GB1107079A - Process for the production of copolymers of ethylene and acrylic monomers - Google Patents
Process for the production of copolymers of ethylene and acrylic monomersInfo
- Publication number
- GB1107079A GB1107079A GB1644466A GB1644466A GB1107079A GB 1107079 A GB1107079 A GB 1107079A GB 1644466 A GB1644466 A GB 1644466A GB 1644466 A GB1644466 A GB 1644466A GB 1107079 A GB1107079 A GB 1107079A
- Authority
- GB
- United Kingdom
- Prior art keywords
- ethylene
- acrylic
- copolymers
- peroxide
- butanol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 title abstract 4
- 239000005977 Ethylene Substances 0.000 title abstract 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 title abstract 3
- 229920001577 copolymer Polymers 0.000 title abstract 3
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- 239000000178 monomer Substances 0.000 title 1
- DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 abstract 4
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 abstract 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 abstract 2
- 125000000217 alkyl group Chemical group 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- PCJGHYSTCBLKIA-UHFFFAOYSA-N (1-acetylcyclohexyl)sulfonyloxy 1-acetylcyclohexane-1-sulfonate Chemical compound C1CCCCC1(C(C)=O)S(=O)(=O)OOS(=O)(=O)C1(C(=O)C)CCCCC1 PCJGHYSTCBLKIA-UHFFFAOYSA-N 0.000 abstract 1
- WRXCBRHBHGNNQA-UHFFFAOYSA-N (2,4-dichlorobenzoyl) 2,4-dichlorobenzenecarboperoxoate Chemical compound ClC1=CC(Cl)=CC=C1C(=O)OOC(=O)C1=CC=C(Cl)C=C1Cl WRXCBRHBHGNNQA-UHFFFAOYSA-N 0.000 abstract 1
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 abstract 1
- YIVJZNGAASQVEM-UHFFFAOYSA-N Lauroyl peroxide Chemical compound CCCCCCCCCCCC(=O)OOC(=O)CCCCCCCCCCC YIVJZNGAASQVEM-UHFFFAOYSA-N 0.000 abstract 1
- 230000001070 adhesive effect Effects 0.000 abstract 1
- 230000009435 amidation Effects 0.000 abstract 1
- 238000007112 amidation reaction Methods 0.000 abstract 1
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 238000004132 cross linking Methods 0.000 abstract 1
- BLCKNMAZFRMCJJ-UHFFFAOYSA-N cyclohexyl cyclohexyloxycarbonyloxy carbonate Chemical compound C1CCCCC1OC(=O)OOC(=O)OC1CCCCC1 BLCKNMAZFRMCJJ-UHFFFAOYSA-N 0.000 abstract 1
- 230000032050 esterification Effects 0.000 abstract 1
- 238000005886 esterification reaction Methods 0.000 abstract 1
- 229920001038 ethylene copolymer Polymers 0.000 abstract 1
- 239000011888 foil Substances 0.000 abstract 1
- 238000005755 formation reaction Methods 0.000 abstract 1
- 239000011953 free-radical catalyst Substances 0.000 abstract 1
- -1 hydroxyalkyl ester Chemical class 0.000 abstract 1
- 125000002768 hydroxyalkyl group Chemical group 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- BWJUFXUULUEGMA-UHFFFAOYSA-N propan-2-yl propan-2-yloxycarbonyloxy carbonate Chemical compound CC(C)OC(=O)OOC(=O)OC(C)C BWJUFXUULUEGMA-UHFFFAOYSA-N 0.000 abstract 1
- 239000011541 reaction mixture Substances 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 239000012945 sealing adhesive Substances 0.000 abstract 1
- 239000003566 sealing material Substances 0.000 abstract 1
- 239000002562 thickening agent Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F20/62—Monocarboxylic acids having ten or more carbon atoms; Derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
Ethylene copolymers are prepared by reacting ethylene with acrylic and/or methacrylic acid and, optionally, an alkyl or hydroxyalkyl ester of acrylic and/or methacrylic acid containing 1 to 8 carbon atoms in the alkyl or hydroxyalkyl group, the molar ratio of ethylene to acrylic component(s) being from 8:1 to 10,000:1, in the presence of t-butanol and a free radical catalyst having a half-life below 5 hours at the polymerization temperature, the reaction being effected at an ethylene pressure of 20-450 atmospheres and a temperature below 100 DEG C., and the acrylic component(s) and catalyst, or solutions thereof in t-butanol, being added continuously and simultaneously to the reaction mixture. The process can be carried out batchwise or continuously. Catalysts specified are lauroyl peroxide, 2,4-dichlorobenzoyl peroxide, diisopropyl peroxydicarbonate, dicyclohexyl - peroxydicarbonate, acetyl cyclohexanesulphonyl peroxide and azodiisobutyronitrile. The copolymer products can undergo esterification, salt formation, amidation or cross-linking. The copolymers are suitable for the production of shaped articles, e.g. fibres or foils, and for use as sealing materials, adhesives and thickeners.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEF0045815 | 1965-04-14 | ||
| DEF0047403 | 1965-10-12 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1107079A true GB1107079A (en) | 1968-03-20 |
Family
ID=25976719
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB1644466A Expired GB1107079A (en) | 1965-04-14 | 1966-04-14 | Process for the production of copolymers of ethylene and acrylic monomers |
Country Status (6)
| Country | Link |
|---|---|
| BE (1) | BE679490A (en) |
| DE (1) | DE1570612C3 (en) |
| FR (1) | FR1482183A (en) |
| GB (1) | GB1107079A (en) |
| NL (1) | NL6605019A (en) |
| SE (1) | SE317502B (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0207161A4 (en) * | 1984-11-27 | 1987-04-14 | Sumitomo Chemical Co | PROCESS FOR PRODUCING ETHYLENE COPOLYMER. |
| CN112126002A (en) * | 2020-09-10 | 2020-12-25 | 珠海展辰新材料股份有限公司 | Water-based acrylic resin, preparation method thereof and amino baking varnish |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1237055B (en) * | 1965-10-21 | 1967-03-23 | Bayer Ag | Process for the heat sealing of textiles |
-
0
- FR FR1482183D patent/FR1482183A/fr not_active Expired
-
1965
- 1965-10-12 DE DE19651570612 patent/DE1570612C3/en not_active Expired
-
1966
- 1966-04-05 SE SE461666A patent/SE317502B/xx unknown
- 1966-04-14 GB GB1644466A patent/GB1107079A/en not_active Expired
- 1966-04-14 BE BE679490D patent/BE679490A/xx unknown
- 1966-04-14 NL NL6605019A patent/NL6605019A/xx unknown
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0207161A4 (en) * | 1984-11-27 | 1987-04-14 | Sumitomo Chemical Co | PROCESS FOR PRODUCING ETHYLENE COPOLYMER. |
| US4721761A (en) * | 1984-11-27 | 1988-01-26 | Sumitomo Chemical Company, Limited | Process for the preparation of ethylene copolymer |
| CN112126002A (en) * | 2020-09-10 | 2020-12-25 | 珠海展辰新材料股份有限公司 | Water-based acrylic resin, preparation method thereof and amino baking varnish |
| CN112126002B (en) * | 2020-09-10 | 2022-05-10 | 珠海展辰新材料股份有限公司 | Water-based acrylic resin, preparation method thereof and amino baking varnish |
Also Published As
| Publication number | Publication date |
|---|---|
| DE1570612C3 (en) | 1974-01-31 |
| BE679490A (en) | 1966-09-16 |
| FR1482183A (en) | 1967-08-23 |
| NL6605019A (en) | 1966-10-17 |
| SE317502B (en) | 1969-11-17 |
| DE1570612A1 (en) | 1970-09-10 |
| DE1570560A1 (en) | 1970-01-29 |
| DE1570612B2 (en) | 1973-06-20 |
| DE1570560B2 (en) | 1972-07-20 |
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