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GB1182885A - A process for the production of very High-Viscosity-Index Lubricating Oils - Google Patents

A process for the production of very High-Viscosity-Index Lubricating Oils

Info

Publication number
GB1182885A
GB1182885A GB42311/68A GB4231168A GB1182885A GB 1182885 A GB1182885 A GB 1182885A GB 42311/68 A GB42311/68 A GB 42311/68A GB 4231168 A GB4231168 A GB 4231168A GB 1182885 A GB1182885 A GB 1182885A
Authority
GB
United Kingdom
Prior art keywords
oil
metal
catalyst
viscosity
polymethacrylates
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB42311/68A
Inventor
Peter William Dun
Formijn Johann Van Hemert
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SHELL INT RESEARCH
Shell Internationale Research Maatschappij BV
Original Assignee
SHELL INT RESEARCH
Shell Internationale Research Maatschappij BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SHELL INT RESEARCH, Shell Internationale Research Maatschappij BV filed Critical SHELL INT RESEARCH
Priority to GB42311/68A priority Critical patent/GB1182885A/en
Priority to US853719A priority patent/US3663422A/en
Priority to NL6913396A priority patent/NL6913396A/xx
Priority to AT840369A priority patent/AT295716B/en
Priority to DE19691944757 priority patent/DE1944757A1/en
Priority to CA061,054A priority patent/CA945096A/en
Priority to FR6930075A priority patent/FR2019327B1/fr
Priority to CH1333469A priority patent/CH524681A/en
Priority to BE738357D priority patent/BE738357A/xx
Priority to NO3530/69A priority patent/NO125493B/no
Publication of GB1182885A publication Critical patent/GB1182885A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M101/00—Lubricating compositions characterised by the base-material being a mineral or fatty oil
    • C10M101/02—Petroleum fractions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/10—Lubricating oil
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/102—Aliphatic fractions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02—Hydroxy compounds
    • C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02—Hydroxy compounds
    • C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
    • C10M2207/027—Neutral salts thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/16—Naphthenic acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/08—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
    • C10M2209/084—Acrylate; Methacrylate
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
    • C10M2215/086—Imides [having hydrocarbon substituents containing less than thirty carbon atoms]
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
    • C10M2215/24—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions having hydrocarbon substituents containing thirty or more carbon atoms, e.g. nitrogen derivatives of substituted succinic acid
    • C10M2215/28—Amides; Imides
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
    • C10M2223/045—Metal containing thio derivatives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00—Metal present as such or in compounds
    • C10N2010/04—Groups 2 or 12
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2050/00—Form in which the lubricant is applied to the material being lubricated
    • C10N2050/015—Dispersions of solid lubricants
    • C10N2050/02—Dispersions of solid lubricants dissolved or suspended in a carrier which subsequently evaporates to leave a lubricant coating

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Catalysts (AREA)

Abstract

1,182,885. Hydrocracking; hydrotreating; lubricants. SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ N.V. 5 Sept.. 1968, No. 42311/68. Headings C5E and C5F. A process for the production of very high viscosity index lubricating oils comprises hydrotreating a solvent-refined, asphalt-free waxy hydrocarbon oil in the presence of a sulphided catalyst comprising a Group VI and/or Group VIII metal supported on a substantially non-acidic refractory cracking base at a temperature in the range of from 400‹ to 460‹ C., a pressure of from 165 to 225 kg/cm.<SP>2</SP> and a weight hourly space velocity of from 0À25 to 2-25 kg. of the said oil per litre of catalyst per hour and recovering a dewaxed lubricating oil having a V.I. of at least 125 and a viscosity at 210‹ F. of at least 9 centistokes from the hydrotreated waxy oil by means of fractionation and dewaxing. A product of one embodiment of the process is an oil meeting 10W/30 requirements without additives. The starting material may be a distillate, reduced or tapped crude or residuum; it may be extracted with furfural, liquid SO 2 , phenol, cresol or chlorex; it may be deasphalted with ethane, propane, butane or pentane or mixtures of these with each other or with methanol or isopropanol. The catalyst may comprise Mo, W, Co, Ni, or Pt, present as metal, sulphide or oxide on alumina which may contain alkali or alkaline earth metals but not more than 5% of silica. Lubricating compositions may comprise the oil produced by the invention, plus isobutylene polymers, polyacrylates, polymethacrylates, metal sulphonates, metal phenates, metal naphthenates, polyethylene glycol substituted polymethacrylates, zinc dithiophosphates, alkylated phenols and amine-derived succinic anhydrides.
GB42311/68A 1968-09-05 1968-09-05 A process for the production of very High-Viscosity-Index Lubricating Oils Expired GB1182885A (en)

Priority Applications (10)

Application Number Priority Date Filing Date Title
GB42311/68A GB1182885A (en) 1968-09-05 1968-09-05 A process for the production of very High-Viscosity-Index Lubricating Oils
US853719A US3663422A (en) 1968-09-05 1969-08-28 Process for the production of very high vi lubricating oils by hydrotreating
NL6913396A NL6913396A (en) 1968-09-05 1969-09-03
AT840369A AT295716B (en) 1968-09-05 1969-09-03 Process for the production of lubricating oils with a very high viscosity index
DE19691944757 DE1944757A1 (en) 1968-09-05 1969-09-03 Process for the production of lubricating oils with a very high viscosity index
CA061,054A CA945096A (en) 1968-09-05 1969-09-03 Process for the production of very high-viscosity-index lubricating oils
FR6930075A FR2019327B1 (en) 1968-09-05 1969-09-03
CH1333469A CH524681A (en) 1968-09-05 1969-09-03 Process for the production of lubricating oils with a very high viscosity index
BE738357D BE738357A (en) 1968-09-05 1969-09-03
NO3530/69A NO125493B (en) 1968-09-05 1969-09-03

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB42311/68A GB1182885A (en) 1968-09-05 1968-09-05 A process for the production of very High-Viscosity-Index Lubricating Oils

Publications (1)

Publication Number Publication Date
GB1182885A true GB1182885A (en) 1970-03-04

Family

ID=10423877

Family Applications (1)

Application Number Title Priority Date Filing Date
GB42311/68A Expired GB1182885A (en) 1968-09-05 1968-09-05 A process for the production of very High-Viscosity-Index Lubricating Oils

Country Status (10)

Country Link
US (1) US3663422A (en)
AT (1) AT295716B (en)
BE (1) BE738357A (en)
CA (1) CA945096A (en)
CH (1) CH524681A (en)
DE (1) DE1944757A1 (en)
FR (1) FR2019327B1 (en)
GB (1) GB1182885A (en)
NL (1) NL6913396A (en)
NO (1) NO125493B (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1993004147A1 (en) * 1991-08-27 1993-03-04 Mobil Oil Ag Carburetor fuel additive
RU2287555C1 (en) * 2005-11-15 2006-11-20 ООО "Компания Катахим" Method of production of high-viscosity base-stock oils

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4515680A (en) * 1983-05-16 1985-05-07 Ashland Oil, Inc. Naphthenic lube oils
GB8425837D0 (en) * 1984-10-12 1984-11-21 Shell Int Research Manufacture of lubricating base oils
GB8518940D0 (en) * 1985-07-26 1985-09-04 Shell Int Research Manufacture of lubricating base oils
US5059299A (en) * 1987-12-18 1991-10-22 Exxon Research And Engineering Company Method for isomerizing wax to lube base oils
US4992159A (en) * 1988-12-16 1991-02-12 Exxon Research And Engineering Company Upgrading waxy distillates and raffinates by the process of hydrotreating and hydroisomerization
US5167847A (en) * 1990-05-21 1992-12-01 Exxon Research And Engineering Company Process for producing transformer oil from a hydrocracked stock
US5376257A (en) * 1993-08-02 1994-12-27 Nippon Petroleum Refining Company, Limited Process for feed oil refining for production of lubricating oil
CA2260104C (en) * 1996-07-16 2003-12-30 Chevron U.S.A. Inc. Base stock lube oil manufacturing process
AU2002240859A1 (en) * 2000-12-19 2002-07-01 Shell Internationale Research Maatschappij B.V. Process to prepare a spindle oil, light machine oil and a medium machine oil
CN114350395B (en) * 2021-04-21 2022-09-23 山东省新睿化工科技有限公司 Special asphalt for producing graphite electrode raw material, calcined coke and metallurgical coke and preparation process thereof

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3078222A (en) * 1960-07-27 1963-02-19 Gulf Research Development Co Preparation of multi-grade lubricating oil by severe hydrogenation and urea adduction
GB1006508A (en) * 1962-01-12 1965-10-06 British Petroleum Co Improvements relating to the production of lubricating oils
FR1333117A (en) * 1962-05-23 1963-07-26 British Petroleum Co Improvements relating to the production of lubricating oils
FR1521459A (en) * 1966-03-07 1968-04-19 Gulf Research Development Co Process for improving lubricating oils and catalyst that can be used for its implementation
US3328287A (en) * 1966-06-02 1967-06-27 Mobil Oil Corp Production of lubricating oils from resin extracts

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1993004147A1 (en) * 1991-08-27 1993-03-04 Mobil Oil Ag Carburetor fuel additive
RU2287555C1 (en) * 2005-11-15 2006-11-20 ООО "Компания Катахим" Method of production of high-viscosity base-stock oils

Also Published As

Publication number Publication date
FR2019327A1 (en) 1970-07-03
DE1944757A1 (en) 1970-03-12
NO125493B (en) 1972-09-18
AT295716B (en) 1972-01-10
BE738357A (en) 1970-03-03
US3663422A (en) 1972-05-16
CA945096A (en) 1974-04-09
FR2019327B1 (en) 1973-12-21
NL6913396A (en) 1970-03-09
CH524681A (en) 1972-06-30

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Legal Events

Date Code Title Description
PS Patent sealed [section 19, patents act 1949]
PLNP Patent lapsed through nonpayment of renewal fees