GB1163086A - Polyamides. - Google Patents
Polyamides.Info
- Publication number
- GB1163086A GB1163086A GB48486/66A GB4848666A GB1163086A GB 1163086 A GB1163086 A GB 1163086A GB 48486/66 A GB48486/66 A GB 48486/66A GB 4848666 A GB4848666 A GB 4848666A GB 1163086 A GB1163086 A GB 1163086A
- Authority
- GB
- United Kingdom
- Prior art keywords
- polyamide
- phenol
- phosphorus compound
- polyamides
- compound
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/53—Phosphorus bound to oxygen bound to oxygen and to carbon only
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Artificial Filaments (AREA)
Abstract
1,163,086. Polyamides. IMPERIAL CHEMICAL INDUSTRIES Ltd. 15 Feb., 1967 [7 March, 1966; 28 Oct., 1966], Nos. 9763/66 and 48486/66. Heading C3R. Polyamides (especially polyhexamethylene adipamide) are stabilized by the addition of a sterically hindered phenol which is stable in the polymer when molten and a phosphorus compound which has the general formula R is a hydrogen atom or an aliphatic, cycloaliphatic, araliphatic or aryl radical, and X is an aliphatic, cycloaliphatic, aryl or araliphatic radical or when (I) is an acid, a salt or ester thereof. Suitable compounds are: phosphonous acids, its salts and esters. Suitable phenols are; 1,1,3 - tris - (2<SP>1</SP> - methyl, - 4<SP>1</SP>- hydroxy - 5 - tert. - butylphenyl) butane and 1,1,5,5-tetrakis- (21 - methyl - 4<SP>1</SP> - hydroxy - 5 - tert. - butylphenyl) pentane. The phenol may be used at 0-01-10% by wt. of the polyamide and the phosphorus compound at 0.01-2% by wt. of the polyamide. The composition may also contain TiO 2 and a manganese compound. The phenol and phosphorus compound may be coated on to a solid polyamide which is then melted and may be spun into fibres. Alternatively the phenol and phosphorus compound may be added to polyamide forming compound either before or during polymerization.
Priority Applications (7)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB48486/66A GB1163086A (en) | 1966-03-07 | 1966-03-07 | Polyamides. |
| NL6703331A NL6703331A (en) | 1966-03-07 | 1967-02-28 | |
| BE694789D BE694789A (en) | 1966-03-07 | 1967-02-28 | |
| US619144A US3533986A (en) | 1966-03-07 | 1967-02-28 | Polyamides |
| DE19671694447 DE1694447A1 (en) | 1966-03-07 | 1967-03-02 | Polyamides |
| FR97713A FR1516450A (en) | 1966-03-07 | 1967-03-07 | Polyamides |
| CH328767A CH471850A (en) | 1966-03-07 | 1967-03-07 | Stabilized polyamide |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB976366 | 1966-03-07 | ||
| GB48486/66A GB1163086A (en) | 1966-03-07 | 1966-03-07 | Polyamides. |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1163086A true GB1163086A (en) | 1969-09-04 |
Family
ID=26243156
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB48486/66A Expired GB1163086A (en) | 1966-03-07 | 1966-03-07 | Polyamides. |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US3533986A (en) |
| BE (1) | BE694789A (en) |
| CH (1) | CH471850A (en) |
| DE (1) | DE1694447A1 (en) |
| FR (1) | FR1516450A (en) |
| GB (1) | GB1163086A (en) |
| NL (1) | NL6703331A (en) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1276007A (en) * | 1969-04-15 | 1972-06-01 | Ici Ltd | Polyamides |
| US3860558A (en) * | 1970-12-07 | 1975-01-14 | Ciba Geigy Corp | Stabilized polyamide compositions |
| US3691131A (en) * | 1971-02-01 | 1972-09-12 | Ciba Geigy Corp | Stabilized polyamide compositions |
| US3844713A (en) * | 1972-04-11 | 1974-10-29 | Allied Chem | Alkyl and aryl phosphites to inhibit ozone fading of dyed polyamides |
| US3935165A (en) * | 1972-07-22 | 1976-01-27 | Dynamit Nobel Aktiengesellschaft | Process for the stabilization of polyester amides |
| US3872055A (en) * | 1972-08-19 | 1975-03-18 | Toyo Boseki | Polyamide composition having decreased gel-forming property in molten state |
| US5380774A (en) * | 1989-11-28 | 1995-01-10 | Hoechst Celanese Corporation | Nylon molding compositions exhibiting improved protection against UV-light degradation |
| DE69400136T3 (en) * | 1993-02-18 | 2003-06-18 | E.I. Du Pont De Nemours And Co., Wilmington | POLYAMIDES WITH IMPROVED COLOR BEHAVIOR AND IMPROVED PROCESSABILITY AND METHOD FOR THE PRODUCTION THEREOF |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB890437A (en) * | 1958-02-20 | 1962-02-28 | Du Pont | Polycarbonamides |
| US3210428A (en) * | 1959-09-04 | 1965-10-05 | Union Carbide Corp | Polyols from 2-hydroxymethyl-1, 3-dioxolane and phenolic compounds |
| BE593476A (en) * | 1960-04-14 | |||
| BE608862A (en) * | 1960-10-06 | 1900-01-01 | ||
| NL122899C (en) * | 1961-11-24 | |||
| US3374288A (en) * | 1965-09-03 | 1968-03-19 | Du Pont | Polycarbonamide filaments containing polyalkylene oxide, sodium phenyl phosphinate and sodium aminoalkylphosphinate |
-
1966
- 1966-03-07 GB GB48486/66A patent/GB1163086A/en not_active Expired
-
1967
- 1967-02-28 US US619144A patent/US3533986A/en not_active Expired - Lifetime
- 1967-02-28 NL NL6703331A patent/NL6703331A/xx unknown
- 1967-02-28 BE BE694789D patent/BE694789A/xx unknown
- 1967-03-02 DE DE19671694447 patent/DE1694447A1/en active Pending
- 1967-03-07 FR FR97713A patent/FR1516450A/en not_active Expired
- 1967-03-07 CH CH328767A patent/CH471850A/en not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| CH471850A (en) | 1969-04-30 |
| NL6703331A (en) | 1967-09-08 |
| FR1516450A (en) | 1968-03-08 |
| BE694789A (en) | 1967-08-28 |
| US3533986A (en) | 1970-10-13 |
| DE1694447A1 (en) | 1970-12-17 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed [section 19, patents act 1949] | ||
| PLNP | Patent lapsed through nonpayment of renewal fees |