GB1168406A - Preparation of Symmetrical Azo Compounds - Google Patents
Preparation of Symmetrical Azo CompoundsInfo
- Publication number
- GB1168406A GB1168406A GB06592/68A GB1659268A GB1168406A GB 1168406 A GB1168406 A GB 1168406A GB 06592/68 A GB06592/68 A GB 06592/68A GB 1659268 A GB1659268 A GB 1659268A GB 1168406 A GB1168406 A GB 1168406A
- Authority
- GB
- United Kingdom
- Prior art keywords
- substituted
- azo compounds
- radical
- symmetrical azo
- formula
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229910052736 halogen Inorganic materials 0.000 abstract 2
- 150000002367 halogens Chemical class 0.000 abstract 2
- WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Chemical class Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 abstract 2
- 239000002253 acid Substances 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 125000002947 alkylene group Chemical group 0.000 abstract 1
- -1 amino compound Chemical class 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 239000007795 chemical reaction product Substances 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 230000008014 freezing Effects 0.000 abstract 1
- 238000007710 freezing Methods 0.000 abstract 1
- 238000011065 in-situ storage Methods 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 239000000376 reactant Substances 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C255/00—Carboxylic acid nitriles
- C07C255/63—Carboxylic acid nitriles containing cyano groups and nitrogen atoms further bound to other hetero atoms, other than oxygen atoms of nitro or nitroso groups, bound to the same carbon skeleton
- C07C255/65—Carboxylic acid nitriles containing cyano groups and nitrogen atoms further bound to other hetero atoms, other than oxygen atoms of nitro or nitroso groups, bound to the same carbon skeleton with the nitrogen atoms further bound to nitrogen atoms
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
1,168,406. Symmetrical azo compounds. E. I. DU PONT DE NEMOURS & CO. 5 April, 1968, No. 16592/68. Heading C20. Symmetrical azo compounds of the formula are obtained by reacting an amino compound of the formula with a source of positively charged halogen in the presence of a solvent which contains 0 to 55% by wt. of water and 45 to 100% by wt. of water-miscible organic liquid having a b.pt. between 0‹ and 350‹ C., at a temperature above the freezing point of the reactants and below 100‹ 0. and separating the reaction product from said solution, wherein R 1 is a C 1 -C 6 alkyl radical which may be substituted; R 2 is a C 1 -C 6 alkyl or C 3 -C 6 cycloalkyl radical which may be substituted, with the limitation that R 1 and R 2 together contain at least 4 carbon atoms, or R 1 and R 2 together are a C 4 -C 12 alkylene group which may be substituted; and R 3 is a CN, COOR or COOM radical, where R is a C 1 -C 6 alkyl radical which may be substituted and M is Na or K. Specificed sources of positively charged halogen are hypochlorites or hypochlorites formed in situ from Cl 2 and an acid acceptor. Examples are given for the production of compounds. Reference has been directed by the Comptroller to Specification 1,102,532.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AU35906/68A AU439242B2 (en) | 1968-04-03 | 1968-04-03 | Preparation of symmetrical azo compounds |
| GB06592/68A GB1168406A (en) | 1968-04-03 | 1968-04-05 | Preparation of Symmetrical Azo Compounds |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AU35906/68A AU439242B2 (en) | 1968-04-03 | 1968-04-03 | Preparation of symmetrical azo compounds |
| GB06592/68A GB1168406A (en) | 1968-04-03 | 1968-04-05 | Preparation of Symmetrical Azo Compounds |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1168406A true GB1168406A (en) | 1969-10-22 |
Family
ID=25623466
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB06592/68A Expired GB1168406A (en) | 1968-04-03 | 1968-04-05 | Preparation of Symmetrical Azo Compounds |
Country Status (2)
| Country | Link |
|---|---|
| AU (1) | AU439242B2 (en) |
| GB (1) | GB1168406A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4272435A (en) * | 1977-10-12 | 1981-06-09 | Sumitomo Chemical Company, Limited | Process for the preparation of azo compounds from amino compounds in the presence of a phase transfer catalyst |
| US4290945A (en) * | 1979-11-06 | 1981-09-22 | Syrov Anatoly A | α,α-azo-bis-isobutyric acid α,ω-bis alkyl ester derivatives and method for preparing same |
| US4546174A (en) * | 1979-12-20 | 1985-10-08 | Fbc Limited | Process for the preparation of aliphatic azo compounds using an amine coupling |
-
1968
- 1968-04-03 AU AU35906/68A patent/AU439242B2/en not_active Expired
- 1968-04-05 GB GB06592/68A patent/GB1168406A/en not_active Expired
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4272435A (en) * | 1977-10-12 | 1981-06-09 | Sumitomo Chemical Company, Limited | Process for the preparation of azo compounds from amino compounds in the presence of a phase transfer catalyst |
| US4290945A (en) * | 1979-11-06 | 1981-09-22 | Syrov Anatoly A | α,α-azo-bis-isobutyric acid α,ω-bis alkyl ester derivatives and method for preparing same |
| US4546174A (en) * | 1979-12-20 | 1985-10-08 | Fbc Limited | Process for the preparation of aliphatic azo compounds using an amine coupling |
Also Published As
| Publication number | Publication date |
|---|---|
| AU439242B2 (en) | 1973-08-15 |
| AU3590668A (en) | 1969-10-09 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed [section 19, patents act 1949] | ||
| PLNP | Patent lapsed through nonpayment of renewal fees |