GB1121443A - A process for the preparation of lubricating oil fractions by hydrocracking of hydrocarbon oils - Google Patents
A process for the preparation of lubricating oil fractions by hydrocracking of hydrocarbon oilsInfo
- Publication number
- GB1121443A GB1121443A GB13785/66A GB1378566A GB1121443A GB 1121443 A GB1121443 A GB 1121443A GB 13785/66 A GB13785/66 A GB 13785/66A GB 1378566 A GB1378566 A GB 1378566A GB 1121443 A GB1121443 A GB 1121443A
- Authority
- GB
- United Kingdom
- Prior art keywords
- oil
- hydrogen
- reaction zone
- catalyst
- lubricating oil
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003921 oil Substances 0.000 title abstract 11
- 229930195733 hydrocarbon Natural products 0.000 title abstract 8
- 150000002430 hydrocarbons Chemical class 0.000 title abstract 8
- 239000004215 Carbon black (E152) Substances 0.000 title abstract 5
- 239000010687 lubricating oil Substances 0.000 title abstract 5
- 238000002360 preparation method Methods 0.000 title abstract 3
- 238000004517 catalytic hydrocracking Methods 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 9
- 239000001257 hydrogen Substances 0.000 abstract 9
- 229910052739 hydrogen Inorganic materials 0.000 abstract 9
- 238000006243 chemical reaction Methods 0.000 abstract 7
- 238000009835 boiling Methods 0.000 abstract 6
- 239000003054 catalyst Substances 0.000 abstract 5
- 239000007789 gas Substances 0.000 abstract 3
- 238000005984 hydrogenation reaction Methods 0.000 abstract 3
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 abstract 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 abstract 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 abstract 2
- 239000007795 chemical reaction product Substances 0.000 abstract 2
- 238000005336 cracking Methods 0.000 abstract 2
- 239000007788 liquid Substances 0.000 abstract 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 abstract 2
- 239000011541 reaction mixture Substances 0.000 abstract 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 abstract 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 abstract 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 abstract 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical class [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 abstract 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 1
- 229910017052 cobalt Inorganic materials 0.000 abstract 1
- 239000010941 cobalt Substances 0.000 abstract 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 abstract 1
- 229910052802 copper Inorganic materials 0.000 abstract 1
- 239000010949 copper Substances 0.000 abstract 1
- 239000011737 fluorine Substances 0.000 abstract 1
- 229910052731 fluorine Inorganic materials 0.000 abstract 1
- 239000000395 magnesium oxide Substances 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 229910052750 molybdenum Inorganic materials 0.000 abstract 1
- 239000011733 molybdenum Substances 0.000 abstract 1
- 229910052759 nickel Inorganic materials 0.000 abstract 1
- 229910017464 nitrogen compound Inorganic materials 0.000 abstract 1
- 150000002830 nitrogen compounds Chemical class 0.000 abstract 1
- 229910052763 palladium Inorganic materials 0.000 abstract 1
- 229910052697 platinum Inorganic materials 0.000 abstract 1
- 238000000926 separation method Methods 0.000 abstract 1
- 239000000377 silicon dioxide Substances 0.000 abstract 1
- 229910052709 silver Inorganic materials 0.000 abstract 1
- 239000004332 silver Substances 0.000 abstract 1
- 239000001117 sulphuric acid Substances 0.000 abstract 1
- 235000011149 sulphuric acid Nutrition 0.000 abstract 1
- 150000003568 thioethers Chemical class 0.000 abstract 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 abstract 1
- 229910052721 tungsten Inorganic materials 0.000 abstract 1
- 239000010937 tungsten Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G65/00—Treatment of hydrocarbon oils by two or more hydrotreatment processes only
- C10G65/02—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only
- C10G65/10—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including only cracking steps
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Catalysts (AREA)
- Lubricants (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
A process for the preparation of a lubricating oil fraction or fractions having a high viscosity index by hydrocracking of hydrocarbon oil having a boiling range at least partly above the final boiling point of lubricating oil comprises contacting the oil, in a first reaction zone and in the presence of hydrogen or a hydrogen-containing gas, at a temperature of between 250 DEG and 475 DEG C., a liquid hourly space velocity of from 0.4 to 5 litres of oil per hour per litre of catalyst, a pressure of from 50 to 500 atmospheres and an oil to hydrogen ratio of from 250 to 5,000 N litres of hydrogen per kilogram of oil, with a catalyst containing a hydrogenation component and an acid-acting cracking component, this contacting being carried out under such conditions that the percentage by weight of hydrocarbons having a boiling range of between 370 DEG and 525 DEG C. in the hydrocarbon mixture leaving the first reaction zone is at least 5 and at most 50 higher than the percentage by weight of the corresponding hydrocarbons in the hydrocarbon oil introduced into the first reaction zone; subsequently separating a hydrogen-containing gas and at least one hydrocarbon fraction having a final boiling point of between 370 DEG and 525 DEG C. from the reaction product; contacting at least part of the remaining reaction product, likewise in the presence of hydrogen or a hydrogen-containing gas, in a second reaction zone and at a temperature of from 325 DEG to 450 DEG C., a liquid hourly space velocity of from 0.2 to 5 litres of oil per hour per litre of catalyst, a pressure of from 50 to 500 atmospheres and a hydrogen to oil ratio of from 250 to 5,000 N litres of hydrogen per kilogram of oil, with a catalyst likewise containing a hydrogenation component and an acid-acting cracking component, this contacting being carried out under such conditions that the reaction mixture, when leaving the second reaction zone after the separation of normally gaseous components, contains 20 to 75% by weight of hydrocarbons having boiling points above 525 DEG C; and separating at least one lubricating oil fraction having a boiling range of between 370 DEG and 525 DEG C. from the reaction mixture of the second reaction zone. The feed stock may be pretreated to reduce the content of nitrogen compounds and carbonaceous components with sulphuric acid or by hydrogenation. Sulphur compounds such as hydrogen sulphide may be added to the feedstock in the first and/or second reaction zone. The catalyst in both zones may comprise cobalt, nickel, tungsten, molybdenum, platinum, palladium, copper and/or silver and/or the sulphides and/or oxides thereof supported on silica, alumina, magnesia, zirconia, titania and/or boria and may also contain a small amount of fluorine. An example describes the preparation of lubricating oil from a residual oil.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NL656504066A NL144326B (en) | 1965-03-31 | 1965-03-31 | METHOD FOR HYDROGENATING CRACKING OF A HYDROCARBON OIL. |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1121443A true GB1121443A (en) | 1968-07-24 |
Family
ID=19792799
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB13785/66A Expired GB1121443A (en) | 1965-03-31 | 1966-03-29 | A process for the preparation of lubricating oil fractions by hydrocracking of hydrocarbon oils |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US3444071A (en) |
| BE (1) | BE678609A (en) |
| CH (1) | CH479687A (en) |
| DE (1) | DE1276264B (en) |
| ES (1) | ES324827A1 (en) |
| GB (1) | GB1121443A (en) |
| NL (1) | NL144326B (en) |
| NO (1) | NO115222B (en) |
| SE (1) | SE308936B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5358628A (en) * | 1990-07-05 | 1994-10-25 | Mobil Oil Corporation | Production of high viscosity index lubricants |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3617484A (en) * | 1968-11-29 | 1971-11-02 | Sun Oil Co | Increasing the v.i. of hydrocracked light lubes |
| BE754805A (en) * | 1969-09-05 | 1971-02-15 | Atlantic Richfield Co | PERFECTED PROCESS FOR PREPARATION OF LUBRICATING MINERAL OIL FROM NEW RAW MATERIALS |
| US3617482A (en) * | 1969-11-10 | 1971-11-02 | Chevron Res | Process for the production of lubricating oils |
| US3666657A (en) * | 1970-11-16 | 1972-05-30 | Sun Oil Co Pennsylvania | Oil stabilizing sequential hydrocracking and hydrogenation treatment |
| US3992283A (en) * | 1974-09-23 | 1976-11-16 | Universal Oil Products Company | Hydrocracking process for the maximization of an improved viscosity lube oil |
| US4743355A (en) * | 1979-10-15 | 1988-05-10 | Union Oil Company Of California | Process for producing a high quality lube oil stock |
| US4743354A (en) * | 1979-10-15 | 1988-05-10 | Union Oil Company Of California | Process for producing a product hydrocarbon having a reduced content of normal paraffins |
| US4419271A (en) * | 1979-10-15 | 1983-12-06 | Union Oil Company Of California | Hydrocarbon conversion catalyst |
| US4592828A (en) * | 1984-05-07 | 1986-06-03 | Mobil Oil Corporation | Process for upgrading petroleum residua |
| US5250588A (en) * | 1990-01-16 | 1993-10-05 | Ceram Sna Inc. | Organic friction material composition for use to produce friction linings |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3047490A (en) * | 1958-11-04 | 1962-07-31 | Phillips Petroleum Co | Hydrocracking process |
| FR1327395A (en) * | 1962-05-29 | 1963-05-17 | California Research Corp | Process for the hydrogenating cracking of petroleum hydrocarbons |
| US3242068A (en) * | 1962-12-24 | 1966-03-22 | Chevron Res | Production of lubricating oil |
| US3308055A (en) * | 1964-04-13 | 1967-03-07 | Chevron Res | Hydrocracking process producing lubricating oil |
-
1965
- 1965-03-31 NL NL656504066A patent/NL144326B/en unknown
-
1966
- 1966-03-18 US US535354A patent/US3444071A/en not_active Expired - Lifetime
- 1966-03-29 NO NO162334A patent/NO115222B/no unknown
- 1966-03-29 ES ES0324827A patent/ES324827A1/en not_active Expired
- 1966-03-29 DE DES102875A patent/DE1276264B/en active Pending
- 1966-03-29 CH CH455566A patent/CH479687A/en not_active IP Right Cessation
- 1966-03-29 SE SE4170/66A patent/SE308936B/xx unknown
- 1966-03-29 GB GB13785/66A patent/GB1121443A/en not_active Expired
- 1966-03-29 BE BE678609D patent/BE678609A/xx unknown
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5358628A (en) * | 1990-07-05 | 1994-10-25 | Mobil Oil Corporation | Production of high viscosity index lubricants |
Also Published As
| Publication number | Publication date |
|---|---|
| SE308936B (en) | 1969-03-03 |
| CH479687A (en) | 1969-10-15 |
| BE678609A (en) | 1966-09-29 |
| DE1276264B (en) | 1968-08-29 |
| US3444071A (en) | 1969-05-13 |
| NO115222B (en) | 1968-09-02 |
| NL6504066A (en) | 1966-10-03 |
| ES324827A1 (en) | 1967-02-16 |
| NL144326B (en) | 1974-12-16 |
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