GB1173574A - Trioxane Copolymers - Google Patents
Trioxane CopolymersInfo
- Publication number
- GB1173574A GB1173574A GB54525/66A GB5452566A GB1173574A GB 1173574 A GB1173574 A GB 1173574A GB 54525/66 A GB54525/66 A GB 54525/66A GB 5452566 A GB5452566 A GB 5452566A GB 1173574 A GB1173574 A GB 1173574A
- Authority
- GB
- United Kingdom
- Prior art keywords
- oxazinyl
- sulphonyl
- tetrahydro
- bis
- formula
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920001577 copolymer Polymers 0.000 title 1
- 239000001273 butane Substances 0.000 abstract 3
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 abstract 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 abstract 2
- 125000004432 carbon atom Chemical group C* 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- 238000006798 ring closing metathesis reaction Methods 0.000 abstract 2
- NGNBDVOYPDDBFK-UHFFFAOYSA-N 2-[2,4-di(pentan-2-yl)phenoxy]acetyl chloride Chemical compound CCCC(C)C1=CC=C(OCC(Cl)=O)C(C(C)CCC)=C1 NGNBDVOYPDDBFK-UHFFFAOYSA-N 0.000 abstract 1
- KNIUHBNRWZGIQQ-UHFFFAOYSA-N 7-diethoxyphosphinothioyloxy-4-methylchromen-2-one Chemical compound CC1=CC(=O)OC2=CC(OP(=S)(OCC)OCC)=CC=C21 KNIUHBNRWZGIQQ-UHFFFAOYSA-N 0.000 abstract 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 abstract 1
- WUGQZFFCHPXWKQ-UHFFFAOYSA-N Propanolamine Chemical compound NCCCO WUGQZFFCHPXWKQ-UHFFFAOYSA-N 0.000 abstract 1
- 239000003377 acid catalyst Substances 0.000 abstract 1
- 150000001299 aldehydes Chemical class 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- UHOVQNZJYSORNB-UHFFFAOYSA-N benzene Substances C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 abstract 1
- 230000001588 bifunctional effect Effects 0.000 abstract 1
- VZHRPLJULARYDO-UHFFFAOYSA-N butane-1,4-disulfonyl chloride Chemical compound ClS(=O)(=O)CCCCS(Cl)(=O)=O VZHRPLJULARYDO-UHFFFAOYSA-N 0.000 abstract 1
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N dimethylmethane Natural products CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 abstract 1
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Natural products C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 abstract 1
- 230000000694 effects Effects 0.000 abstract 1
- 125000000623 heterocyclic group Chemical group 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 1
- 239000012442 inert solvent Substances 0.000 abstract 1
- 150000002576 ketones Chemical class 0.000 abstract 1
- 125000000325 methylidene group Chemical group [H]C([H])=* 0.000 abstract 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 abstract 1
- 239000001294 propane Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2/00—Addition polymers of aldehydes or cyclic oligomers thereof or of ketones; Addition copolymers thereof with less than 50 molar percent of other substances
- C08G2/18—Copolymerisation of aldehydes or ketones
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Abstract
1,173,574. Heterocyclic disulphonamides. FARBENFABRIKEN BAYER A.G. 6 Dec., 1966 [11 Dec., 1965 (2)], No. 54525/66. Heading C2C. [Also in Division C3] Compounds of the formula are obtained by reacting 2 mols. of an alkanolamine of the formula with 1 mol. of a disulphonic acid chloride of the formula Cl.So 2 .R<SP>1</SP>.So 2 .Cl to yield an intermediate of the formula and reacting the intermediate with an aldehyde or ketone at 0 to 130 C. in the presence of an acid catalyst, preferably in an inert solvent, to effect double ring closure. In the above formulµ, R is hydrogen, or an alkyl or halogenoalkyl radical of 1 to 6 carbon atoms, R<SP>1</SP> is a methylene chain with up to 20 carbon atoms or a bifunctional aromatic radical, and n is 1 or 2. In Example 1, 1,3-propanolamine is reacted with 1,4-butanedisulphonic acid chloride, followed by ring closure with a 40% formalin solution in dilute hydrochloric acid to yield 1,4-bis-[tetrahydro - 1,3 - oxazinyl - N - sulphonyl] - butane. In the other examples, the following compounds are prepared: (2) 1,4-bis-[tetrahydro-1,3-oxazinyl - N - sulphonyl] butane, (3) 1,3 - bis- [tetrahydro - 1,3 - oxazinyl - N - sulphonyl]- propane, (4) 1,4 - bis - [6 - methyl - tetrahydro - 1,3 - oxazinyl - N - sulphonyl] - butane, (5) 1,3 - bis - [tetrahydro - 1,3 - oxazinyl - N- sulphonyl]-benzene, and (6) 4,4<SP>1</SP>-bis-[tetrahydro - 1,3 - oxazinyl - N - sulphonyl] - diphenyl ether.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEF0047897 | 1965-12-11 | ||
| DEF47898A DE1254351B (en) | 1965-12-11 | 1965-12-11 | Use of certain mixed trioxane polymers for the production of films, sheets, tubes |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1173574A true GB1173574A (en) | 1969-12-10 |
Family
ID=25977063
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB54525/66A Expired GB1173574A (en) | 1965-12-11 | 1966-12-06 | Trioxane Copolymers |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US3489717A (en) |
| BE (1) | BE690954A (en) |
| CH (1) | CH490436A (en) |
| DE (2) | DE1570635A1 (en) |
| FR (1) | FR1504933A (en) |
| GB (1) | GB1173574A (en) |
| IL (1) | IL26782A (en) |
| NL (1) | NL6617357A (en) |
| SE (1) | SE334741B (en) |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL127434C (en) * | 1960-11-21 | |||
| US3293219A (en) * | 1963-07-10 | 1966-12-20 | Tenneco Chem | Polyacetal terpolymers containing randomly recurring groups derived from a methylene-bis- |
| DE1218154B (en) * | 1964-04-20 | 1966-06-02 | Bayer Ag | Process for the preparation of copolymers of trioxane |
-
1965
- 1965-12-11 DE DE19651570635 patent/DE1570635A1/en active Pending
- 1965-12-11 DE DEF47898A patent/DE1254351B/en active Pending
-
1966
- 1966-11-01 IL IL26782A patent/IL26782A/en unknown
- 1966-11-07 US US592316A patent/US3489717A/en not_active Expired - Lifetime
- 1966-11-23 SE SE16024/66A patent/SE334741B/xx unknown
- 1966-12-06 GB GB54525/66A patent/GB1173574A/en not_active Expired
- 1966-12-08 FR FR86731A patent/FR1504933A/en not_active Expired
- 1966-12-09 NL NL6617357A patent/NL6617357A/xx unknown
- 1966-12-09 BE BE690954D patent/BE690954A/xx unknown
- 1966-12-09 CH CH1761766A patent/CH490436A/en not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| FR1504933A (en) | 1967-12-08 |
| CH490436A (en) | 1970-05-15 |
| DE1570635A1 (en) | 1970-02-05 |
| DE1254351B (en) | 1967-11-16 |
| SE334741B (en) | 1971-05-03 |
| NL6617357A (en) | 1967-06-12 |
| BE690954A (en) | 1967-05-16 |
| US3489717A (en) | 1970-01-13 |
| IL26782A (en) | 1970-08-19 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed [section 19, patents act 1949] | ||
| PLNP | Patent lapsed through nonpayment of renewal fees |