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GB1161661A - Improvements in or relating to Adhesive Compositions Curing Rapidly by Polymerisation under Anaerobic Conditions - Google Patents

Improvements in or relating to Adhesive Compositions Curing Rapidly by Polymerisation under Anaerobic Conditions

Info

Publication number
GB1161661A
GB1161661A GB163/66A GB16366A GB1161661A GB 1161661 A GB1161661 A GB 1161661A GB 163/66 A GB163/66 A GB 163/66A GB 16366 A GB16366 A GB 16366A GB 1161661 A GB1161661 A GB 1161661A
Authority
GB
United Kingdom
Prior art keywords
acid
glycol
peroxide
compositions
organic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB163/66A
Inventor
William Arthur Lees
John Richard Swire
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hexion UK Ltd
Original Assignee
Borden Chemical UK Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from GB26798/63A external-priority patent/GB1090753A/en
Application filed by Borden Chemical UK Ltd filed Critical Borden Chemical UK Ltd
Priority to GB163/66A priority Critical patent/GB1161661A/en
Priority to FR89465A priority patent/FR93063E/en
Priority to BE692031D priority patent/BE692031A/xx
Priority to NL6700089A priority patent/NL6700089A/xx
Priority to NL6700989A priority patent/NL6700989A/xx
Publication of GB1161661A publication Critical patent/GB1161661A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
    • C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
    • C08F265/06—Polymerisation of acrylate or methacrylate esters on to polymers thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/10—Esters
    • C08F20/20—Esters of polyhydric alcohols or polyhydric phenols, e.g. 2-hydroxyethyl (meth)acrylate or glycerol mono-(meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
    • C08F222/10—Esters
    • C08F222/1006—Esters of polyhydric alcohols or polyhydric phenols
    • C08F222/102—Esters of polyhydric alcohols or polyhydric phenols of dialcohols, e.g. ethylene glycol di(meth)acrylate or 1,4-butanediol dimethacrylate
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J4/00—Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

1,161,661. Anaerobic curing adhesives. BORDEN CHEMICAL CO. (U.K.) Ltd. 22 Dec., 1966 [3 Jan., 1966], No. 163/66. Addition to 1,090,753. Heading C3P. Anaerobic curing compositions comprise a monomer (or a partial polymer thereof) of the formula where R is -H, -CH 3 , -C 2 H 5 , -CH 2 OH or X and Y are integers each equal to at least 1 and n is 0 or 1, an organic peroxide (other than a hydroperoxide) having a half-life (as defined) greater than 5 hours at 100‹ C., and an organic acid or an anhydride, imide or amide thereof, the composition being free from water. The compositions may also include an amine, particularly an aromatic tertiary amine. Monomers specified are diacrylates and dimethacrylates of diethylene glycol, triethylene glycol, tetraethylene glycol, dipropylene glycol, diglycerol and di-(pentamethylene) glycol, and diglycerol tetramethacrylate; esters of ethacrylic or chloroacrylic acid, e.g. tetraethylene glycol dichloracrylate, are also suitable. Suitable peroxides include 2,5-dimethyl-2,5-di-(tbutyl peroxy)-hexane, di-t-butyl peroxide, dihexylene glycol peroxide, t-butyl cumyl peroxide, methyl isobutyl ketone peroxide and 2,5 - diethyl - 2,5 - di - (t - butylperoxy)-hexane. As the organic acid (or derivative thereof) there are mentioned benzoic acid, p-toluic acid, naphthoic acid, naphthylacetic acid, phthalic acid and their anhydrides, methacrylic acid, p - toluene-sulphonamide, methylene - bis -acrylamide, phthalimide and saccharin. The compositions may also contain a thickener, e.g. polyvinyl acetate. The compositions are suitable for bonding metal surfaces, particularly in systems such as nuts and bolts.
GB163/66A 1963-07-05 1966-01-03 Improvements in or relating to Adhesive Compositions Curing Rapidly by Polymerisation under Anaerobic Conditions Expired GB1161661A (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
GB163/66A GB1161661A (en) 1963-07-05 1966-01-03 Improvements in or relating to Adhesive Compositions Curing Rapidly by Polymerisation under Anaerobic Conditions
FR89465A FR93063E (en) 1963-07-05 1966-12-30 Composition curing under anaerobic conditions.
BE692031D BE692031A (en) 1963-07-05 1966-12-30
NL6700089A NL6700089A (en) 1963-07-05 1967-01-03
NL6700989A NL6700989A (en) 1966-01-03 1967-01-20

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB26798/63A GB1090753A (en) 1963-07-05 1963-07-05 Improvements in or relating to anaerobic curing compositions
GB163/66A GB1161661A (en) 1963-07-05 1966-01-03 Improvements in or relating to Adhesive Compositions Curing Rapidly by Polymerisation under Anaerobic Conditions

Publications (1)

Publication Number Publication Date
GB1161661A true GB1161661A (en) 1969-08-20

Family

ID=26235728

Family Applications (1)

Application Number Title Priority Date Filing Date
GB163/66A Expired GB1161661A (en) 1963-07-05 1966-01-03 Improvements in or relating to Adhesive Compositions Curing Rapidly by Polymerisation under Anaerobic Conditions

Country Status (3)

Country Link
BE (1) BE692031A (en)
GB (1) GB1161661A (en)
NL (1) NL6700089A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2711748A1 (en) * 1977-03-17 1978-09-21 Bostik Gmbh ANAEROBICLY CURING ADHESIVE COMPOUND AND METHOD OF JOINING SURFACES USING THIS ADHESIVE COMPOUND

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2711748A1 (en) * 1977-03-17 1978-09-21 Bostik Gmbh ANAEROBICLY CURING ADHESIVE COMPOUND AND METHOD OF JOINING SURFACES USING THIS ADHESIVE COMPOUND

Also Published As

Publication number Publication date
BE692031A (en) 1967-06-30
NL6700089A (en) 1967-07-04

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Legal Events

Date Code Title Description
PS Patent sealed [section 19, patents act 1949]
PLE Entries relating assignments, transmissions, licences in the register of patents
PE Patent expired