GB1171012A - Thermosetting Coating Compositions - Google Patents
Thermosetting Coating CompositionsInfo
- Publication number
- GB1171012A GB1171012A GB6437/67A GB643767A GB1171012A GB 1171012 A GB1171012 A GB 1171012A GB 6437/67 A GB6437/67 A GB 6437/67A GB 643767 A GB643767 A GB 643767A GB 1171012 A GB1171012 A GB 1171012A
- Authority
- GB
- United Kingdom
- Prior art keywords
- copolymer
- weight
- meth
- condensate
- groups
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920001187 thermosetting polymer Polymers 0.000 title abstract 2
- 239000008199 coating composition Substances 0.000 title 1
- 229920001577 copolymer Polymers 0.000 abstract 6
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 4
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 abstract 3
- 239000000463 material Substances 0.000 abstract 3
- 239000000178 monomer Substances 0.000 abstract 3
- 229920005989 resin Polymers 0.000 abstract 3
- 239000011347 resin Substances 0.000 abstract 3
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 abstract 2
- 229910008051 Si-OH Inorganic materials 0.000 abstract 2
- 229910006358 Si—OH Inorganic materials 0.000 abstract 2
- XXROGKLTLUQVRX-UHFFFAOYSA-N allyl alcohol Chemical compound OCC=C XXROGKLTLUQVRX-UHFFFAOYSA-N 0.000 abstract 2
- 229920003180 amino resin Polymers 0.000 abstract 2
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 abstract 2
- -1 methylol groups Chemical group 0.000 abstract 2
- JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical compound C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 abstract 1
- LUMNWCHHXDUKFI-UHFFFAOYSA-N 5-bicyclo[2.2.1]hept-2-enylmethanol Chemical compound C1C2C(CO)CC1C=C2 LUMNWCHHXDUKFI-UHFFFAOYSA-N 0.000 abstract 1
- 239000004215 Carbon black (E152) Substances 0.000 abstract 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 abstract 1
- 229910010413 TiO 2 Inorganic materials 0.000 abstract 1
- 230000002378 acidificating effect Effects 0.000 abstract 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 abstract 1
- 238000000576 coating method Methods 0.000 abstract 1
- 238000009833 condensation Methods 0.000 abstract 1
- 230000005494 condensation Effects 0.000 abstract 1
- 235000014113 dietary fatty acids Nutrition 0.000 abstract 1
- 238000001035 drying Methods 0.000 abstract 1
- 229930195729 fatty acid Natural products 0.000 abstract 1
- 239000000194 fatty acid Substances 0.000 abstract 1
- 150000004665 fatty acids Chemical class 0.000 abstract 1
- 150000002191 fatty alcohols Chemical class 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 125000002768 hydroxyalkyl group Chemical group 0.000 abstract 1
- 230000007935 neutral effect Effects 0.000 abstract 1
- 239000003960 organic solvent Substances 0.000 abstract 1
- 239000000049 pigment Substances 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- 239000000758 substrate Substances 0.000 abstract 1
- 150000005846 sugar alcohols Polymers 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
- 239000008096 xylene Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D161/00—Coating compositions based on condensation polymers of aldehydes or ketones; Coating compositions based on derivatives of such polymers
- C09D161/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F20/62—Monocarboxylic acids having ten or more carbon atoms; Derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/42—Introducing metal atoms or metal-containing groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/42—Block-or graft-polymers containing polysiloxane sequences
- C08G77/442—Block-or graft-polymers containing polysiloxane sequences containing vinyl polymer sequences
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
- C09D125/02—Homopolymers or copolymers of hydrocarbons
- C09D125/04—Homopolymers or copolymers of styrene
- C09D125/08—Copolymers of styrene
- C09D125/14—Copolymers of styrene with unsaturated esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
- C08L61/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Paints Or Removers (AREA)
- Phenolic Resins Or Amino Resins (AREA)
Abstract
1,171,012. Coated products. DE SOTO Inc. 10 Feb., 1967, No. 6437/67. Heading B2K. [Also in Division C3] Substrates, e.g. of sheet for automotive finishes, are coated with a thermosetting composition comprising an organic solvent in which is dissolved: (I) A non-gelled condensate of a copolymer of from 3-30% (of the weight of the copolymer) of an ethylenically unsaturated monomer carrying a hydroxyl group, the remainder being at least one monomer containing the CH 2 =C< group, with a Si-containing material having an average of at least 1.2 Si-bonded OH or alkoxy radicals per molecule. The equivalent ratio of Si-OH or Sialkoxy radicals to hydroxy groups in the copolymer ranges from 1:4 to 4:1. Condensation is continued to eliminate 5-95 % of the water or alcohol of reaction and to cause the bulk of the material to become chemically combined with the copolymer. The condensate obtained contains unreacted essentially neutral hydroxyl groups in the copolymer and unreacted acidic Si-OH or Si-alkoxy groups carried by the residue of the Si-containing material in the condensate. (II) an aminoplast resin providing basic methylol groups. The total resin in the composition may comprises 40- 95% by weight of I and 60-5% by weight of II. Suitable OH- containing monomers useful in preparing the copolymer of I are hydroxyalkyl (meth)acrylates, (meth)allyl ethers of polyhydric alcohols, (meth)allyl alcohol, 2-hydroxymethyl-5-nor bornene or an unsaturated fatty alcohol derived from a drying oil fatty acid. The siloxane may have the average general formula: in which R is a monovalent hydrocarbon radical, R' is a hydroxyl or alkoxy radical, n has an average value of 1 to 2, m has an average value of at least 0.1 and m+n is not greater than 3, there being at least 1.2 (preferably 2 to 8) R' radicals per siloxane molecule. Examples of suitable aminoplasts are triazine 1 formaldehyde resins. The solvent (e.g. xylene and butanol) may comprises 30-65% by weight of the composition. Conventional pigments, e.g. TiO 2 may also be present. The coatings may be hardened by stoving e.g. for 15 minutes at 350‹F.
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB6437/67A GB1171012A (en) | 1967-02-10 | 1967-02-10 | Thermosetting Coating Compositions |
| NL6702952A NL6702952A (en) | 1967-02-10 | 1967-02-24 | |
| BE694994D BE694994A (en) | 1967-02-10 | 1967-03-03 |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB6437/67A GB1171012A (en) | 1967-02-10 | 1967-02-10 | Thermosetting Coating Compositions |
| NL6702952A NL6702952A (en) | 1967-02-10 | 1967-02-24 | |
| BE694994 | 1967-03-03 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1171012A true GB1171012A (en) | 1969-11-19 |
Family
ID=27159217
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB6437/67A Expired GB1171012A (en) | 1967-02-10 | 1967-02-10 | Thermosetting Coating Compositions |
Country Status (3)
| Country | Link |
|---|---|
| BE (1) | BE694994A (en) |
| GB (1) | GB1171012A (en) |
| NL (1) | NL6702952A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2192399A (en) * | 1986-07-09 | 1988-01-13 | Nippon Paint Co Ltd | Coating composition |
| US5409994A (en) * | 1990-04-25 | 1995-04-25 | Kansai Paint Company, Limited | Automotive top coating composition |
| US5449717A (en) * | 1992-04-08 | 1995-09-12 | Kansai Paint Company, Limited | Coating composition |
-
1967
- 1967-02-10 GB GB6437/67A patent/GB1171012A/en not_active Expired
- 1967-02-24 NL NL6702952A patent/NL6702952A/xx unknown
- 1967-03-03 BE BE694994D patent/BE694994A/xx unknown
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2192399A (en) * | 1986-07-09 | 1988-01-13 | Nippon Paint Co Ltd | Coating composition |
| GB2192399B (en) * | 1986-07-09 | 1990-04-11 | Nippon Paint Co Ltd | Coating composition |
| US5100962A (en) * | 1986-07-09 | 1992-03-31 | Nippon Paint Co., Ltd. | Coating composition |
| US5409994A (en) * | 1990-04-25 | 1995-04-25 | Kansai Paint Company, Limited | Automotive top coating composition |
| US5449717A (en) * | 1992-04-08 | 1995-09-12 | Kansai Paint Company, Limited | Coating composition |
Also Published As
| Publication number | Publication date |
|---|---|
| NL6702952A (en) | 1968-08-26 |
| BE694994A (en) | 1967-08-14 |
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