GB1115456A - Antistatic polyolefine mixtures - Google Patents
Antistatic polyolefine mixturesInfo
- Publication number
- GB1115456A GB1115456A GB4253165A GB4253165A GB1115456A GB 1115456 A GB1115456 A GB 1115456A GB 4253165 A GB4253165 A GB 4253165A GB 4253165 A GB4253165 A GB 4253165A GB 1115456 A GB1115456 A GB 1115456A
- Authority
- GB
- United Kingdom
- Prior art keywords
- alkyl
- carbon atoms
- alkenyl
- compositions
- polyethylene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000203 mixture Substances 0.000 title abstract 5
- 229920000098 polyolefin Polymers 0.000 title abstract 3
- -1 ethylene, propylene Chemical group 0.000 abstract 6
- 125000004432 carbon atom Chemical group C* 0.000 abstract 4
- 239000004698 Polyethylene Substances 0.000 abstract 3
- 125000003342 alkenyl group Chemical group 0.000 abstract 3
- 125000000217 alkyl group Chemical group 0.000 abstract 3
- 239000002216 antistatic agent Substances 0.000 abstract 3
- 229920000573 polyethylene Polymers 0.000 abstract 3
- XFGJTWBJZDMEJE-UHFFFAOYSA-N 1-[2-[2-[2-[2-[2-(2-hydroxyethoxy)ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]-2-phenylundecan-2-ol Chemical compound C(CCCCCCCC)C(COCCOCCOCCOCCOCCOCCO)(C1=CC=CC=C1)O XFGJTWBJZDMEJE-UHFFFAOYSA-N 0.000 abstract 2
- AGPGSIQLOWCTLV-UHFFFAOYSA-N 1-[2-[2-[2-[2-[2-(2-hydroxyethoxy)ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]tetradecan-2-ol Chemical compound C(CCCCCCCCCCC)C(COCCOCCOCCOCCOCCOCCO)O AGPGSIQLOWCTLV-UHFFFAOYSA-N 0.000 abstract 2
- 239000004743 Polypropylene Substances 0.000 abstract 2
- 125000002252 acyl group Chemical group 0.000 abstract 2
- 125000002947 alkylene group Chemical group 0.000 abstract 2
- 125000003118 aryl group Chemical group 0.000 abstract 2
- JXLHNMVSKXFWAO-UHFFFAOYSA-N azane;7-fluoro-2,1,3-benzoxadiazole-4-sulfonic acid Chemical compound N.OS(=O)(=O)C1=CC=C(F)C2=NON=C12 JXLHNMVSKXFWAO-UHFFFAOYSA-N 0.000 abstract 2
- 229920001577 copolymer Polymers 0.000 abstract 2
- 229910052739 hydrogen Inorganic materials 0.000 abstract 2
- 239000001257 hydrogen Substances 0.000 abstract 2
- 229920001155 polypropylene Polymers 0.000 abstract 2
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 abstract 2
- 125000006545 (C1-C9) alkyl group Chemical group 0.000 abstract 1
- ZZNDQCACFUJAKJ-UHFFFAOYSA-N 1-phenyltridecan-1-one Chemical compound CCCCCCCCCCCCC(=O)C1=CC=CC=C1 ZZNDQCACFUJAKJ-UHFFFAOYSA-N 0.000 abstract 1
- NKFNBVMJTSYZDV-UHFFFAOYSA-N 2-[dodecyl(2-hydroxyethyl)amino]ethanol Chemical compound CCCCCCCCCCCCN(CCO)CCO NKFNBVMJTSYZDV-UHFFFAOYSA-N 0.000 abstract 1
- ZFCMPNYCFGASCJ-UHFFFAOYSA-N 2-[heptadecyl(2-hydroxyethyl)amino]ethanol Chemical compound CCCCCCCCCCCCCCCCCN(CCO)CCO ZFCMPNYCFGASCJ-UHFFFAOYSA-N 0.000 abstract 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 1
- 239000005977 Ethylene Substances 0.000 abstract 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 abstract 1
- 125000005024 alkenyl aryl group Chemical group 0.000 abstract 1
- 125000002877 alkyl aryl group Chemical group 0.000 abstract 1
- 125000003710 aryl alkyl group Chemical group 0.000 abstract 1
- 238000001125 extrusion Methods 0.000 abstract 1
- 150000002431 hydrogen Chemical class 0.000 abstract 1
- 238000001746 injection moulding Methods 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 238000009747 press moulding Methods 0.000 abstract 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 abstract 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 abstract 1
- 238000001175 rotational moulding Methods 0.000 abstract 1
- 238000005245 sintering Methods 0.000 abstract 1
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 abstract 1
- 229910021653 sulphate ion Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/41—Compounds containing sulfur bound to oxygen
- C08K5/42—Sulfonic acids; Derivatives thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Abstract
Polyolefin compositions comprise up to 6 weight per cent of one or more antistatic agents selected from metal and nitrogenous base sulphonates in which the organic radical is a C4- 30 alkyl or alkenyl group, an alkaryl or alkenyl aryl group having 2 to 30 chain carbon atoms or a polynuclear aromatic group having one or two C1- 9 alkyl or alkylene groups. Specified polyolefins are polymers and copolymers of ethylene, propylene and butylene. The compositions may also comprise non-ionic antistatic agents of formula R1O(CH2CH2O)n where R1 is alkyl, alkenyl, acyl, aryl or aralkyl having up to 20 carbon atoms or hydrogen and n is 2 to 100; or of formulae NR2R3R4 or R5R6N-X-NR7R8 where R2 is alkyl, alkenyl or acyl having 6 to 30 carbon atoms, R3 to R8 denote -(CxH2xO)nH where x is 2 or 3, n i 1 to 30, R4,R6 and R8 may alternatively be hydrogen, and X is C2- 6 alkylene. The compositions may be formed into shaped articles by extrusion, injection-moulding, press-moulding, rotational moulding and sintering. Many sulphate, sulphonate and non-ionic antistatic agents are listed, and examples describe compositions comprising alkyl sulphonates having an average of 15 carbon atoms with polyethylene, or copolymers of ethylene with propylene or butylene; and comprising the same sulphonate together with (4) polypropylene, lauryl heptaethylene glycol and nonylphenylheptaethylene glycol, (5) polypropylene and lauric diethanolamide, heptadecyl diethanolamine or N,N,N1,N1-tetrahydroxyethyl ethylenediamine, (6) polyethylene, lauryl heptaethylene glycol and nonylphenylheptaethylene glycol, and (7) polyethylene and dodecyl diethanolamine.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE1964C0034046 DE1234020B (en) | 1964-10-08 | 1964-10-08 | Thermoplastic compounds made from polyolefins for the production of anti-static moldings |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1115456A true GB1115456A (en) | 1968-05-29 |
Family
ID=7021121
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB4253165A Expired GB1115456A (en) | 1964-10-08 | 1965-10-07 | Antistatic polyolefine mixtures |
Country Status (3)
| Country | Link |
|---|---|
| BE (1) | BE670721A (en) |
| DE (1) | DE1234020B (en) |
| GB (1) | GB1115456A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| USRE31269E (en) | 1978-09-19 | 1983-06-07 | British Cellophane Limited | Heat-sealable antistatic polypropylene films |
| US6107454A (en) * | 1996-08-06 | 2000-08-22 | Exxon Chemical Patents, Inc. | Method of processing polyethylene |
| US6670412B1 (en) | 1996-12-19 | 2003-12-30 | Exxonmobil Chemical Patents Inc. | Method of melt processing amine containing polyethylenes |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3310417A1 (en) * | 1983-03-19 | 1984-09-20 | Peter Heinrich 2000 Hamburg Urdahl | Means for the antistatic finishing of polyolefins |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1034849B (en) * | 1954-02-20 | 1958-07-24 | Dehydag Gmbh | Process for reducing the electrostatic charge on the surfaces of deformed or processed, carbohydrate-free, high-polymer materials |
| US2805964A (en) * | 1956-04-04 | 1957-09-10 | Pennsalt Chemical Corp | Treatment of plastics |
| DE1154268B (en) * | 1960-01-07 | 1963-09-12 | Bayer Ag | The prevention of electrostatic charges in synthetic high polymers |
| DE1174739B (en) * | 1962-02-19 | 1964-07-30 | Boehme Fettchemie Gmbh | Process for the antistatic finishing of molded structures |
-
1964
- 1964-10-08 DE DE1964C0034046 patent/DE1234020B/en active Pending
-
1965
- 1965-10-07 GB GB4253165A patent/GB1115456A/en not_active Expired
- 1965-10-08 BE BE670721A patent/BE670721A/xx unknown
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| USRE31269E (en) | 1978-09-19 | 1983-06-07 | British Cellophane Limited | Heat-sealable antistatic polypropylene films |
| US6107454A (en) * | 1996-08-06 | 2000-08-22 | Exxon Chemical Patents, Inc. | Method of processing polyethylene |
| US6670412B1 (en) | 1996-12-19 | 2003-12-30 | Exxonmobil Chemical Patents Inc. | Method of melt processing amine containing polyethylenes |
Also Published As
| Publication number | Publication date |
|---|---|
| BE670721A (en) | 1966-01-31 |
| DE1234020B (en) | 1967-02-09 |
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