GB1174719A - Chromogenic Printing Ink - Google Patents
Chromogenic Printing InkInfo
- Publication number
- GB1174719A GB1174719A GB50771/68A GB5077168A GB1174719A GB 1174719 A GB1174719 A GB 1174719A GB 50771/68 A GB50771/68 A GB 50771/68A GB 5077168 A GB5077168 A GB 5077168A GB 1174719 A GB1174719 A GB 1174719A
- Authority
- GB
- United Kingdom
- Prior art keywords
- bis
- phthalide
- methylindol
- xanthene
- viz
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 abstract 3
- -1 1 - ethyl Chemical group 0.000 abstract 2
- ZKURGBYDCVNWKH-UHFFFAOYSA-N [3,7-bis(dimethylamino)phenothiazin-10-yl]-phenylmethanone Chemical compound C12=CC=C(N(C)C)C=C2SC2=CC(N(C)C)=CC=C2N1C(=O)C1=CC=CC=C1 ZKURGBYDCVNWKH-UHFFFAOYSA-N 0.000 abstract 2
- 230000002378 acidificating effect Effects 0.000 abstract 2
- 239000000976 ink Substances 0.000 abstract 2
- WNZQDUSMALZDQF-UHFFFAOYSA-N isobenzofuranone Natural products C1=CC=C2C(=O)OCC2=C1 WNZQDUSMALZDQF-UHFFFAOYSA-N 0.000 abstract 2
- LIZLYZVAYZQVPG-UHFFFAOYSA-N (3-bromo-2-fluorophenyl)methanol Chemical compound OCC1=CC=CC(Br)=C1F LIZLYZVAYZQVPG-UHFFFAOYSA-N 0.000 abstract 1
- NGIMIRGNQFEQIV-UHFFFAOYSA-N 2H-benzo[a]xanthene Chemical compound C=1CC=CC=2C1C1=CC3=CC=CC=C3OC1=CC2 NGIMIRGNQFEQIV-UHFFFAOYSA-N 0.000 abstract 1
- VXVRAGONKSWKEZ-UHFFFAOYSA-N 3,3-bis(1,2-dimethylindol-3-yl)-2-benzofuran-1-one Chemical compound C1=CC=C2C(C3(C4=CC=CC=C4C(=O)O3)C3=C(N(C4=CC=CC=C43)C)C)=C(C)N(C)C2=C1 VXVRAGONKSWKEZ-UHFFFAOYSA-N 0.000 abstract 1
- SZHWJOYOAUKPIU-UHFFFAOYSA-N 6-(dimethylamino)-3,3-bis[1-(dimethylamino)cyclohexa-2,4-dien-1-yl]-2-benzofuran-1-one Chemical compound CN(C1(CC=CC=C1)C1(OC(=O)C2=CC(=CC=C12)N(C)C)C1(CC=CC=C1)N(C)C)C SZHWJOYOAUKPIU-UHFFFAOYSA-N 0.000 abstract 1
- 239000005995 Aluminium silicate Substances 0.000 abstract 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 abstract 1
- CYTYCFOTNPOANT-UHFFFAOYSA-N Perchloroethylene Chemical group ClC(Cl)=C(Cl)Cl CYTYCFOTNPOANT-UHFFFAOYSA-N 0.000 abstract 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 1
- 229910021536 Zeolite Inorganic materials 0.000 abstract 1
- 235000012211 aluminium silicate Nutrition 0.000 abstract 1
- 229960000892 attapulgite Drugs 0.000 abstract 1
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 abstract 1
- 239000012965 benzophenone Substances 0.000 abstract 1
- 125000006267 biphenyl group Chemical group 0.000 abstract 1
- 238000009835 boiling Methods 0.000 abstract 1
- UFULAYFCSOUIOV-UHFFFAOYSA-N cysteamine Chemical compound NCCS UFULAYFCSOUIOV-UHFFFAOYSA-N 0.000 abstract 1
- 125000004663 dialkyl amino group Chemical group 0.000 abstract 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 abstract 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 229920000620 organic polymer Polymers 0.000 abstract 1
- 239000003960 organic solvent Substances 0.000 abstract 1
- 229910052625 palygorskite Inorganic materials 0.000 abstract 1
- 239000003208 petroleum Substances 0.000 abstract 1
- 239000003209 petroleum derivative Substances 0.000 abstract 1
- 239000000376 reactant Substances 0.000 abstract 1
- 230000001235 sensitizing effect Effects 0.000 abstract 1
- 239000000741 silica gel Substances 0.000 abstract 1
- 229910002027 silica gel Inorganic materials 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- 239000008096 xylene Substances 0.000 abstract 1
- 239000010457 zeolite Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/50—Sympathetic, colour changing or similar inks
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/124—Duplicating or marking methods; Sheet materials for use therein using pressure to make a masked colour visible, e.g. to make a coloured support visible, to create an opaque or transparent pattern, or to form colour by uniting colour-forming components
- B41M5/132—Chemical colour-forming components; Additives or binders therefor
- B41M5/136—Organic colour formers, e.g. leuco dyes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/124—Duplicating or marking methods; Sheet materials for use therein using pressure to make a masked colour visible, e.g. to make a coloured support visible, to create an opaque or transparent pattern, or to form colour by uniting colour-forming components
- B41M5/132—Chemical colour-forming components; Additives or binders therefor
- B41M5/136—Organic colour formers, e.g. leuco dyes
- B41M5/145—Organic colour formers, e.g. leuco dyes with a lactone or lactam ring
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/124—Duplicating or marking methods; Sheet materials for use therein using pressure to make a masked colour visible, e.g. to make a coloured support visible, to create an opaque or transparent pattern, or to form colour by uniting colour-forming components
- B41M5/165—Duplicating or marking methods; Sheet materials for use therein using pressure to make a masked colour visible, e.g. to make a coloured support visible, to create an opaque or transparent pattern, or to form colour by uniting colour-forming components characterised by the use of microcapsules; Special solvents for incorporating the ingredients
- B41M5/1655—Solvents
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Color Printing (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Printing Methods (AREA)
Abstract
1,174,719. Chromogenic printing inks. NATIONAL CASH REGISTER CO. 25 Oct., 1968 [6 Dec., 1967], No. 50771/68. Heading C4A. A normally colourless, basic, chromogenic printing ink which reacts with an acidic recording material sensitizing substance to produce a black colour comprises an organic solvent having dissolved therein 3,3-bis-(1-dimethylaminophenyl) - 6 - dimethylaminophthalide, viz. crystal violet lactone and/or 3,7-bis-(dimethylamino)-10-benzoyl phenothiazine, viz. benzoyl leuco methylene blue in combination with (i) 4,4<SP>1</SP> - bis-(dimethylamino)benzophenone-N- phenyl imide (orange); or in combination with (ii) 4,4<SP>1</SP> - bis - (dialkylamino)benzophenone (yellow) and any one of the following (red): 3,3 - bis - (1,2 - dimethylindol - 3yl)phthalide; 3 - (1 - ethyl, 2 - methylindol - 3yl) - 3 - (2- methylindol - 3yl) phthalide; 2 - chloro - 6- diethylamino - 3 - methylspiro [9 - H - xanthene- 9,1<SP>1</SP> - phthalide]; or 9 - diethylaminospiro [1,2 - H - benzo(a)xanthene - 12,1<SP>1 </SP>- phthalide]. Specified solvents are toluene, petroleum distillate, perchloroethylene, xylene, high boiling petroleum fractions and chlorinated diphenyls. The acidic reactant may be kaolin, attapulgite, silica gel, a zeolite or an organic polymer.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US68859667A | 1967-12-06 | 1967-12-06 | |
| US80713069A | 1969-03-13 | 1969-03-13 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1174719A true GB1174719A (en) | 1969-12-17 |
Family
ID=27104253
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB50771/68A Expired GB1174719A (en) | 1967-12-06 | 1968-10-25 | Chromogenic Printing Ink |
| GB1239705D Expired GB1239705A (en) | 1967-12-06 | 1970-02-23 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB1239705D Expired GB1239705A (en) | 1967-12-06 | 1970-02-23 |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US3525630A (en) |
| AT (1) | AT294133B (en) |
| BE (2) | BE724937A (en) |
| CH (2) | CH495414A (en) |
| DE (2) | DE1812380A1 (en) |
| FR (2) | FR1598276A (en) |
| GB (2) | GB1174719A (en) |
| NL (2) | NL6817452A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2288606A (en) * | 1994-04-22 | 1995-10-25 | Yamada Chem Co | Phenylimine derivatives of benzoyl aromatic compounds and recording material comprising the same |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4915397A (en) * | 1972-05-17 | 1974-02-09 | ||
| DE2327723C2 (en) * | 1972-05-30 | 1983-01-05 | Pilot Ink Co., Ltd., Nagoya, Aichi | Reversible thermochromatic material |
| US3940275A (en) * | 1973-01-24 | 1976-02-24 | Ncr Corporation | Record material and marking liquid |
| US4138522A (en) * | 1974-09-17 | 1979-02-06 | Fuji Photo Film Co., Ltd. | Color image forming system including a layer formed from a dried residue of a developing ink containing a polyester resin binder |
| JPS54115907A (en) * | 1977-12-02 | 1979-09-08 | Barry Graham Charles | Thin sheet printed with transparent ink* and developer eraser for said ink |
| US4239544A (en) * | 1979-04-23 | 1980-12-16 | The Mead Corporation | Jet drop printing ink composition |
| DE3507173A1 (en) * | 1985-03-01 | 1986-09-04 | Basf Ag, 6700 Ludwigshafen | COLOR IMAGE MIXTURES AND PRESSURE SENSITIVE RECORD MATERIAL CONTAINING THESE MIXTURES |
| JPS61202883A (en) * | 1985-03-06 | 1986-09-08 | Kanzaki Paper Mfg Co Ltd | Pressure-sensitive copying paper |
| US4639271A (en) * | 1985-04-24 | 1987-01-27 | Moore Business Forms, Inc. | Chromogenic mixtures |
| DE29903497U1 (en) * | 1999-02-26 | 2000-07-06 | Bundesdruckerei GmbH, 10969 Berlin | Security document with chemiluminescent properties |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL285755A (en) * | 1961-11-21 | |||
| US3455721A (en) * | 1964-12-21 | 1969-07-15 | Ncr Co | Color sensitized record material comprising phenolic resin and acid type mineral |
| US3427180A (en) * | 1965-03-31 | 1969-02-11 | Ncr Co | Pressure-sensitive record system and compositions |
-
1968
- 1968-10-25 GB GB50771/68A patent/GB1174719A/en not_active Expired
- 1968-12-02 CH CH1791268A patent/CH495414A/en not_active IP Right Cessation
- 1968-12-03 DE DE19681812380 patent/DE1812380A1/en active Pending
- 1968-12-04 FR FR1598276D patent/FR1598276A/fr not_active Expired
- 1968-12-05 NL NL6817452A patent/NL6817452A/xx unknown
- 1968-12-05 BE BE724937D patent/BE724937A/xx unknown
-
1969
- 1969-03-13 US US807130A patent/US3525630A/en not_active Expired - Lifetime
-
1970
- 1970-02-23 GB GB1239705D patent/GB1239705A/en not_active Expired
- 1970-03-11 FR FR7008632A patent/FR2037922A6/fr not_active Expired
- 1970-03-11 DE DE2011384A patent/DE2011384C3/en not_active Expired
- 1970-03-11 NL NL7003468A patent/NL7003468A/xx unknown
- 1970-03-11 BE BE747174D patent/BE747174R/en active
- 1970-03-12 CH CH357370A patent/CH524467A/en not_active IP Right Cessation
- 1970-03-12 AT AT231270A patent/AT294133B/en not_active IP Right Cessation
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2288606A (en) * | 1994-04-22 | 1995-10-25 | Yamada Chem Co | Phenylimine derivatives of benzoyl aromatic compounds and recording material comprising the same |
Also Published As
| Publication number | Publication date |
|---|---|
| DE2011384B2 (en) | 1973-03-29 |
| DE2011384A1 (en) | 1970-09-17 |
| CH495414A (en) | 1970-08-31 |
| CH524467A (en) | 1972-06-30 |
| BE724937A (en) | 1969-05-16 |
| DE2011384C3 (en) | 1973-10-25 |
| GB1239705A (en) | 1971-07-21 |
| NL7003468A (en) | 1970-09-15 |
| DE1812380A1 (en) | 1969-07-31 |
| FR2037922A6 (en) | 1970-12-31 |
| US3525630A (en) | 1970-08-25 |
| AT294133B (en) | 1971-11-10 |
| NL6817452A (en) | 1969-06-10 |
| FR1598276A (en) | 1970-08-14 |
| BE747174R (en) | 1970-08-17 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed [section 19, patents act 1949] | ||
| PLNP | Patent lapsed through nonpayment of renewal fees |