GB1111264A - Vessel for measuring oxygen potential in molten metal - Google Patents
Vessel for measuring oxygen potential in molten metalInfo
- Publication number
- GB1111264A GB1111264A GB18682/65A GB1868265A GB1111264A GB 1111264 A GB1111264 A GB 1111264A GB 18682/65 A GB18682/65 A GB 18682/65A GB 1868265 A GB1868265 A GB 1868265A GB 1111264 A GB1111264 A GB 1111264A
- Authority
- GB
- United Kingdom
- Prior art keywords
- electrode
- furnace
- molten metal
- standard
- standard electrode
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 title abstract 5
- 229910052760 oxygen Inorganic materials 0.000 title abstract 5
- 239000001301 oxygen Substances 0.000 title abstract 5
- 229910052751 metal Inorganic materials 0.000 title abstract 3
- 239000002184 metal Substances 0.000 title abstract 3
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 abstract 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract 4
- LTPBRCUWZOMYOC-UHFFFAOYSA-N Beryllium oxide Chemical compound O=[Be] LTPBRCUWZOMYOC-UHFFFAOYSA-N 0.000 abstract 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 abstract 2
- 239000003792 electrolyte Substances 0.000 abstract 2
- 229910002804 graphite Inorganic materials 0.000 abstract 2
- 239000010439 graphite Substances 0.000 abstract 2
- 239000000395 magnesium oxide Substances 0.000 abstract 2
- 239000000155 melt Substances 0.000 abstract 2
- 229910052759 nickel Inorganic materials 0.000 abstract 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 abstract 2
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 abstract 2
- 229910010271 silicon carbide Inorganic materials 0.000 abstract 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 1
- 239000007772 electrode material Substances 0.000 abstract 1
- 230000006698 induction Effects 0.000 abstract 1
- 229910052742 iron Inorganic materials 0.000 abstract 1
- JHOPGIQVBWUSNH-UHFFFAOYSA-N iron tungsten Chemical compound [Fe].[Fe].[W] JHOPGIQVBWUSNH-UHFFFAOYSA-N 0.000 abstract 1
- 229910052697 platinum Inorganic materials 0.000 abstract 1
- 239000012254 powdered material Substances 0.000 abstract 1
- 239000011819 refractory material Substances 0.000 abstract 1
- 239000000377 silicon dioxide Substances 0.000 abstract 1
- ZCUFMDLYAMJYST-UHFFFAOYSA-N thorium dioxide Chemical compound O=[Th]=O ZCUFMDLYAMJYST-UHFFFAOYSA-N 0.000 abstract 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 abstract 1
- 229910052721 tungsten Inorganic materials 0.000 abstract 1
- 239000010937 tungsten Substances 0.000 abstract 1
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
- G01N27/26—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
- G01N27/403—Cells and electrode assemblies
- G01N27/406—Cells and probes with solid electrolytes
- G01N27/411—Cells and probes with solid electrolytes for investigating or analysing of liquid metals
- G01N27/4115—Composition or fabrication of the electrodes and coatings thereon, e.g. catalysts
- G01N27/4117—Reference electrodes or reference mixtures
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
- G01N27/26—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
- G01N27/403—Cells and electrode assemblies
- G01N27/406—Cells and probes with solid electrolytes
- G01N27/411—Cells and probes with solid electrolytes for investigating or analysing of liquid metals
- G01N27/4115—Composition or fabrication of the electrodes and coatings thereon, e.g. catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Physics & Mathematics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Molecular Biology (AREA)
- Analytical Chemistry (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Measuring Oxygen Concentration In Cells (AREA)
Abstract
1,111,264. Determining oxygen content of molten metal electrically. YAWATA IRON & STEEL CO. Ltd. May 4, 1965 [May 6, 1964], No. 18682/65. Heading G1N. The oxygen content of molten metal is measured by means of a standard electrode 4, 5, 6 (Fig. 1) used as a reference in measuring the oxygen potential and a metallic electrode 8, which project through the bottom wall of a crucible 2 and contact the melt, and are connected to a recording meter 9. The standard electrode comprises a permeable shell 4, acting as an intermediate electrolyte, (of sintered magnesia, zirconia, alumina, silica, beryllia or thoria), which may be filled with powdered material 5 of constant low oxygen potential (e. g. graphite or silicon carbide), and a conductive rod 6 (of graphite, tungsten, silicon carbide). The crucible contents may be heated by a h. f. energized induction coil 1. The electrode 8 may be of iron tungsten or nickel surrounded by refractory material. In an alternative embodiment Fig. 3 (not shown) the standard electrode is constituted by an electrocast magnesia plug (4), which is used simultaneously as the intermediate electrolyte and as the standard electrode material and has a conductive rod of platinum or nickel embedded therein which is connected to the recording meter. When used in an industrial furnace Figs. 5, 7 (not shown) there may be a number of the standard electrodes (such as the Fig. 3 embodiment) used, each electrode being disposed in the furnace bottom wall at a different depth below the surface of the furnace adjacent the melt. As the furnace wall erodes in time then succeeding electrodes are selectively switched into a measuring circuit according to which one is exposed at the said surface.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2546864 | 1964-05-06 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1111264A true GB1111264A (en) | 1968-04-24 |
Family
ID=12166845
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB18682/65A Expired GB1111264A (en) | 1964-05-06 | 1965-05-04 | Vessel for measuring oxygen potential in molten metal |
Country Status (3)
| Country | Link |
|---|---|
| US (1) | US3403090A (en) |
| DE (1) | DE1673336A1 (en) |
| GB (1) | GB1111264A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2150299A (en) * | 1983-11-04 | 1985-06-26 | Italsider Spa Nuova | Oxygen cells |
Families Citing this family (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1177630A (en) * | 1966-04-12 | 1970-01-14 | Gkn Group Services Ltd | Improvements relating to the Measurement of Oxygen Potential of Gases at High Temperatures. |
| GB1132753A (en) * | 1966-06-23 | 1968-11-06 | Atomic Energy Authority Uk | Improvements in or relating to the determination of combined carbon in metals |
| US3514377A (en) * | 1967-11-27 | 1970-05-26 | Gen Electric | Measurement of oxygen-containing gas compositions and apparatus therefor |
| US3645720A (en) * | 1968-08-08 | 1972-02-29 | Nippon Kokan Kk | Method of deoxidizing steel |
| BE795847Q (en) * | 1968-09-11 | 1973-06-18 | Salzgitter Peine Stahlwerke | METHOD OF DETERMINING THE OXYGEN CONTENT OF MELTED MASSES OF METALS, IN PARTICULAR, OF STEEL |
| US3619381A (en) * | 1968-12-23 | 1971-11-09 | George R Fitterer | Determining oxygen content of materials |
| GB1252215A (en) * | 1969-06-13 | 1971-11-03 | ||
| US3719574A (en) * | 1970-07-06 | 1973-03-06 | Metallurgie Hoboken | Apparatus for measuring in a continuous manner the oxygen in a molten metal |
| US3674654A (en) * | 1970-12-11 | 1972-07-04 | Ford Motor Co | Determination of oxygen in molten steel |
| US4021326A (en) * | 1972-06-02 | 1977-05-03 | Robert Bosch G.M.B.H. | Electro-chemical sensor |
| CA979072A (en) * | 1972-12-06 | 1975-12-02 | Paul L. Jackson | Determination of oxygen in molten steel |
| US3891512A (en) * | 1972-12-06 | 1975-06-24 | Ford Motor Co | Determination of oxygen in molten steel |
| JPS5630194B2 (en) * | 1974-11-01 | 1981-07-13 | ||
| JPS527293A (en) * | 1975-07-08 | 1977-01-20 | Nissan Motor Co Ltd | Oxygen sensor |
| US4105523A (en) * | 1976-03-31 | 1978-08-08 | A. R. F. Products, Inc. | Biochemical oxygen demand measuring device |
| US4140475A (en) * | 1976-06-30 | 1979-02-20 | Robertshaw Controls Company | Combustion detection apparatus |
| US4174258A (en) * | 1978-05-03 | 1979-11-13 | Bendix Autolite Corporation | Solid electrolyte oxygen sensor with zero oxygen reference |
| CA1119249A (en) * | 1979-03-30 | 1982-03-02 | Ireq Institut De Recherche De L'hydro-Quebec | Method and apparatus for mesuring a gaseous anhydride in a gas containing oxygen |
| DE3209438C1 (en) * | 1982-03-16 | 1983-07-28 | Joachim Dr-Ing Wuenning | Method and measuring device for determining the activity of carbon in furnace atmospheres |
| US4526667A (en) * | 1984-01-31 | 1985-07-02 | Parkhurst Warren E | Corrosion protection anode |
| US4908105A (en) * | 1985-02-15 | 1990-03-13 | Hydrolab Corporation | Flow-compensated electrochemical cell and method of analysis |
| JPS61260156A (en) * | 1985-05-15 | 1986-11-18 | Nisshin Steel Co Ltd | Method and apparatus for measuring silicon concentration in molten metal |
| DE19736469A1 (en) * | 1997-08-21 | 1999-02-25 | Wacker Siltronic Halbleitermat | Method and device for measuring the oxygen potential in a silicon melt |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3297551A (en) * | 1961-01-09 | 1967-01-10 | Atomic Energy Authority Uk | Determination of oxygen in fluids |
| US3147149A (en) * | 1961-02-27 | 1964-09-01 | Mc Graw Edison Co | Fuel cell construction |
| US3138490A (en) * | 1961-02-28 | 1964-06-23 | Gen Electric | Fuel cell |
| US3216911A (en) * | 1961-09-29 | 1965-11-09 | Union Carbide Corp | Method of determining gas concentration and fuel cell construction |
-
1965
- 1965-05-04 US US453083A patent/US3403090A/en not_active Expired - Lifetime
- 1965-05-04 GB GB18682/65A patent/GB1111264A/en not_active Expired
- 1965-05-06 DE DE19651673336 patent/DE1673336A1/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2150299A (en) * | 1983-11-04 | 1985-06-26 | Italsider Spa Nuova | Oxygen cells |
Also Published As
| Publication number | Publication date |
|---|---|
| US3403090A (en) | 1968-09-24 |
| DE1673336A1 (en) | 1970-04-16 |
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