GB1105585A - High impact strength polystyrene compositions - Google Patents
High impact strength polystyrene compositionsInfo
- Publication number
- GB1105585A GB1105585A GB4344265A GB4344265A GB1105585A GB 1105585 A GB1105585 A GB 1105585A GB 4344265 A GB4344265 A GB 4344265A GB 4344265 A GB4344265 A GB 4344265A GB 1105585 A GB1105585 A GB 1105585A
- Authority
- GB
- United Kingdom
- Prior art keywords
- impact strength
- copolymer
- high impact
- polystyrene
- block
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000004793 Polystyrene Substances 0.000 title abstract 3
- 229920002223 polystyrene Polymers 0.000 title abstract 3
- 239000000203 mixture Substances 0.000 title abstract 2
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 abstract 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 abstract 2
- MZRVEZGGRBJDDB-UHFFFAOYSA-N N-Butyllithium Chemical compound [Li]CCCC MZRVEZGGRBJDDB-UHFFFAOYSA-N 0.000 abstract 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 abstract 2
- 229920001577 copolymer Polymers 0.000 abstract 2
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 abstract 2
- OEVVKKAVYQFQNV-UHFFFAOYSA-N 1-ethenyl-2,4-dimethylbenzene Chemical compound CC1=CC=C(C=C)C(C)=C1 OEVVKKAVYQFQNV-UHFFFAOYSA-N 0.000 abstract 1
- JZHGRUMIRATHIU-UHFFFAOYSA-N 1-ethenyl-3-methylbenzene Chemical compound CC1=CC=CC(C=C)=C1 JZHGRUMIRATHIU-UHFFFAOYSA-N 0.000 abstract 1
- IGGDKDTUCAWDAN-UHFFFAOYSA-N 1-vinylnaphthalene Chemical compound C1=CC=C2C(C=C)=CC=CC2=C1 IGGDKDTUCAWDAN-UHFFFAOYSA-N 0.000 abstract 1
- KXYAVSFOJVUIHT-UHFFFAOYSA-N 2-vinylnaphthalene Chemical compound C1=CC=CC2=CC(C=C)=CC=C21 KXYAVSFOJVUIHT-UHFFFAOYSA-N 0.000 abstract 1
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 abstract 1
- 239000003963 antioxidant agent Substances 0.000 abstract 1
- 230000003078 antioxidant effect Effects 0.000 abstract 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 abstract 1
- 229920001400 block copolymer Polymers 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 150000001993 dienes Chemical class 0.000 abstract 1
- 230000000379 polymerizing effect Effects 0.000 abstract 1
- 229920005604 random copolymer Polymers 0.000 abstract 1
- 229920006395 saturated elastomer Polymers 0.000 abstract 1
- 235000003441 saturated fatty acids Nutrition 0.000 abstract 1
- 150000004671 saturated fatty acids Chemical class 0.000 abstract 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 abstract 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 abstract 1
- 150000004670 unsaturated fatty acids Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
- C08L25/06—Polystyrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Graft Or Block Polymers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The impact strength of polystyrene is increased by mixing with a linear, random or block, solution copolymer of a conjugated diene and a monovinyl substituted aromatic hydrocarbon. The block or random copolymer may be formed by polymerizing (i) 1,3-butadiene and (ii) styrene, 3-vinyltoluene, 1- or 2-vinylnaphthalene or 2,4-dimethylstyrene and optionally (iii) divinylbenzene, in n-hexane in the presence of n-butyllithium and tetrahydrofuran; and then adding a mixture of C16- 18 saturated and unsaturated fatty acids to inactivate the catalyst and 2,6-ditert.-butyl-4-methylphenol as antioxidant. The polystyrene and copolymer may be blended in the molten state.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US40837164A | 1964-11-02 | 1964-11-02 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1105585A true GB1105585A (en) | 1968-03-06 |
Family
ID=23616019
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB4344265A Expired GB1105585A (en) | 1964-11-02 | 1965-10-13 | High impact strength polystyrene compositions |
Country Status (6)
| Country | Link |
|---|---|
| BE (1) | BE671697A (en) |
| DE (1) | DE1569311B2 (en) |
| ES (1) | ES318694A1 (en) |
| FR (1) | FR1457763A (en) |
| GB (1) | GB1105585A (en) |
| NL (2) | NL6513980A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2601655A1 (en) * | 1974-05-28 | 1977-07-21 | Dow Chemical Co | PROCESS FOR IMPROVING THE IMPACT STRENGTH OF AROMATIC MONOVINYLIDENE POLYMERISATES |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2219756C3 (en) * | 1972-01-05 | 1984-04-12 | The General Tire & Rubber Co., 44329 Akron, Ohio | High impact molding compound and process for the production of such molding compounds |
| CA959196A (en) * | 1972-02-24 | 1974-12-10 | Richard R. Durst | High impact two-component resin blends |
-
0
- NL NL128294D patent/NL128294C/xx active
-
1965
- 1965-10-08 FR FR34309A patent/FR1457763A/en not_active Expired
- 1965-10-13 GB GB4344265A patent/GB1105585A/en not_active Expired
- 1965-10-20 ES ES0318694A patent/ES318694A1/en not_active Expired
- 1965-10-27 DE DE19651569311 patent/DE1569311B2/en active Pending
- 1965-10-28 NL NL6513980A patent/NL6513980A/xx unknown
- 1965-10-29 BE BE671697D patent/BE671697A/xx unknown
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2601655A1 (en) * | 1974-05-28 | 1977-07-21 | Dow Chemical Co | PROCESS FOR IMPROVING THE IMPACT STRENGTH OF AROMATIC MONOVINYLIDENE POLYMERISATES |
Also Published As
| Publication number | Publication date |
|---|---|
| NL6513980A (en) | 1966-05-03 |
| BE671697A (en) | 1966-04-29 |
| NL128294C (en) | |
| DE1569311A1 (en) | 1970-05-06 |
| FR1457763A (en) | 1966-01-24 |
| DE1569311B2 (en) | 1971-06-09 |
| ES318694A1 (en) | 1966-05-16 |
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