[go: up one dir, main page]

GB1189001A - Improvements in or relating to the Catalytic Reforming of Gaseous and/or Liquid Hydrocarbons - Google Patents

Improvements in or relating to the Catalytic Reforming of Gaseous and/or Liquid Hydrocarbons

Info

Publication number
GB1189001A
GB1189001A GB20350/67A GB2035067A GB1189001A GB 1189001 A GB1189001 A GB 1189001A GB 20350/67 A GB20350/67 A GB 20350/67A GB 2035067 A GB2035067 A GB 2035067A GB 1189001 A GB1189001 A GB 1189001A
Authority
GB
United Kingdom
Prior art keywords
stage
catalyst
oxides
liquid hydrocarbons
gaseous
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB20350/67A
Inventor
Jean Gignier
Pierre Lhonore
Jacques Quibel
Michel Senes
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Societe Chimique de la Grande Paroisse Azote et Produits Chimiques
Original Assignee
Societe Chimique de la Grande Paroisse Azote et Produits Chimiques
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from FR61061A external-priority patent/FR1492926A/en
Priority claimed from FR102684A external-priority patent/FR92171E/en
Application filed by Societe Chimique de la Grande Paroisse Azote et Produits Chimiques filed Critical Societe Chimique de la Grande Paroisse Azote et Produits Chimiques
Publication of GB1189001A publication Critical patent/GB1189001A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/384—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts the catalyst being continuously externally heated
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1047—Group VIII metal catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1047—Group VIII metal catalysts
    • C01B2203/1052—Nickel or cobalt catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)

Abstract

1,189,001. Making combustible gas. SOC. CHIMIQUE DE LA GRANDE PAROISSE AZOTE ET PRODUITS CHIMIQUES. 2 May, 1967 [11 May, 1966; 14 April, 1967], No. 20350/67. Heading C5E. Gases containing about 60 to 70% H 2 are made by catalytically steam reforming gaseous and/or liquid hydrocarbons having a B.P. not greater than 350‹ C., containing up to 30% aromatics, and having from 4 to 12 C atoms per molecule. Essential reaction conditions are: pressure 70 to 200 bars, inlet temperature 300‹ to 700‹ C., space velocity (litres hydrocarbon/litre of catalyst per hour) up to 30, steam to carbon mole ratio 1.5 to 5, and the catalyst should contain Ni in an amount calculated as Ni oxide, of from 8 to 30% b.w. of the total catalyst. The catalyst support is one or more of the oxides of Mg, Ca, Al, and/or Zr dioxide, and may contain SiO 2 and one or more of the oxides of K, Na, Ba and/or Cr trioxide. Conventional radiantly heated reformers are used, and air, CO, C0 2 or recycled H 2 may be delivered to the inlet. Two-stage reforming processes are described, air being added at the second stage which acts to adjust the CH 4 content of the make gas, and the second stage may be carried out in a chamber containing the tubes forming the first stage.
GB20350/67A 1966-05-11 1967-05-02 Improvements in or relating to the Catalytic Reforming of Gaseous and/or Liquid Hydrocarbons Expired GB1189001A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR61061A FR1492926A (en) 1966-05-11 1966-05-11 High pressure reforming process for hydrocarbons
FR102684A FR92171E (en) 1967-04-14 1967-04-14 High pressure reforming process for hydrocarbons

Publications (1)

Publication Number Publication Date
GB1189001A true GB1189001A (en) 1970-04-22

Family

ID=26170572

Family Applications (1)

Application Number Title Priority Date Filing Date
GB20350/67A Expired GB1189001A (en) 1966-05-11 1967-05-02 Improvements in or relating to the Catalytic Reforming of Gaseous and/or Liquid Hydrocarbons

Country Status (5)

Country Link
US (1) US3533766A (en)
BE (1) BE698289A (en)
DE (1) DE1645861A1 (en)
ES (1) ES340242A1 (en)
GB (1) GB1189001A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2170508A (en) * 1985-01-17 1986-08-06 Linde Ag Production of H2/CO synthesis gas
US4824440A (en) * 1986-03-21 1989-04-25 British Gas Plc Production of methane containing gases

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4005031A (en) * 1973-04-11 1977-01-25 Hoffmann-La Roche Inc. Nickel peroxide oxidizing agent
US4452915A (en) * 1977-12-22 1984-06-05 General Electric Company Nickel oxide catalyst supported on magnesium for the selective ortho-alkylation of phenolic compounds with an alkane
US4451578A (en) * 1982-04-26 1984-05-29 United Technologies Corporation Iron oxide catalyst for steam reforming
RU2553457C1 (en) * 2013-11-08 2015-06-20 Федеральное государственное бюджетное образовательное учреждение высшего образования "Московский государственный университет имени М.В. Ломоносова" (МГУ) Catalyst of steam conversion of hydrocarbons and method of obtaining thereof
MX2023000297A (en) * 2020-07-07 2023-04-11 Proteum Energy Llc METHOD AND SYSTEM FOR CONVERTING NON-METHANE HYDROCARBONS TO RECOVER HYDROGEN GAS AND/OR METHANE GAS FROM THESE.

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2028326A (en) * 1931-01-23 1936-01-21 Standard Oil Dev Co Apparatus for the production of hydrogen
GB772787A (en) * 1952-02-19 1957-04-17 Azote Office Nat Ind Improvements in or relating to processes for the manufacture of gases containing hydrogen by a conversion of hydrocarbons
US3119667A (en) * 1961-01-31 1964-01-28 Pullman Inc Process for hydrogen production
NL268083A (en) * 1961-08-16
US3278268A (en) * 1962-08-15 1966-10-11 Engelhard Ind Inc Method for hydrogen production
US3132010A (en) * 1962-11-08 1964-05-05 Pullman Inc Reforming of gaseous hydrocarbons
DE1185590B (en) * 1962-12-18 1965-01-21 Basf Ag Tube furnace
US3201214A (en) * 1963-02-01 1965-08-17 Pullman Inc Production of domestic heating gas
US3394086A (en) * 1964-05-04 1968-07-23 Exxon Research Engineering Co Selective partial conversion of naphtha hydrocarbons to hydrogen
US3385670A (en) * 1964-12-29 1968-05-28 Pullman Inc Steam reforming of hydrocarbons and catalyst therefor containing a cobalt component on a zirconia support
US3420643A (en) * 1965-08-24 1969-01-07 Azote & Prod Chim Method for reforming light petrol fractions under pressure

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2170508A (en) * 1985-01-17 1986-08-06 Linde Ag Production of H2/CO synthesis gas
US4824440A (en) * 1986-03-21 1989-04-25 British Gas Plc Production of methane containing gases

Also Published As

Publication number Publication date
DE1645861A1 (en) 1970-07-09
BE698289A (en) 1967-11-10
US3533766A (en) 1970-10-13
ES340242A1 (en) 1968-06-01

Similar Documents

Publication Publication Date Title
US2056911A (en) Production of hydrogen from hydrocarbons
GB1505254A (en) Catalyst and process for preparing methane rich gas
US5310506A (en) Process of producing a synthesis gas for methanol synthesis
US4048091A (en) Process for the preparation of reducing gases
US3415634A (en) Treatment of hydrocarbon containing oils
GB1446378A (en) Process for producing carbon monoxide from light hydrocarbons
US3387942A (en) Production of hydrogen
Medsforth CLXIX.—Promotion of catalytic reactions. Part I
GB1189001A (en) Improvements in or relating to the Catalytic Reforming of Gaseous and/or Liquid Hydrocarbons
GB423001A (en) Process for the production of non-knocking benzines
GB366360A (en) Improvements in or relating to the production of hydrogen from hydrocarbon gases
GB1432696A (en) Catalytic process
US3467506A (en) Catalytic conversion of liquid petroleum hydrocarbons
US3481722A (en) Process for producing hydrogen
NO313666B1 (en) Reactor and process for producing synthesis gas and use thereof
GB1462059A (en) Catalyst and its use for the manufacture of gases containing methane manufacture of methane from gases containing carbon monoxide and dioxide and hydrogen
US2069545A (en) Synthesis of hydrocyanic acid
GB1072221A (en) Low-temperature, high pressure, catalytic conversion of hydrocarbons to hydrogen
US2111584A (en) Process for making formaldehyde
US2701756A (en) Manufacture of synthesis gas
US3624176A (en) Catalytic process for producing gas mixtures having high ethylene contents
GB129743A (en) Improvements in the Purification of Hydrogen.
GB1375226A (en)
US3859373A (en) Manufacture of hydrogen
GB1270756A (en) A process for producing synthesis gas for use in the production of ammonia

Legal Events

Date Code Title Description
PS Patent sealed [section 19, patents act 1949]
PE Patent expired