GB1194704A - Copolyester Compositions and Shaped Articles thereof - Google Patents
Copolyester Compositions and Shaped Articles thereofInfo
- Publication number
- GB1194704A GB1194704A GB21870/67A GB2187067A GB1194704A GB 1194704 A GB1194704 A GB 1194704A GB 21870/67 A GB21870/67 A GB 21870/67A GB 2187067 A GB2187067 A GB 2187067A GB 1194704 A GB1194704 A GB 1194704A
- Authority
- GB
- United Kingdom
- Prior art keywords
- copolyester
- polyethylene
- ethylene glycol
- terephthalic acid
- acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920001634 Copolyester Polymers 0.000 title abstract 17
- 239000000203 mixture Substances 0.000 title abstract 8
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 abstract 21
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 abstract 14
- -1 polyethylene Polymers 0.000 abstract 8
- 239000004698 Polyethylene Substances 0.000 abstract 6
- 229920000573 polyethylene Polymers 0.000 abstract 6
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 abstract 4
- 239000002202 Polyethylene glycol Substances 0.000 abstract 3
- 239000002131 composite material Substances 0.000 abstract 3
- 239000012188 paraffin wax Substances 0.000 abstract 3
- 229920001223 polyethylene glycol Polymers 0.000 abstract 3
- QLIQIXIBZLTPGQ-UHFFFAOYSA-N 4-(2-hydroxyethoxy)benzoic acid Chemical compound OCCOC1=CC=C(C(O)=O)C=C1 QLIQIXIBZLTPGQ-UHFFFAOYSA-N 0.000 abstract 2
- 235000011037 adipic acid Nutrition 0.000 abstract 2
- 239000001361 adipic acid Substances 0.000 abstract 2
- 239000000839 emulsion Substances 0.000 abstract 2
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 abstract 2
- 229920000728 polyester Polymers 0.000 abstract 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 1
- 239000005977 Ethylene Substances 0.000 abstract 1
- 239000005062 Polybutadiene Substances 0.000 abstract 1
- 239000004743 Polypropylene Substances 0.000 abstract 1
- 150000002009 diols Chemical class 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 239000000155 melt Substances 0.000 abstract 1
- 230000008018 melting Effects 0.000 abstract 1
- 238000002844 melting Methods 0.000 abstract 1
- 229920002857 polybutadiene Polymers 0.000 abstract 1
- 229920001610 polycaprolactone Polymers 0.000 abstract 1
- 239000004632 polycaprolactone Substances 0.000 abstract 1
- 229920006267 polyester film Polymers 0.000 abstract 1
- 229920000139 polyethylene terephthalate Polymers 0.000 abstract 1
- 239000005020 polyethylene terephthalate Substances 0.000 abstract 1
- 229920000098 polyolefin Polymers 0.000 abstract 1
- 229920001155 polypropylene Polymers 0.000 abstract 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/14—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyester as constituent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
1,194,704. Polyester films and filaments. KANEGAFUCHI BOSEKI K.K. 11 May, 1967 [11 May, 1966], No. 21870/67. Heading B5B. [Also in Division C3] The stickiness of copolyester films and fibres is reduced by incorporating into the copolyester a polyolefin, a polybutadiene or a paraffin wax in an amount of 0À01 to 25% by weight of the copolyester. The copolyester compositions may be extruded by themselves into films or fibres but preferably are used in the manufacture of composite filaments by separately melting the copolyester composition and a homopolyester or different copolyester, and extruding the two melts through the same orifice to form a single filament in which the two polyesters extend in side-by-side conjugated relationship along the entire length of the filament. In Example I, the following copolyester compositions were melt spun and the resulting filaments lubricated with an aqueous oil emulsion, (i) copoly-(ethylene terephthalate adipate) with polyethylene; (ii) a copolyester of ethylene glycol, polyethylene glycol and terephthalic acid with polyethylene, (iii) a copolyester of ethylene glycol, terephthalic acid and adipic acid with polypropylene, (iv) a block copolyester of poly- (ethylene diphenoxyethane-4:4<SP>1</SP>-dicarboxylate) and poly-(1:10-decylene diphenoxyethane-4:4<SP>1</SP>- dicarboxylate) with polyethylene, (v) a copolyester of p-(beta-hydroxyethoxy) benzoic acid, 1:10-decanedicarboxylic acid and triethylene glycol with paraffin wax. In Example 2, composite filaments were made by extruding together polyethylene terephthalate and a mixture of a copolyester of ethylene glycol, polyethylene glycol and terephthalic acid with polyethylene, the resulting filaments being lubricated with an aqueous oil emulsion, wound and possibly drawn 5 x at 80‹ C. In Example 3, a composition of a copolyester of ethylene glycol, polyethylene glycol and terephthalic acid with polyethylene was melt extruded at 260‹ C. through a T-die into a film. In Example 4, composite filaments were made in a manner similar to that in Example 2 by extruding together (a) a copolyester of ethylene glycol, terephthalic acid and isophthalic acid and a composition of a copolyester of ethylene glycol, terephthalic acid and adipic acid with polyethylene, (b) a polyester of p-(beta-hydroxyethoxy)-benzoic acid and a composition of a copolyester of ethylene glycol, polycaprolactone diol and terephthalic acid with paraffin wax.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3014866 | 1966-05-11 | ||
| FR106107A FR1525443A (en) | 1966-05-11 | 1967-05-11 | Process for producing shaped articles made from copolyester fibers |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1194704A true GB1194704A (en) | 1970-06-10 |
Family
ID=29217285
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB21870/67A Expired GB1194704A (en) | 1966-05-11 | 1967-05-11 | Copolyester Compositions and Shaped Articles thereof |
Country Status (2)
| Country | Link |
|---|---|
| FR (1) | FR1525443A (en) |
| GB (1) | GB1194704A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4187113A (en) | 1975-11-05 | 1980-02-05 | Imperial Chemical Industries Limited | Voided films of polyester with polyolefin particles |
| EP0185555A3 (en) * | 1984-12-21 | 1987-09-09 | Polyplastics Co. Ltd. | Polybutylene terephthalate resin composition |
| EP0255735A3 (en) * | 1984-07-09 | 1988-04-27 | Mitsui Petrochemical Industries, Ltd. | Polyester composition |
| US5069970A (en) * | 1989-01-23 | 1991-12-03 | Allied-Signal Inc. | Fibers and filters containing said fibers |
| WO2005061604A1 (en) * | 2003-12-24 | 2005-07-07 | Gale Pacific Limited | Polymeric plastics material and manufacture thereof |
| CN114058123A (en) * | 2021-12-20 | 2022-02-18 | 苏州度辰新材料有限公司 | Master batch for polyolefin film, preparation method, polyolefin film and BOPP film |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3963802A (en) * | 1975-06-20 | 1976-06-15 | E. I. Du Pont De Nemours And Company | Blend of ethylene copolymer elastomer and a copolyetherester elastomer |
-
1967
- 1967-05-11 GB GB21870/67A patent/GB1194704A/en not_active Expired
- 1967-05-11 FR FR106107A patent/FR1525443A/en not_active Expired
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4187113A (en) | 1975-11-05 | 1980-02-05 | Imperial Chemical Industries Limited | Voided films of polyester with polyolefin particles |
| EP0255735A3 (en) * | 1984-07-09 | 1988-04-27 | Mitsui Petrochemical Industries, Ltd. | Polyester composition |
| US4914145A (en) * | 1984-07-09 | 1990-04-03 | Mitsui Petrochemical Industries, Ltd. | Polyester composition |
| EP0185555A3 (en) * | 1984-12-21 | 1987-09-09 | Polyplastics Co. Ltd. | Polybutylene terephthalate resin composition |
| US5069970A (en) * | 1989-01-23 | 1991-12-03 | Allied-Signal Inc. | Fibers and filters containing said fibers |
| WO2005061604A1 (en) * | 2003-12-24 | 2005-07-07 | Gale Pacific Limited | Polymeric plastics material and manufacture thereof |
| EP1697453A4 (en) * | 2003-12-24 | 2007-03-21 | Gale Pacific Ltd | Polymeric plastics material and manufacture thereof |
| CN114058123A (en) * | 2021-12-20 | 2022-02-18 | 苏州度辰新材料有限公司 | Master batch for polyolefin film, preparation method, polyolefin film and BOPP film |
Also Published As
| Publication number | Publication date |
|---|---|
| FR1525443A (en) | 1968-05-17 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed [section 19, patents act 1949] | ||
| PLNP | Patent lapsed through nonpayment of renewal fees |