GB1120033A - The preparation of í¸-pyrrolin-2-carboxylic acid - Google Patents
The preparation of í¸-pyrrolin-2-carboxylic acidInfo
- Publication number
- GB1120033A GB1120033A GB3287364A GB3287364A GB1120033A GB 1120033 A GB1120033 A GB 1120033A GB 3287364 A GB3287364 A GB 3287364A GB 3287364 A GB3287364 A GB 3287364A GB 1120033 A GB1120033 A GB 1120033A
- Authority
- GB
- United Kingdom
- Prior art keywords
- carboxylic acid
- acid
- water
- pyrrolin
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- WRHZVMBBRYBTKZ-UHFFFAOYSA-N pyrrole-2-carboxylic acid Chemical compound OC(=O)C1=CC=CN1 WRHZVMBBRYBTKZ-UHFFFAOYSA-N 0.000 abstract 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 3
- 239000002253 acid Substances 0.000 abstract 2
- 239000003960 organic solvent Substances 0.000 abstract 2
- OMGHIGVFLOPEHJ-UHFFFAOYSA-N 2,5-dihydro-1h-pyrrol-1-ium-2-carboxylate Chemical compound OC(=O)C1NCC=C1 OMGHIGVFLOPEHJ-UHFFFAOYSA-N 0.000 abstract 1
- YZCKVEUIGOORGS-UHFFFAOYSA-N Hydrogen atom Chemical group [H] YZCKVEUIGOORGS-UHFFFAOYSA-N 0.000 abstract 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 abstract 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 abstract 1
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- ACVYVLVWPXVTIT-UHFFFAOYSA-N phosphinic acid Chemical compound O[PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-N 0.000 abstract 1
- 229910052725 zinc Inorganic materials 0.000 abstract 1
- 239000011701 zinc Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D207/00—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom
- C07D207/02—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D207/18—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having one double bond between ring members or between a ring member and a non-ring member
- C07D207/22—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having one double bond between ring members or between a ring member and a non-ring member with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Pyrrole Compounds (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
D 3-Pyrroline-2-carboxylic acid is prepared by reduction of 2-pyrrole carboxylic acid by reacting the latter acid with hydriodic acid and hypophosphorous acid, in the presence of water or a mixture of water and an organic solvent which is inert under the reaction conditions and miscible with water, or by reacting 2-pyrrole carboxylic acid with nascent hydrogen form from a hydrohalic acid and a suitable metal such as zinc or tin, in the presence of an organic solvent.
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB3287364A GB1120033A (en) | 1964-08-12 | 1964-08-12 | The preparation of í¸-pyrrolin-2-carboxylic acid |
| DE19651620163 DE1620163A1 (en) | 1964-08-12 | 1965-08-10 | Process for the preparation of delta? -Pyrroline-2-carboxylic acid |
| FR27854A FR1462259A (en) | 1964-08-12 | 1965-08-10 | Process for preparing delta3-pyrroline-2-carboxylic acid |
| CH1134565A CH449621A (en) | 1964-08-12 | 1965-08-12 | Process for the preparation of 3-pyrroline-2-carboxylic acid |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB3287364A GB1120033A (en) | 1964-08-12 | 1964-08-12 | The preparation of í¸-pyrrolin-2-carboxylic acid |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1120033A true GB1120033A (en) | 1968-07-17 |
Family
ID=10345295
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB3287364A Expired GB1120033A (en) | 1964-08-12 | 1964-08-12 | The preparation of í¸-pyrrolin-2-carboxylic acid |
Country Status (3)
| Country | Link |
|---|---|
| CH (1) | CH449621A (en) |
| DE (1) | DE1620163A1 (en) |
| GB (1) | GB1120033A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6124472A (en) * | 1996-07-26 | 2000-09-26 | Basf Aktiengesellschaft | Process for preparing 3-pyrroline-2-carboxylic acid derivatives |
-
1964
- 1964-08-12 GB GB3287364A patent/GB1120033A/en not_active Expired
-
1965
- 1965-08-10 DE DE19651620163 patent/DE1620163A1/en active Pending
- 1965-08-12 CH CH1134565A patent/CH449621A/en unknown
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6124472A (en) * | 1996-07-26 | 2000-09-26 | Basf Aktiengesellschaft | Process for preparing 3-pyrroline-2-carboxylic acid derivatives |
Also Published As
| Publication number | Publication date |
|---|---|
| DE1620163A1 (en) | 1970-02-19 |
| CH449621A (en) | 1968-01-15 |
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