GB1161725A - Hydrocracking process with Zeolite and Amorphous Base Catalysts - Google Patents
Hydrocracking process with Zeolite and Amorphous Base CatalystsInfo
- Publication number
- GB1161725A GB1161725A GB4724867A GB4724867A GB1161725A GB 1161725 A GB1161725 A GB 1161725A GB 4724867 A GB4724867 A GB 4724867A GB 4724867 A GB4724867 A GB 4724867A GB 1161725 A GB1161725 A GB 1161725A
- Authority
- GB
- United Kingdom
- Prior art keywords
- catalyst
- zeolite
- nickel
- hydrocracking
- base catalyst
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003054 catalyst Substances 0.000 title abstract 15
- 229910021536 Zeolite Inorganic materials 0.000 title abstract 7
- 238000004517 catalytic hydrocracking Methods 0.000 title abstract 7
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 title abstract 7
- 239000010457 zeolite Substances 0.000 title abstract 7
- 238000000034 method Methods 0.000 title abstract 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract 6
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 abstract 5
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 abstract 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract 4
- 238000005984 hydrogenation reaction Methods 0.000 abstract 4
- 229910052751 metal Inorganic materials 0.000 abstract 4
- 239000002184 metal Substances 0.000 abstract 4
- 238000009835 boiling Methods 0.000 abstract 3
- 239000007788 liquid Substances 0.000 abstract 3
- 229910052759 nickel Inorganic materials 0.000 abstract 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 2
- 229910017052 cobalt Inorganic materials 0.000 abstract 2
- 239000010941 cobalt Substances 0.000 abstract 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 abstract 2
- 229910052742 iron Inorganic materials 0.000 abstract 2
- 229910052763 palladium Inorganic materials 0.000 abstract 2
- 229910052697 platinum Inorganic materials 0.000 abstract 2
- -1 platinum group metals Chemical class 0.000 abstract 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 abstract 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 abstract 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 1
- 239000005864 Sulphur Substances 0.000 abstract 1
- MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Inorganic materials O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 abstract 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 1
- 150000001768 cations Chemical class 0.000 abstract 1
- 229910052804 chromium Inorganic materials 0.000 abstract 1
- 239000011651 chromium Substances 0.000 abstract 1
- WHDPTDWLEKQKKX-UHFFFAOYSA-N cobalt molybdenum Chemical compound [Co].[Co].[Mo] WHDPTDWLEKQKKX-UHFFFAOYSA-N 0.000 abstract 1
- INILCLIQNYSABH-UHFFFAOYSA-N cobalt;sulfanylidenemolybdenum Chemical compound [Mo].[Co]=S INILCLIQNYSABH-UHFFFAOYSA-N 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 150000002430 hydrocarbons Chemical class 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000000395 magnesium oxide Substances 0.000 abstract 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 abstract 1
- 150000001457 metallic cations Chemical class 0.000 abstract 1
- 229910052750 molybdenum Inorganic materials 0.000 abstract 1
- 239000011733 molybdenum Substances 0.000 abstract 1
- MOWMLACGTDMJRV-UHFFFAOYSA-N nickel tungsten Chemical compound [Ni].[W] MOWMLACGTDMJRV-UHFFFAOYSA-N 0.000 abstract 1
- XOROUWAJDBBCRC-UHFFFAOYSA-N nickel;sulfanylidenetungsten Chemical compound [Ni].[W]=S XOROUWAJDBBCRC-UHFFFAOYSA-N 0.000 abstract 1
- 229910052757 nitrogen Inorganic materials 0.000 abstract 1
- 125000001477 organic nitrogen group Chemical group 0.000 abstract 1
- 239000003209 petroleum derivative Substances 0.000 abstract 1
- 239000011148 porous material Substances 0.000 abstract 1
- 229910052761 rare earth metal Inorganic materials 0.000 abstract 1
- 150000002910 rare earth metals Chemical class 0.000 abstract 1
- 238000004064 recycling Methods 0.000 abstract 1
- 239000000377 silicon dioxide Substances 0.000 abstract 1
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 abstract 1
- 229910001948 sodium oxide Inorganic materials 0.000 abstract 1
- WWNBZGLDODTKEM-UHFFFAOYSA-N sulfanylidenenickel Chemical compound [Ni]=S WWNBZGLDODTKEM-UHFFFAOYSA-N 0.000 abstract 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 abstract 1
- 229910052721 tungsten Inorganic materials 0.000 abstract 1
- 239000010937 tungsten Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G65/00—Treatment of hydrocarbon oils by two or more hydrotreatment processes only
- C10G65/02—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only
- C10G65/10—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including only cracking steps
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/061—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing metallic elements added to the zeolite
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G65/00—Treatment of hydrocarbon oils by two or more hydrotreatment processes only
- C10G65/02—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only
- C10G65/12—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including cracking steps and other hydrotreatment steps
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Materials Engineering (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Abstract
1,161,725. Hydrocracking. MOBIL OIL CORP. 17 Oct., 1967 [17 Oct., 1966], No. 47248/67. Heading CSE. A process for selectively producing gasoline boiling range hydrocarbons by hydrocracking comprises contacting under hydrocracking conditions a heavy petroleum hydrocarbon feed containing less than 500 p.p.m. organic nitrogen with an amorphous base hydrocracking catalyst and a zeolite base hydrocracking catalyst, said contact being carried out in a series of catalyst beds wherein said amorphous base catalyst is separated from said zeolite base catalyst, said amorphous base catalyst containing a hydrogenation component and having a Cat A activity index above 20, said zeolite base catalyst having pore size openings between 6 Angstroms and 15 Angstroms and containing a hydrogenation component and less than 5 weight per cent sodium oxide, recovering a normally liquid effluent from the last catalyst bed, separating a gasoline boiling range fraction from said liquid effluent, and recycling at least a portion of the liquid effluent boiling above the gasoline range to contact the amorphous base hydrocracking catalyst bed. It is possible to use the amorphous base catalyst first, but it is preferred to use the zeolite base catalyst first and the amorphous base catalyst second. The amorphous base catalyst may comprise silicaalumina, silica-zirconia, silica-magnesia, silica, or alumina containing a hydrogenation component such as iron, nickel, cobalt, the platinum group metals, or the palladium group metals; preferred examples being nickel-tungsten sulphide, nickel sulphide, cobalt-molybdenum sulphide, platinum and palladium. The zeolite catalyst comprises a natural or synthetic zeolite carrier which may be base-exchanged with a hydrogen-containing cation or a metallic cation such as nickel or a rare earth metal, plus a hydrogenation component which may be chromium, molybdenum, tungsten, iron, nickel, cobalt, a platinum group metal or a palladium group metal; preferred components being nickel-tungsten, cobalt-molybdenum, platinum and palladium. There may be a preliminary hydrofining stage to reduce the amount of sulphur and nitrogen in the feed.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US58711366A | 1966-10-17 | 1966-10-17 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1161725A true GB1161725A (en) | 1969-08-20 |
Family
ID=24348413
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB4724867A Expired GB1161725A (en) | 1966-10-17 | 1967-10-17 | Hydrocracking process with Zeolite and Amorphous Base Catalysts |
Country Status (3)
| Country | Link |
|---|---|
| DE (1) | DE1645773A1 (en) |
| GB (1) | GB1161725A (en) |
| NL (1) | NL6714117A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0428224A1 (en) * | 1989-11-16 | 1991-05-22 | Shell Internationale Researchmaatschappij B.V. | Process for converting hydrocarbon oils |
| WO2015128038A1 (en) | 2014-02-25 | 2015-09-03 | Saudi Basic Industries Corporation | Method for converting a high-boiling hydrocarbon feedstock into lighter boiling hydrocarbon products |
| WO2016183200A1 (en) * | 2015-05-12 | 2016-11-17 | Ergon, Inc. | High performance process oil based on distilled aromatic extracts |
| FR3071849A1 (en) * | 2017-09-29 | 2019-04-05 | IFP Energies Nouvelles | PROCESS FOR THE IMPROVED PRODUCTION OF MEDIUM DISTILLATES BY HYDROCRACKING TWO STEPS OF VACUUM DISTILLATES |
| US11332679B2 (en) | 2015-05-12 | 2022-05-17 | Ergon, Inc. | High performance process oil |
-
1967
- 1967-10-17 NL NL6714117A patent/NL6714117A/xx unknown
- 1967-10-17 GB GB4724867A patent/GB1161725A/en not_active Expired
- 1967-10-17 DE DE19671645773 patent/DE1645773A1/en active Pending
Cited By (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0428224A1 (en) * | 1989-11-16 | 1991-05-22 | Shell Internationale Researchmaatschappij B.V. | Process for converting hydrocarbon oils |
| AU636683B2 (en) * | 1989-11-16 | 1993-05-06 | Shell Internationale Research Maatschappij B.V. | Process for converting hydrocarbon oils |
| TR28744A (en) * | 1989-11-16 | 1997-02-18 | Shell Int Research | Process for the conversion of hydrocarbon oils. |
| US10301559B2 (en) | 2014-02-25 | 2019-05-28 | Saudi Basic Industries Corporation | Method for converting a high-boiling hydrocarbon feedstock into lighter boiling hydrocarbon products |
| CN106133119A (en) * | 2014-02-25 | 2016-11-16 | 沙特基础工业公司 | The method being converted into the hydrocarbon products that gentlier boils for the hydrocarbon feed that boiled by height |
| WO2015128038A1 (en) | 2014-02-25 | 2015-09-03 | Saudi Basic Industries Corporation | Method for converting a high-boiling hydrocarbon feedstock into lighter boiling hydrocarbon products |
| EA032566B1 (en) * | 2014-02-25 | 2019-06-28 | Сауди Бейсик Индастриз Корпорейшн | Method for converting a high-boiling hydrocarbon feedstock into lighter boiling hydrocarbon products |
| CN106133119B (en) * | 2014-02-25 | 2022-02-25 | 沙特基础工业公司 | Process for converting high boiling hydrocarbon feedstocks to lighter boiling hydrocarbon products |
| WO2016183200A1 (en) * | 2015-05-12 | 2016-11-17 | Ergon, Inc. | High performance process oil based on distilled aromatic extracts |
| CN107636123A (en) * | 2015-05-12 | 2018-01-26 | 埃尔根公司 | High performance processing oils based on distilled aromatic extracts |
| RU2733842C2 (en) * | 2015-05-12 | 2020-10-07 | Эргон, Инк. | Process oil based on distilled aromatic extracts with high performance characteristics |
| US11332679B2 (en) | 2015-05-12 | 2022-05-17 | Ergon, Inc. | High performance process oil |
| EP4092097A1 (en) * | 2015-05-12 | 2022-11-23 | Ergon, Inc. | High performance process oil based on distilled aromatic extracts |
| US11560521B2 (en) | 2015-05-12 | 2023-01-24 | Ergon, Inc. | High performance process oil |
| US11566187B2 (en) | 2015-05-12 | 2023-01-31 | Ergon, Inc. | High performance process oil based on distilled aromatic extracts |
| FR3071849A1 (en) * | 2017-09-29 | 2019-04-05 | IFP Energies Nouvelles | PROCESS FOR THE IMPROVED PRODUCTION OF MEDIUM DISTILLATES BY HYDROCRACKING TWO STEPS OF VACUUM DISTILLATES |
Also Published As
| Publication number | Publication date |
|---|---|
| NL6714117A (en) | 1968-04-18 |
| DE1645773A1 (en) | 1970-05-14 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed | ||
| PLNP | Patent lapsed through nonpayment of renewal fees |