2009-05-07 | 2012-05-08 | Celanese International Corporation | Vinyl ester production from acetylene and carboxylic acid utilizing homogeneous catalyst |
| CN102421743B (en) * | 2009-05-07 | 2016-05-04 | 塞拉尼斯国际公司 | Use heterogeneous catalysis to be prepared the method for vinyl esters by acetylene and carboxylic acid |
| WO2019147515A1 (en) * | 2018-01-29 | 2019-08-01 | Exxonmobil Chemical Patents Inc. | Anaerobically biodegradable fluids for drilling applications |
Also Published As
| Publication number | Publication date |
|---|---|
| NL157588B (en) | 1978-08-15 |
| NL6704693A (en) | 1967-10-06 |
| DE1283228B (en) | 1968-11-21 |
| BE696487A (en) | 1967-10-03 |
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