[go: up one dir, main page]

GB1117336A - Production of peracetic acid - Google Patents

Production of peracetic acid

Info

Publication number
GB1117336A
GB1117336A GB46105/65A GB4610565A GB1117336A GB 1117336 A GB1117336 A GB 1117336A GB 46105/65 A GB46105/65 A GB 46105/65A GB 4610565 A GB4610565 A GB 4610565A GB 1117336 A GB1117336 A GB 1117336A
Authority
GB
United Kingdom
Prior art keywords
amount
peracetic acid
acid solution
active oxygen
hydrogen peroxide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB46105/65A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
FMC Corp
Original Assignee
FMC Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by FMC Corp filed Critical FMC Corp
Publication of GB1117336A publication Critical patent/GB1117336A/en
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24—Stationary reactors without moving elements inside
    • B01J19/2415—Tubular reactors
    • B01J19/243—Tubular reactors spirally, concentrically or zigzag wound
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J14/00—Chemical processes in general for reacting liquids with liquids; Apparatus specially adapted therefor
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C407/00—Preparation of peroxy compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00054—Controlling or regulating the heat exchange system
    • B01J2219/00056—Controlling or regulating the heat exchange system involving measured parameters
    • B01J2219/00069—Flow rate measurement
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
    • B01J2219/00087—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor
    • B01J2219/00099—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor the reactor being immersed in the heat exchange medium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00162—Controlling or regulating processes controlling the pressure
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00164—Controlling or regulating processes controlling the flow
    • B01J2219/00166—Controlling or regulating processes controlling the flow controlling the residence time inside the reactor vessel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00177—Controlling or regulating processes controlling the pH

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)

Abstract

An aqueous peracetic acid solution having a concentration of 0.5-7.0% by wt. of peracid, a pH of 5.4-7.0 and free from deleterious amounts of diacetyl peroxide, is prepared by continuously introducing into a tubular reaction zone, under an even, pulse-free pressure at a rate to produce turbulent flow designated by a Reynolds number of 5000-30,000 and a residence time of 30 seconds-5 mins., at 80-140 DEG F., the following reactants, (a) aqueous hydrogen peroxide in an amount to provide an active oxygen concentration of 0.8-12.0 vols, (b) acetic anhydride in an amount to provide an anhydride : hydrogen peroxide molar ratio of 1.0-1.16:1, and (c) a basic catalyst compatible with active oxygen in an amount to provide a pH in the reaction mixture of 5.4-7.0, and continuously withdrawing the peracetic acid solution from the reaction zone. The preferred catalyst is ammonium hydroxide The process is preferably effected in a water-cooled tubular reactor which is illustrated in drawings (not shown).
GB46105/65A 1964-11-03 1965-11-01 Production of peracetic acid Expired GB1117336A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US40848664A 1964-11-03 1964-11-03

Publications (1)

Publication Number Publication Date
GB1117336A true GB1117336A (en) 1968-06-19

Family

ID=23616479

Family Applications (2)

Application Number Title Priority Date Filing Date
GB30260/67A Expired GB1117337A (en) 1964-11-03 1965-11-01 Apparatus for production of peracetic acid
GB46105/65A Expired GB1117336A (en) 1964-11-03 1965-11-01 Production of peracetic acid

Family Applications Before (1)

Application Number Title Priority Date Filing Date
GB30260/67A Expired GB1117337A (en) 1964-11-03 1965-11-01 Apparatus for production of peracetic acid

Country Status (10)

Country Link
US (1) US3432546A (en)
AT (1) AT265229B (en)
BE (1) BE671777A (en)
CH (1) CH471067A (en)
DE (1) DE1289524B (en)
ES (1) ES319142A1 (en)
FI (1) FI42711B (en)
GB (2) GB1117337A (en)
NL (1) NL6513939A (en)
SE (1) SE324758B (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2495215A3 (en) * 2006-10-18 2012-10-24 Mitsubishi Gas Chemical Company, Inc. Process for producing monopersulfuric acid and monopersulfuric acid continuous production apparatus
AU2012201470B2 (en) * 2006-10-18 2013-10-24 Mitsubishi Gas Chemical Company, Inc. Method for producing peroxymonosulfuric acid and apparatus for continuously producing peroxymonosulfuric acid
US20180042231A1 (en) * 2016-08-12 2018-02-15 Eltron Water Systems, LLC Systems and Methods for the Continuous On-Site Production of Peroxycarboxcylic Acid Solutions

Families Citing this family (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2462425A1 (en) * 1979-08-01 1981-02-13 Air Liquide METHOD FOR MANUFACTURING STABLE DILUTED SOLUTIONS OF ALIPHATIC CARBOXYLIC PERACIDS
GB8628441D0 (en) * 1986-11-27 1986-12-31 Unilever Plc Disinfectant dilution
US5977403A (en) * 1997-08-04 1999-11-02 Fmc Corporation Method for the production of lower organic peracids
WO2009023492A2 (en) * 2007-08-10 2009-02-19 Fmc Corporation Dilute stabilized peracetic acid production and treatment process
EP2620413B1 (en) * 2007-12-28 2020-07-01 3M Innovative Properties Company Continuous hydrothermal reactor system comprising a fluorinated polymer tubular reactor
US20100113692A1 (en) * 2008-11-04 2010-05-06 Mcguire Jr James E Apparatus for Continuous Production of Partially Polymerized Compositions
US8858895B2 (en) * 2010-12-29 2014-10-14 Ecolab Usa Inc. Continuous on-line adjustable disinfectant/sanitizer/bleach generator
WO2012090124A2 (en) 2010-12-29 2012-07-05 Ecolab Usa Inc. IN SITU GENERATION OF PEROXYCARBOXYLIC ACIDS AT ALKALINE pH, AND METHODS OF USE THEREOF
WO2012090125A2 (en) 2010-12-29 2012-07-05 Ecolab Usa Inc. Sugar ester peracid on-site generator and formulator
ES2553431T3 (en) 2011-03-24 2015-12-09 Enviro Tech Chemical Services Inc. Methods and compositions for the generation of peracetic acid at the site at the point of use
US8546449B2 (en) 2011-03-24 2013-10-01 Enviro Tech Chemical Services, Inc. Methods and compositions for the generation of peracetic acid on site at the point-of-use
US9321664B2 (en) 2011-12-20 2016-04-26 Ecolab Usa Inc. Stable percarboxylic acid compositions and uses thereof
US9242879B2 (en) 2012-03-30 2016-01-26 Ecolab Usa Inc. Use of peracetic acid/hydrogen peroxide and peroxide-reducing agents for treatment of drilling fluids, frac fluids, flowback water and disposal water
US10165774B2 (en) 2013-03-05 2019-01-01 Ecolab Usa Inc. Defoamer useful in a peracid composition with anionic surfactants
US8822719B1 (en) 2013-03-05 2014-09-02 Ecolab Usa Inc. Peroxycarboxylic acid compositions suitable for inline optical or conductivity monitoring
US20140256811A1 (en) 2013-03-05 2014-09-11 Ecolab Usa Inc. Efficient stabilizer in controlling self accelerated decomposition temperature of peroxycarboxylic acid compositions with mineral acids
CA2971411C (en) 2014-12-18 2022-03-22 Ecolab Usa Inc. Generation of peroxyformic acid through polyhydric alcohol formate
CA2971416C (en) 2014-12-18 2024-01-23 Ecolab Usa Inc. Methods for forming peroxyformic acid and uses thereof
US11040902B2 (en) 2014-12-18 2021-06-22 Ecolab Usa Inc. Use of percarboxylic acids for scale prevention in treatment systems
CN105541688B (en) * 2016-01-19 2018-03-09 黎明化工研究设计院有限责任公司 A kind of method for synthesizing high concentration anhydrous peroxyacetic acid solution coproduction acetylurea
US9907305B2 (en) 2016-03-22 2018-03-06 Solvay Sa Production of disinfecting solutions
EP3454914A4 (en) 2016-05-13 2020-03-11 Eltron Research&Development, LLC Process for the continuous on-site production of percarboxycilic acid solutions and device for its implementation
CA3103876C (en) 2018-06-15 2024-02-27 Ecolab Usa Inc. On site generated performic acid compositions for teat treatment
WO2020041545A1 (en) 2018-08-22 2020-02-27 Ecolab Usa Inc. Hydrogen peroxide and peracid stabilization with molecules based on a pyridine carboxylic acid at c-3, -4 or -5
WO2021026410A1 (en) 2019-08-07 2021-02-11 Ecolab Usa Inc. Polymeric and solid-supported chelators for stabilization of peracid-containing compositions
CN111233728A (en) * 2020-03-18 2020-06-05 中国天辰工程有限公司 A kind of method for rapidly preparing high-concentration peracetic acid
CN111333559A (en) * 2020-03-18 2020-06-26 中国天辰工程有限公司 A kind of method for continuous flow rapid preparation of peracetic acid

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2314385A (en) * 1940-02-21 1943-03-23 Celanese Corp Preparation of aliphatic peracids by oxidation of aldehydes
NL102493C (en) * 1940-07-08
US2377038A (en) * 1941-09-15 1945-05-29 Du Pont Manufacture of peracids
AT203454B (en) * 1956-06-15 1959-05-25 Haemmerle Fa F M Process for the acidic peroxide bleaching of textile fibers
GB803159A (en) * 1956-07-31 1958-10-22 Union Carbide Corp Process for producing peracids from aliphatic carboxylic acids
DE1158956B (en) * 1957-11-25 1963-12-12 Degussa Process for the production of peracetic acid or its salts containing aqueous bleaching solutions
NL289739A (en) * 1962-03-08

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2495215A3 (en) * 2006-10-18 2012-10-24 Mitsubishi Gas Chemical Company, Inc. Process for producing monopersulfuric acid and monopersulfuric acid continuous production apparatus
AU2012201470B2 (en) * 2006-10-18 2013-10-24 Mitsubishi Gas Chemical Company, Inc. Method for producing peroxymonosulfuric acid and apparatus for continuously producing peroxymonosulfuric acid
AU2012201470A8 (en) * 2006-10-18 2013-10-31 Mitsubishi Gas Chemical Company, Inc. Method for producing peroxymonosulfuric acid and apparatus for continuously producing peroxymonosulfuric acid
AU2012201470B8 (en) * 2006-10-18 2013-10-31 Mitsubishi Gas Chemical Company, Inc. Method for producing peroxymonosulfuric acid and apparatus for continuously producing peroxymonosulfuric acid
US9181094B2 (en) 2006-10-18 2015-11-10 Mitsubishi Gas Chemical Company, Inc. Method for producing peroxymonosulfuric acid and apparatus for continuously producing peroxymonosulfuric acid
US9988269B2 (en) 2006-10-18 2018-06-05 Mitsubishi Gas Chemical Co., Inc. Method for producing peroxymonosulfuric acid and apparatus for continuously producing peroxymonosulfuric acid
US20180042231A1 (en) * 2016-08-12 2018-02-15 Eltron Water Systems, LLC Systems and Methods for the Continuous On-Site Production of Peroxycarboxcylic Acid Solutions

Also Published As

Publication number Publication date
NL6513939A (en) 1966-05-04
CH471067A (en) 1969-05-30
AT265229B (en) 1968-10-10
ES319142A1 (en) 1966-08-01
DE1289524B (en) 1969-02-20
SE324758B (en) 1970-06-15
US3432546A (en) 1969-03-11
GB1117337A (en) 1968-06-19
BE671777A (en) 1966-03-01
FI42711B (en) 1970-06-30

Similar Documents

Publication Publication Date Title
GB1117336A (en) Production of peracetic acid
GB630286A (en) Manufacture of peroxides
GB1070322A (en) Process for the preparation of 6-formyloxy caproic acids and derivatives thereof
GR3002689T3 (en) Process for producing 2-methyl-1,4-naphthoquinone
GB1135875A (en) Process for the production of diphenols
GB1463050A (en) Process for the manufacture of bromine
GB1259968A (en) Preparation of straight chain dicarboxylic acids
ES447413A1 (en) Process for the preparation of perpropionic acid solutions
FR2500453B1 (en)
ES372033A1 (en) Preparation of peracetic acid by oxidation of acetaldehyde
GB646102A (en) Manufacture of organic oxidation products
GB1421876A (en) Process for the continuous detoxification of cyanides
GB955421A (en) Improvements in and relating to the oxidation of aldehydes
GB975715A (en) A process for the preparation of solutions of pure percarboxylic acids
GB1167955A (en) Controlling Continuous Reactions Between Gases and Liquids.
GB1423028A (en) Acid calcium cis-epoxy-succinate and its production
GB1178746A (en) Process of producing Acrylonitrile
GB1282775A (en) Improvements in or relating to the preparation of terephthalic acid
ES287874A1 (en) Process for making cyclohexanoneoxime
GB1428739A (en) Process for the production of formaldehyde
GB1351632A (en) Process for the preparation of bis-4-aminophenyl-methane
GB1369131A (en) Production of trioxane
GB978267A (en) Process for the production of unsaturated aliphatic nitriles
US3499924A (en) Process for the manufacture of anhydrous solutions of peracetic acid
GB1347943A (en) Process for producing fibre grade terephthalic acid