GB1119133A - Sizing staple fiber yarns containing cellulosic and/or acrylic fibers - Google Patents
Sizing staple fiber yarns containing cellulosic and/or acrylic fibersInfo
- Publication number
- GB1119133A GB1119133A GB4622/67A GB462267A GB1119133A GB 1119133 A GB1119133 A GB 1119133A GB 4622/67 A GB4622/67 A GB 4622/67A GB 462267 A GB462267 A GB 462267A GB 1119133 A GB1119133 A GB 1119133A
- Authority
- GB
- United Kingdom
- Prior art keywords
- sizing
- weight
- monomers
- acrylic
- fibres
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000004513 sizing Methods 0.000 title abstract 7
- 229920002972 Acrylic fiber Polymers 0.000 title abstract 5
- 239000000835 fiber Substances 0.000 title abstract 2
- 239000000178 monomer Substances 0.000 abstract 5
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 abstract 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 abstract 4
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 abstract 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 4
- 239000007864 aqueous solution Substances 0.000 abstract 4
- 229920000642 polymer Polymers 0.000 abstract 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 abstract 3
- 150000003863 ammonium salts Chemical class 0.000 abstract 3
- 239000000203 mixture Substances 0.000 abstract 3
- 229910052708 sodium Inorganic materials 0.000 abstract 3
- 239000011734 sodium Substances 0.000 abstract 3
- 229920000742 Cotton Polymers 0.000 abstract 2
- 229920000297 Rayon Polymers 0.000 abstract 2
- 229920002472 Starch Polymers 0.000 abstract 2
- 239000003795 chemical substances by application Substances 0.000 abstract 2
- 229920001577 copolymer Polymers 0.000 abstract 2
- 238000007334 copolymerization reaction Methods 0.000 abstract 2
- 239000002964 rayon Substances 0.000 abstract 2
- 235000019698 starch Nutrition 0.000 abstract 2
- 239000008107 starch Substances 0.000 abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 2
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 abstract 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 abstract 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 abstract 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 abstract 1
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 abstract 1
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 abstract 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 abstract 1
- 229910052783 alkali metal Inorganic materials 0.000 abstract 1
- 150000001340 alkali metals Chemical class 0.000 abstract 1
- 239000000908 ammonium hydroxide Substances 0.000 abstract 1
- WPKYZIPODULRBM-UHFFFAOYSA-N azane;prop-2-enoic acid Chemical compound N.OC(=O)C=C WPKYZIPODULRBM-UHFFFAOYSA-N 0.000 abstract 1
- 238000001035 drying Methods 0.000 abstract 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 abstract 1
- 239000011976 maleic acid Substances 0.000 abstract 1
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract 1
- 238000006386 neutralization reaction Methods 0.000 abstract 1
- 229920000728 polyester Polymers 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 239000000243 solution Substances 0.000 abstract 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/31—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated nitriles
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
- Woven Fabrics (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
A composition for sizing staple yarns consists of, or contains, a polymer consisting of copolymerized units of (a) acrylonitrile, and (b) acrylic acid and its sodium or ammonium salt in the molar ratio of (a) : (b) of 1 : 1.5 to 1 : 7 and which, as determined in a 10% by weight aqueous solution at 20 DEG C. has a viscosity of 20 to 2000 c.p. and a pH value of 2.5 to 6.5, the said polymer containing from 0 to 20% by weight of copolymerized units of other monomers, said monomers being soluble in water at 20 DEG C. in an amount of at least 2% by weight. The other monomers employed are e.g. acrylamide, methacrylamide, methyl, acrylate, methacrylic acid or its alkali metal or ammonium salts, maleic acid or its salts or semi-esters, methacrylonitrile and vinyl pyrrolidone. The copolymers are prepared in aqueous solution by copolymerization of acrylonitrile and acrylic acid followed by partial neutralization of the copolymer with ammonium or sodium hydroxide, or by copolymerization of acrylonitrile, acrylic acid and sodium or ammonium acrylate. The aqueous solutions produced are used, after the addition, if desired, of conventional sizing agents such as the starch ether employed in Example 7, for the sizing of cellulosic and/or acrylic fibres (see Division D1).ALSO:A process for sizing staple yarns consisting of cellulosic fibres and/or acrylic fibres, or containing at least 30% by weight thereof, comprises applying to the fibres an aqueous liquor which contains in solution a polymer containing copolymerised units of (a) acrylonitrile and (b) acrylic acid and its sodium or ammonium salt and drying and treated yarn, the said polymer containing units of (a) and (b) in the molar ratio of from 1:1.5 to 1:7 and, as determined in a 10% by weight aqueous solution at 20 DEG C., having a viscosity of 20 to 2000 cp and a pH value of 2.5 to 6.5, and containing 0 to 20% by weight of copolymerised units of other monomers, said monomers being soluble in water at 20 DEG C. in an amount of at least 2% by weight. The sizing liquor may contain conventional agents e.g. the starch ether employed in Example 7. In the examples the sizing liquors are applied to cotton yarn, red-dyed acrylic fibres, pale blue rayon staple/acrylic fibre blend yarns, linen warps, staple rayon yarns and polyester fibre/cotton blend yarns.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE1594905A DE1594905C3 (en) | 1966-02-01 | 1966-02-01 | Use of water-soluble polymers as sizing agents |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1119133A true GB1119133A (en) | 1968-07-10 |
Family
ID=6983000
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB4622/67A Expired GB1119133A (en) | 1966-02-01 | 1967-01-31 | Sizing staple fiber yarns containing cellulosic and/or acrylic fibers |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US3519477A (en) |
| AT (1) | AT269797B (en) |
| BE (1) | BE693351A (en) |
| CH (1) | CH467376A (en) |
| DE (1) | DE1594905C3 (en) |
| FR (1) | FR1603324A (en) |
| GB (1) | GB1119133A (en) |
| NL (1) | NL142211B (en) |
| SE (1) | SE330679B (en) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3770494A (en) * | 1969-12-18 | 1973-11-06 | Asahi Chemical Ind | Modified acrylonitrile polymer fibers |
| US3844825A (en) * | 1972-11-30 | 1974-10-29 | American Cyanamid Co | Method of producing an acrylic fiber having an improved touch like animal hair |
| DE2714897C3 (en) * | 1977-04-02 | 1981-12-03 | Basf Ag, 6700 Ludwigshafen | Use of water-soluble alkaline earth salts of polymers of acrylic acid or methacrylic acid as sizing agents |
| DE2926230C2 (en) * | 1979-06-29 | 1986-07-03 | Basf Ag, 6700 Ludwigshafen | Method for sizing staple fiber yarns |
| JPS60120773A (en) * | 1983-12-01 | 1985-06-28 | Matsumoto Yushi Seiyaku Kk | Neutralizing agent for alkali-gelatinized starch paste |
| DE4029348A1 (en) * | 1990-09-15 | 1992-03-19 | Basf Ag | USE OF WATER-SOLUBLE OR WATER-DISPERSIBLE GRAFTED PROTEINS AS A FINISHING AGENT |
| US5208075A (en) * | 1990-09-15 | 1993-05-04 | Basf Aktiengesellschaft | Sizing agent for staple fiber and filament yarns |
| US8419991B2 (en) * | 2004-09-21 | 2013-04-16 | Cordenka Gmbh & Co. Kg | Free-flowing pellets based on cellulose textile fibers and a method for the production thereof |
| CN102839476B (en) * | 2012-09-25 | 2014-12-03 | 江苏恒州特种玻璃纤维材料有限公司 | Production process of high-strength high-silicon dioxide glass fiber yarns |
| CN108330687B (en) * | 2018-01-29 | 2020-09-18 | 西安工程大学 | Hot-melt textile size preparation method based on bulk polymerization method |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2819189A (en) * | 1954-11-15 | 1958-01-07 | American Cyanamid Co | Process of sizing textile yarn and product thereof |
-
1966
- 1966-02-01 DE DE1594905A patent/DE1594905C3/en not_active Expired
-
1967
- 1967-01-10 CH CH30667A patent/CH467376A/en unknown
- 1967-01-25 NL NL676701186A patent/NL142211B/en not_active IP Right Cessation
- 1967-01-27 FR FR1603324D patent/FR1603324A/en not_active Expired
- 1967-01-30 BE BE693351D patent/BE693351A/xx not_active IP Right Cessation
- 1967-01-31 GB GB4622/67A patent/GB1119133A/en not_active Expired
- 1967-01-31 US US612811A patent/US3519477A/en not_active Expired - Lifetime
- 1967-02-01 SE SE01439/67A patent/SE330679B/xx unknown
- 1967-02-01 AT AT94967A patent/AT269797B/en active
Also Published As
| Publication number | Publication date |
|---|---|
| NL6701186A (en) | 1967-08-02 |
| DE1594905B2 (en) | 1973-11-08 |
| DE1594905A1 (en) | 1969-08-28 |
| CH467376A (en) | 1969-02-28 |
| AT269797B (en) | 1969-04-10 |
| NL142211B (en) | 1974-05-15 |
| SE330679B (en) | 1970-11-30 |
| FR1603324A (en) | 1971-04-05 |
| DE1594905C3 (en) | 1979-07-05 |
| CH30667A4 (en) | 1968-08-30 |
| BE693351A (en) | 1967-07-31 |
| US3519477A (en) | 1970-07-07 |
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