GB1182143A - Bleaching Compositions and Methods. - Google Patents
Bleaching Compositions and Methods.Info
- Publication number
- GB1182143A GB1182143A GB8253/67A GB825367A GB1182143A GB 1182143 A GB1182143 A GB 1182143A GB 8253/67 A GB8253/67 A GB 8253/67A GB 825367 A GB825367 A GB 825367A GB 1182143 A GB1182143 A GB 1182143A
- Authority
- GB
- United Kingdom
- Prior art keywords
- acid
- salt
- per salt
- detergent
- sodium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000203 mixture Substances 0.000 title abstract 6
- 238000004061 bleaching Methods 0.000 title 1
- 238000000034 method Methods 0.000 title 1
- 150000003839 salts Chemical class 0.000 abstract 14
- 239000012190 activator Substances 0.000 abstract 7
- 239000002738 chelating agent Substances 0.000 abstract 6
- 239000003599 detergent Substances 0.000 abstract 6
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 abstract 4
- 150000002736 metal compounds Chemical class 0.000 abstract 4
- -1 phenyl ester Chemical class 0.000 abstract 4
- WFDIJRYMOXRFFG-UHFFFAOYSA-N Acetic anhydride Chemical compound CC(=O)OC(C)=O WFDIJRYMOXRFFG-UHFFFAOYSA-N 0.000 abstract 3
- 229910052751 metal Inorganic materials 0.000 abstract 3
- 239000002184 metal Substances 0.000 abstract 3
- 229920002134 Carboxymethyl cellulose Polymers 0.000 abstract 2
- 239000001856 Ethyl cellulose Substances 0.000 abstract 2
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 abstract 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract 2
- ONIBWKKTOPOVIA-UHFFFAOYSA-N Proline Chemical group OC(=O)C1CCCN1 ONIBWKKTOPOVIA-UHFFFAOYSA-N 0.000 abstract 2
- 239000004115 Sodium Silicate Substances 0.000 abstract 2
- 239000007844 bleaching agent Substances 0.000 abstract 2
- 239000001768 carboxy methyl cellulose Substances 0.000 abstract 2
- 235000010948 carboxy methyl cellulose Nutrition 0.000 abstract 2
- 239000008112 carboxymethyl-cellulose Substances 0.000 abstract 2
- WJJMNDUMQPNECX-UHFFFAOYSA-N dipicolinic acid Chemical group OC(=O)C1=CC=CC(C(O)=O)=N1 WJJMNDUMQPNECX-UHFFFAOYSA-N 0.000 abstract 2
- 229920001249 ethyl cellulose Polymers 0.000 abstract 2
- 235000019325 ethyl cellulose Nutrition 0.000 abstract 2
- TWBYWOBDOCUKOW-UHFFFAOYSA-N isonicotinic acid Chemical group OC(=O)C1=CC=NC=C1 TWBYWOBDOCUKOW-UHFFFAOYSA-N 0.000 abstract 2
- 230000003287 optical effect Effects 0.000 abstract 2
- SIOXPEMLGUPBBT-UHFFFAOYSA-N picolinic acid Chemical group OC(=O)C1=CC=CC=N1 SIOXPEMLGUPBBT-UHFFFAOYSA-N 0.000 abstract 2
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 abstract 2
- 229910052911 sodium silicate Inorganic materials 0.000 abstract 2
- 235000019794 sodium silicate Nutrition 0.000 abstract 2
- 229910052938 sodium sulfate Inorganic materials 0.000 abstract 2
- 235000011152 sodium sulphate Nutrition 0.000 abstract 2
- 235000019832 sodium triphosphate Nutrition 0.000 abstract 2
- NOGFHTGYPKWWRX-UHFFFAOYSA-N 2,2,6,6-tetramethyloxan-4-one Chemical compound CC1(C)CC(=O)CC(C)(C)O1 NOGFHTGYPKWWRX-UHFFFAOYSA-N 0.000 abstract 1
- JPSKCQCQZUGWNM-UHFFFAOYSA-N 2,7-Oxepanedione Chemical compound O=C1CCCCC(=O)O1 JPSKCQCQZUGWNM-UHFFFAOYSA-N 0.000 abstract 1
- LAZUHOPLTJOKNS-UHFFFAOYSA-N 2-(2-chloroacetyl)oxybenzoic acid Chemical compound OC(=O)C1=CC=CC=C1OC(=O)CCl LAZUHOPLTJOKNS-UHFFFAOYSA-N 0.000 abstract 1
- FALRKNHUBBKYCC-UHFFFAOYSA-N 2-(chloromethyl)pyridine-3-carbonitrile Chemical compound ClCC1=NC=CC=C1C#N FALRKNHUBBKYCC-UHFFFAOYSA-N 0.000 abstract 1
- GDBUZIKSJGRBJP-UHFFFAOYSA-N 4-acetoxy benzoic acid Chemical compound CC(=O)OC1=CC=C(C(O)=O)C=C1 GDBUZIKSJGRBJP-UHFFFAOYSA-N 0.000 abstract 1
- LTUUGSGSUZRPRV-UHFFFAOYSA-N 6-methylpyridine-2-carboxylic acid Chemical group CC1=CC=CC(C(O)=O)=N1 LTUUGSGSUZRPRV-UHFFFAOYSA-N 0.000 abstract 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 abstract 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 abstract 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 abstract 1
- 239000001828 Gelatine Substances 0.000 abstract 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract 1
- 229910002651 NO3 Inorganic materials 0.000 abstract 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 abstract 1
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 abstract 1
- 239000004698 Polyethylene Substances 0.000 abstract 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 abstract 1
- DGEZNRSVGBDHLK-UHFFFAOYSA-N [1,10]phenanthroline Chemical group C1=CN=C2C3=NC=CC=C3C=CC2=C1 DGEZNRSVGBDHLK-UHFFFAOYSA-N 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 125000001931 aliphatic group Chemical group 0.000 abstract 1
- 229910052783 alkali metal Inorganic materials 0.000 abstract 1
- 150000001340 alkali metals Chemical class 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 239000002585 base Substances 0.000 abstract 1
- 229910021538 borax Inorganic materials 0.000 abstract 1
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 abstract 1
- 150000001244 carboxylic acid anhydrides Chemical class 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 229910017052 cobalt Inorganic materials 0.000 abstract 1
- 239000010941 cobalt Substances 0.000 abstract 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 abstract 1
- 235000019864 coconut oil Nutrition 0.000 abstract 1
- 239000003240 coconut oil Substances 0.000 abstract 1
- 230000009918 complex formation Effects 0.000 abstract 1
- 239000002131 composite material Substances 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 229910052802 copper Inorganic materials 0.000 abstract 1
- 239000010949 copper Substances 0.000 abstract 1
- 230000007797 corrosion Effects 0.000 abstract 1
- 238000005260 corrosion Methods 0.000 abstract 1
- QDOXWKRWXJOMAK-UHFFFAOYSA-N dichromium trioxide Chemical compound O=[Cr]O[Cr]=O QDOXWKRWXJOMAK-UHFFFAOYSA-N 0.000 abstract 1
- 235000014113 dietary fatty acids Nutrition 0.000 abstract 1
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 abstract 1
- NDORGWUNFGHGKU-UHFFFAOYSA-N dodecanoic acid;sodium Chemical compound [Na].CCCCCCCCCCCC(O)=O NDORGWUNFGHGKU-UHFFFAOYSA-N 0.000 abstract 1
- 230000007613 environmental effect Effects 0.000 abstract 1
- 229940117927 ethylene oxide Drugs 0.000 abstract 1
- 239000000194 fatty acid Substances 0.000 abstract 1
- 229930195729 fatty acid Natural products 0.000 abstract 1
- 150000004665 fatty acids Chemical class 0.000 abstract 1
- 229920000159 gelatin Polymers 0.000 abstract 1
- 235000019322 gelatine Nutrition 0.000 abstract 1
- VANNPISTIUFMLH-UHFFFAOYSA-N glutaric anhydride Chemical compound O=C1CCCC(=O)O1 VANNPISTIUFMLH-UHFFFAOYSA-N 0.000 abstract 1
- 239000003112 inhibitor Substances 0.000 abstract 1
- 229910052742 iron Inorganic materials 0.000 abstract 1
- SUMDYPCJJOFFON-UHFFFAOYSA-N isethionic acid Chemical compound OCCS(O)(=O)=O SUMDYPCJJOFFON-UHFFFAOYSA-N 0.000 abstract 1
- LVPMIMZXDYBCDF-UHFFFAOYSA-N isocinchomeronic acid Chemical group OC(=O)C1=CC=C(C(O)=O)N=C1 LVPMIMZXDYBCDF-UHFFFAOYSA-N 0.000 abstract 1
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 abstract 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 abstract 1
- UMHTVKGNHVUENZ-UHFFFAOYSA-N n,n',n'-triacetylacetohydrazide Chemical compound CC(=O)N(C(C)=O)N(C(C)=O)C(C)=O UMHTVKGNHVUENZ-UHFFFAOYSA-N 0.000 abstract 1
- KBDYPDHUODKDRK-UHFFFAOYSA-N n-acetyl-n-phenylacetamide Chemical compound CC(=O)N(C(C)=O)C1=CC=CC=C1 KBDYPDHUODKDRK-UHFFFAOYSA-N 0.000 abstract 1
- 229910052759 nickel Inorganic materials 0.000 abstract 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 abstract 1
- 230000001590 oxidative effect Effects 0.000 abstract 1
- 239000002245 particle Substances 0.000 abstract 1
- VLTRZXGMWDSKGL-UHFFFAOYSA-M perchlorate Inorganic materials [O-]Cl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-M 0.000 abstract 1
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical compound OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 abstract 1
- JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 abstract 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 1
- 229940081066 picolinic acid Drugs 0.000 abstract 1
- 229920000573 polyethylene Polymers 0.000 abstract 1
- 239000005020 polyethylene terephthalate Substances 0.000 abstract 1
- 229920000139 polyethylene terephthalate Polymers 0.000 abstract 1
- 229920000915 polyvinyl chloride Polymers 0.000 abstract 1
- 239000004800 polyvinyl chloride Substances 0.000 abstract 1
- GJAWHXHKYYXBSV-UHFFFAOYSA-N quinolinic acid Chemical group OC(=O)C1=CC=CN=C1C(O)=O GJAWHXHKYYXBSV-UHFFFAOYSA-N 0.000 abstract 1
- 239000000344 soap Substances 0.000 abstract 1
- 239000011734 sodium Substances 0.000 abstract 1
- 229910052708 sodium Inorganic materials 0.000 abstract 1
- 239000004328 sodium tetraborate Substances 0.000 abstract 1
- 235000010339 sodium tetraborate Nutrition 0.000 abstract 1
- HFQQZARZPUDIFP-UHFFFAOYSA-M sodium;2-dodecylbenzenesulfonate Chemical compound [Na+].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O HFQQZARZPUDIFP-UHFFFAOYSA-M 0.000 abstract 1
- MWNQXXOSWHCCOZ-UHFFFAOYSA-L sodium;oxido carbonate Chemical compound [Na+].[O-]OC([O-])=O MWNQXXOSWHCCOZ-UHFFFAOYSA-L 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- 125000001424 substituent group Chemical group 0.000 abstract 1
- 229910021653 sulphate ion Inorganic materials 0.000 abstract 1
- 239000000271 synthetic detergent Substances 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3902—Organic or inorganic per-compounds combined with specific additives
- C11D3/3905—Bleach activators or bleach catalysts
- C11D3/3932—Inorganic compounds or complexes
Landscapes
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
1,182,143. Detergent bleach. UNITED STATES BORAX & CHEMICAL CORP. 21 Feb., 1967 [1 March, 1966], No. 8253/67. Heading C5D. [Also in Division D1] A detergent composition comprises an inorganic per salt bleaching agent, a watersoluble salt or oxide of chromium, manganese, iron, cobalt, nickel or copper, a chelating agent stable under oxidizing conditions and having at 20‹ C. a pK. of 2-10 with the metal, the pK, being the logarithm to base 10 of the first complex formation constant, and a per salt activator which is a carboxylic acid anhydride, a substituted phenyl ester of an aliphatic acid having at least one electronegative substituent on the phenyl ring, an N,N-diacyl compound or an acyl cyanurate, in the molar proportions: per salt 1, metal salt or oxide 0À0005-0À01, chelating agent 0À001-0À1 and per salt activator 0À05-1À5. The per salt may be an alkali metal perborate, persulphate, percarbonate, perpyrophosphate or persilicate and the metal salt may be a chloride, sulphate, nitrate, perchlorate or acetate. The chelating agent may be pyrrolidine - 2 - carboxylic acid, pyridine - 2,6 - dicarboxylic acid, picolinic acid, 6-methylpicolinic acid, isonicotinic acid, quinolinic acid, isocinchomeronic acid, 1,10-phenanthroline or an alkyl substituted derivative thereof or 2,2<SP>1</SP>-bipyridine. Suitable per salt activators are succinic, phthalic, adipic, benzoic, glutaric or acetic anhydride, sodium p-acetoxy- or pbutyroxy-benzene sulphonate, acetyl- or chloroacetyl-salicylic acid, p-acetoxybenzoic acid, N,N-diacetylaniline, tri- or tetra-acetyl methylenediamine, tetra-acetyl-hydrazine, di- or trisacetylcyanurate or trispropionyl cyanurate. The composition may comprise a soap or synthetic detergent, water softeners, anti-redeposition agents and corrosion inhibitors, suitable detergent compositions comprising sodium dodecylbenzene sulphonate, sodium lauric acid isethionate, lauryl alcohol, the monoethanolamide of coconut oil fatty acid, sodium tripolyphosphate, sodium silicate, carboxymethyl cellulose, sodium sulphate and an optical brightener or nonylphenol condensed with 9 molecules of ethyleneoxide, sodium tripolyphosphate, sodium silicate, carboxymethyl cellulose, sodium sulphate and an optical brightener. The composition is preferably packaged so that the unchelated metal compound is kept separate from the per salt, and the per salt activator may be protected from environmental moisture by encapsulating particles or droplets thereof in gelatine, ethyl cellulose or an emulsifiable wax. The metal compound may be mixed with the activator and encapsulated or reacted with the chelating agent prior to mixing it with the detergent and per salt. Alternatively composite tablets containing the detergent, per salt, activator, metal compound and chelating agent may be used or the composition packaged in two separate packets made of polyethylene, polyethylene terephthalate, polyvinyl chloride or ethyl cellulose, the activator and metal compound being placed in one packet and the detergent, per salt and chelating agent in the other.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US53078966A | 1966-03-01 | 1966-03-01 | |
| US81610269A | 1969-04-14 | 1969-04-14 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1182143A true GB1182143A (en) | 1970-02-25 |
Family
ID=27063371
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB8253/67A Expired GB1182143A (en) | 1966-03-01 | 1967-02-21 | Bleaching Compositions and Methods. |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US3532634A (en) |
| AT (1) | AT277143B (en) |
| BE (1) | BE694721A (en) |
| CH (1) | CH497595A (en) |
| DE (1) | DE1594877C3 (en) |
| FR (1) | FR1515338A (en) |
| GB (1) | GB1182143A (en) |
| NL (1) | NL6703189A (en) |
| SE (1) | SE346021B (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4077768A (en) | 1975-06-20 | 1978-03-07 | The Procter & Gamble Company | Inhibiting dye transfer in washing or bleaching |
| US4430243A (en) | 1981-08-08 | 1984-02-07 | The Procter & Gamble Company | Bleach catalyst compositions and use thereof in laundry bleaching and detergent compositions |
| WO1995034628A1 (en) * | 1994-06-13 | 1995-12-21 | Unilever N.V. | Bleach activation |
Families Citing this family (64)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| LU61828A1 (en) * | 1970-10-07 | 1972-06-28 | ||
| US3919107A (en) * | 1973-03-23 | 1975-11-11 | Procter & Gamble | Built detergent compositions containing dextrin esters of poly carboxylic acids |
| US4395344A (en) * | 1973-05-21 | 1983-07-26 | The Clorox Company | Drain opener composition |
| JPS5313355B2 (en) * | 1974-03-18 | 1978-05-09 | ||
| GB1565807A (en) * | 1975-12-18 | 1980-04-23 | Uilever Ltd | Process and compositions for cleaning fabrics |
| US4179390A (en) * | 1976-10-06 | 1979-12-18 | The Procter & Gamble Company | Laundry additive product |
| DE2719235B2 (en) * | 1977-04-29 | 1980-07-17 | Bosch-Siemens Hausgeraete Gmbh, 7000 Stuttgart | Washing process and automatic washing machine to carry out the washing process |
| DE2733849A1 (en) * | 1977-07-27 | 1979-02-15 | Basf Ag | SOLID COLD BLEACH ACTIVATORS FOR COMPOUNDS RELEASING ACTIVE OXYGEN |
| US4111651A (en) * | 1977-10-03 | 1978-09-05 | Fmc Corporation | Sulfonic anhydrides in peroxygen bleaching |
| US4133637A (en) * | 1977-10-03 | 1979-01-09 | Fmc Corporation | Oxybis(diacyloxyboranes) as peroxygen activators |
| US4115058A (en) * | 1977-10-03 | 1978-09-19 | Fmc Corporation | Aromatic sulfonic anhydrides as peroxygen activators |
| US4128490A (en) * | 1977-10-03 | 1978-12-05 | Fmc Corporation | Phenyl sulfonate esters as peroxygen activators |
| US4110074A (en) * | 1977-10-03 | 1978-08-29 | Fmc Corporation | Mixed carboxylic/sulfonic anhydrides in peroxygen bleaching |
| US4207070A (en) * | 1978-10-10 | 1980-06-10 | Fmc Corporation | Peroxygen bleaching and compositions therefor |
| US4214061A (en) * | 1978-11-03 | 1980-07-22 | The B. F. Goodrich Company | Pressure-sensitive adhesive |
| US4215003A (en) * | 1978-11-20 | 1980-07-29 | Fmc Corporation | Peroxygen bleaching and compositions therefor |
| US4202786A (en) * | 1978-12-22 | 1980-05-13 | Fmc Corporation | Peroxygen bleaching and compositions therefor |
| US4212757A (en) * | 1978-12-22 | 1980-07-15 | Fmc Corporation | Peroxygen bleaching and compositions therefor |
| US4194987A (en) * | 1978-12-26 | 1980-03-25 | Fmc Corporation | Peroxygen bleaching and compositions therefor |
| JPS5598750A (en) * | 1979-01-23 | 1980-07-28 | Fuji Photo Film Co Ltd | Photographic bleaching composition |
| US4481129A (en) * | 1981-12-23 | 1984-11-06 | Lever Brothers Company | Bleach compositions |
| US4488980A (en) * | 1982-12-17 | 1984-12-18 | Lever Brothers Company | Detergent compositions |
| US4478733A (en) * | 1982-12-17 | 1984-10-23 | Lever Brothers Company | Detergent compositions |
| GB8311865D0 (en) * | 1983-04-29 | 1983-06-02 | Procter & Gamble Ltd | Bleach compositions |
| GB8312185D0 (en) * | 1983-05-04 | 1983-06-08 | Unilever Plc | Bleaching and cleaning composition |
| GB8316760D0 (en) * | 1983-06-20 | 1983-07-20 | Unilever Plc | Detergent bleach compositions |
| GB8316761D0 (en) * | 1983-06-20 | 1983-07-20 | Unilever Plc | Detergent bleach compositions |
| GB8329762D0 (en) * | 1983-11-08 | 1983-12-14 | Unilever Plc | Manganese adjuncts |
| GB8329761D0 (en) * | 1983-11-08 | 1983-12-14 | Unilever Plc | Metal adjuncts |
| NZ210397A (en) * | 1983-12-06 | 1986-11-12 | Unilever Plc | Alkaline built detergent bleach composition containing a peroxide compound and a manganese compound |
| NZ210398A (en) * | 1983-12-06 | 1986-11-12 | Unilever Plc | Detergent bleach composition containing a peroxide compound and a manganese compound |
| GB8405189D0 (en) * | 1984-02-28 | 1984-04-04 | Interox Chemicals Ltd | Peroxide activation |
| CS249980B1 (en) * | 1984-02-29 | 1987-04-16 | Jaroslav Simunek | Laundry agent with bleaching efficiency |
| US4536183A (en) * | 1984-04-09 | 1985-08-20 | Lever Brothers Company | Manganese bleach activators |
| US4623357A (en) * | 1985-04-02 | 1986-11-18 | Lever Brothers Company | Bleach compositions |
| US4601845A (en) * | 1985-04-02 | 1986-07-22 | Lever Brothers Company | Bleaching compositions containing mixed metal cations adsorbed onto aluminosilicate support materials |
| US4711748A (en) * | 1985-12-06 | 1987-12-08 | Lever Brothers Company | Preparation of bleach catalyst aggregates of manganese cation impregnated aluminosilicates by high velocity granulation |
| US4655782A (en) * | 1985-12-06 | 1987-04-07 | Lever Brothers Company | Bleach composition of detergent base powder and agglomerated manganese-alluminosilicate catalyst having phosphate salt distributed therebetween |
| US4731196A (en) * | 1986-10-28 | 1988-03-15 | Ethyl Corporation | Process for making bleach activator |
| GB8629837D0 (en) * | 1986-12-13 | 1987-01-21 | Interox Chemicals Ltd | Bleach activation |
| GB8908416D0 (en) * | 1989-04-13 | 1989-06-01 | Unilever Plc | Bleach activation |
| GB8915781D0 (en) * | 1989-07-10 | 1989-08-31 | Unilever Plc | Bleach activation |
| GB9003741D0 (en) * | 1990-02-19 | 1990-04-18 | Unilever Plc | Bleach activation |
| US5041142A (en) * | 1990-03-23 | 1991-08-20 | Lever Brothers Company, Division Of Conopco Inc. | Peroxymetallates and their use as bleach activating catalysts |
| US5380458A (en) * | 1992-10-02 | 1995-01-10 | Colgate-Palmolive Co. | Stabilized hypohalite compositions |
| CA2211717C (en) * | 1995-02-02 | 2001-04-03 | The Procter & Gamble Company | Automatic dishwashing compositions comprising cobalt (iii) catalysts |
| CA2212115C (en) * | 1995-02-02 | 2001-04-24 | The Procter & Gamble Company | Automatic dishwashing compositions comprising cobalt catalysts |
| JPH10513214A (en) * | 1995-02-02 | 1998-12-15 | ザ、プロクター、エンド、ギャンブル、カンパニー | Automatic dishwashing composition containing cobalt chelation catalyst |
| DE19600159A1 (en) | 1996-01-04 | 1997-07-10 | Hoechst Ag | Bleaching agent systems containing bis- and tris (mu-oxo) -di-manganese complex salts |
| DE19606343A1 (en) | 1996-02-21 | 1997-08-28 | Hoechst Ag | Bleach |
| KR100470891B1 (en) * | 1997-12-30 | 2005-06-07 | 주식회사 엘지생활건강 | Bleach Detergent Composition Containing Manganese Complex |
| GB0118932D0 (en) * | 2001-08-02 | 2001-09-26 | Unilever Plc | Improvements relating to laundry compositions |
| US7476333B2 (en) * | 2005-06-22 | 2009-01-13 | Truox, Inc. | Composition and method for reducing chemical oxygen demand in water |
| US7695631B2 (en) * | 2005-06-22 | 2010-04-13 | Truox, Inc. | Composition and method for reducing chemical oxygen demand in water |
| US7794607B2 (en) * | 2005-06-22 | 2010-09-14 | Truox, Inc. | Composition and method for enhanced sanitation and oxidation of aqueous systems |
| US7572390B2 (en) * | 2005-06-22 | 2009-08-11 | Truox, Inc. | Composition and method for reducing chemical oxygen demand in water |
| JP5150237B2 (en) * | 2007-12-19 | 2013-02-20 | ライオン株式会社 | Oxidation catalyst for sterilization and sterilization, and oxidization catalyst particles for sterilization and sterilization containing the catalyst |
| JP5401034B2 (en) * | 2007-12-19 | 2014-01-29 | ライオン株式会社 | Bleaching aid and bleaching aid particles containing the bleaching aid |
| DE102008038376A1 (en) * | 2008-08-19 | 2010-02-25 | Clariant International Ltd. | Process for the preparation of 3,7-diazabicyclo [3.3.1] nonane compounds |
| DE102008045215A1 (en) | 2008-08-30 | 2010-03-04 | Clariant International Ltd. | Use of manganese oxalates as bleaching catalysts |
| DE102008045207A1 (en) * | 2008-08-30 | 2010-03-04 | Clariant International Limited | Bleach catalyst mixtures consisting of manganese salts and oxalic acid or salts thereof |
| DE102008064009A1 (en) | 2008-12-19 | 2010-06-24 | Clariant International Ltd. | Process for the preparation of 3,7-diaza-bicyclo [3.3.1] nonane-metal complexes |
| EP3677664B1 (en) * | 2019-01-04 | 2021-05-19 | Henkel AG & Co. KGaA | Non-enzymatic removal of proteinaceous soils |
| EP3677665B1 (en) * | 2019-01-04 | 2021-05-05 | Henkel AG & Co. KGaA | Detergents, especially dishwashing detergents, comprising salicylidene-serine |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB855735A (en) * | 1958-05-09 | 1960-12-07 | Unilever Ltd | Bleaching processes and compositions |
| CA800223A (en) * | 1959-06-19 | 1968-12-03 | General Electric Company | Edge winding of electro-magnetic cores |
| BE614629A (en) * | 1961-03-24 | |||
| US3156654A (en) * | 1961-06-19 | 1964-11-10 | Shell Oil Co | Bleaching |
| US3332882A (en) * | 1964-12-18 | 1967-07-25 | Fmc Corp | Peroxygen compositions |
| CA793720A (en) * | 1964-12-28 | 1968-09-03 | G. Mackellar Donald | Peroxygen compositions |
-
1967
- 1967-02-21 GB GB8253/67A patent/GB1182143A/en not_active Expired
- 1967-02-27 BE BE694721D patent/BE694721A/xx unknown
- 1967-02-28 AT AT194267A patent/AT277143B/en not_active IP Right Cessation
- 1967-02-28 NL NL6703189A patent/NL6703189A/xx unknown
- 1967-03-01 FR FR97007A patent/FR1515338A/en not_active Expired
- 1967-03-01 DE DE1594877A patent/DE1594877C3/en not_active Expired
- 1967-03-01 SE SE2829/67A patent/SE346021B/xx unknown
- 1967-03-01 CH CH297867A patent/CH497595A/en not_active IP Right Cessation
-
1969
- 1969-04-14 US US816102A patent/US3532634A/en not_active Expired - Lifetime
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4077768A (en) | 1975-06-20 | 1978-03-07 | The Procter & Gamble Company | Inhibiting dye transfer in washing or bleaching |
| US4430243A (en) | 1981-08-08 | 1984-02-07 | The Procter & Gamble Company | Bleach catalyst compositions and use thereof in laundry bleaching and detergent compositions |
| WO1995034628A1 (en) * | 1994-06-13 | 1995-12-21 | Unilever N.V. | Bleach activation |
Also Published As
| Publication number | Publication date |
|---|---|
| SE346021B (en) | 1972-06-19 |
| FR1515338A (en) | 1968-03-01 |
| CH497595A (en) | 1970-10-15 |
| BE694721A (en) | 1967-08-28 |
| AT277143B (en) | 1969-12-10 |
| DE1594877B2 (en) | 1974-11-14 |
| DE1594877C3 (en) | 1975-06-26 |
| NL6703189A (en) | 1967-09-04 |
| DE1594877A1 (en) | 1971-05-06 |
| US3532634A (en) | 1970-10-06 |
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