GB1158974A - Oil and Black Loaded Ethylene-Rich EODM Polymers. - Google Patents
Oil and Black Loaded Ethylene-Rich EODM Polymers.Info
- Publication number
- GB1158974A GB1158974A GB17404/68A GB1740468A GB1158974A GB 1158974 A GB1158974 A GB 1158974A GB 17404/68 A GB17404/68 A GB 17404/68A GB 1740468 A GB1740468 A GB 1740468A GB 1158974 A GB1158974 A GB 1158974A
- Authority
- GB
- United Kingdom
- Prior art keywords
- oil
- carbon black
- polymer
- phr
- terpolymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920000642 polymer Polymers 0.000 title abstract 7
- 239000006229 carbon black Substances 0.000 abstract 5
- 229920001897 terpolymer Polymers 0.000 abstract 4
- PRBHEGAFLDMLAL-GQCTYLIASA-N (4e)-hexa-1,4-diene Chemical compound C\C=C\CC=C PRBHEGAFLDMLAL-GQCTYLIASA-N 0.000 abstract 2
- YXIWHUQXZSMYRE-UHFFFAOYSA-N 1,3-benzothiazole-2-thiol Chemical compound C1=CC=C2SC(S)=NC2=C1 YXIWHUQXZSMYRE-UHFFFAOYSA-N 0.000 abstract 2
- 239000006237 Intermediate SAF Substances 0.000 abstract 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 2
- 239000005864 Sulphur Substances 0.000 abstract 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- 239000000178 monomer Substances 0.000 abstract 2
- 229920002943 EPDM rubber Polymers 0.000 abstract 1
- CYTYCFOTNPOANT-UHFFFAOYSA-N Perchloroethylene Chemical group ClC(Cl)=C(Cl)Cl CYTYCFOTNPOANT-UHFFFAOYSA-N 0.000 abstract 1
- 235000021355 Stearic acid Nutrition 0.000 abstract 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 abstract 1
- 229910021552 Vanadium(IV) chloride Inorganic materials 0.000 abstract 1
- HQMRIBYCTLBDAK-UHFFFAOYSA-M bis(2-methylpropyl)alumanylium;chloride Chemical compound CC(C)C[Al](Cl)CC(C)C HQMRIBYCTLBDAK-UHFFFAOYSA-M 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 abstract 1
- -1 ethylene, propylene Chemical group 0.000 abstract 1
- 230000009477 glass transition Effects 0.000 abstract 1
- 238000011065 in-situ storage Methods 0.000 abstract 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 abstract 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 abstract 1
- 239000003208 petroleum Substances 0.000 abstract 1
- 230000000379 polymerizing effect Effects 0.000 abstract 1
- 239000008117 stearic acid Substances 0.000 abstract 1
- 229950011008 tetrachloroethylene Drugs 0.000 abstract 1
- KUAZQDVKQLNFPE-UHFFFAOYSA-N thiram Chemical compound CN(C)C(=S)SSC(=S)N(C)C KUAZQDVKQLNFPE-UHFFFAOYSA-N 0.000 abstract 1
- JTJFQBNJBPPZRI-UHFFFAOYSA-J vanadium tetrachloride Chemical compound Cl[V](Cl)(Cl)Cl JTJFQBNJBPPZRI-UHFFFAOYSA-J 0.000 abstract 1
- 239000011787 zinc oxide Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/16—Ethene-propene or ethene-propene-diene copolymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/06—Sulfur
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L91/00—Compositions of oils, fats or waxes; Compositions of derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2312/00—Crosslinking
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
- C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
1,158,974. Sulphur curable polymers. E. I. DU PONT DE NEMOURS & CO. 10 April, 1968 [14 March, 1967], No. 17404/68. Heading C3P. A composition comprises a linear sulphurcurable EODM polymer, carbon black and oil, in which the polymer has a modulus (M 60 ) of 175-420 p.s.i., a glass transition temperature below 0‹ C., an inherent viscosity of at least 2À2, the oil is present in 75-200 parts per hundred parts of polymer (phr), the carbon black is present in from 52À5 to 300 phr, the amount of carbon black being at least 0À3 of the amount of polymer and oil. Preferably an EPDM polymer is used such as a terpolymer of ethylene, propylene and 1,4-hexadiene. A preferred composition contains the above terpolymer having monomer unit proportions of 72/25/3, an M 60 of 250, and an inherent viscosity of 2À5, which is extended with 150 phr oil and 125 phr ISAF carbon black. In the examples, an ethylene/ propylene/1,4-hexadiene terpolymer is prepared by polymerizing the appropriate monomers in tetrachloroethylene solution, in the presence of a catalyst prepared in situ by mixing diisobutyl aluminium chloride with vanadium tetrachloride. The terpolymer produced was then compounded with naphthenic petroleum oil, ISAF carbon black, zinc oxide, stearic acid, sulphur, 2-mercaptobenzothiazole, and tetramethyl thiuram sulphide.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US63082167A | 1967-04-14 | 1967-04-14 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1158974A true GB1158974A (en) | 1969-07-23 |
Family
ID=24528682
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB17404/68A Expired GB1158974A (en) | 1967-04-14 | 1968-04-10 | Oil and Black Loaded Ethylene-Rich EODM Polymers. |
Country Status (3)
| Country | Link |
|---|---|
| FR (1) | FR1564164A (en) |
| GB (1) | GB1158974A (en) |
| NL (1) | NL6805209A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4421678A (en) | 1980-12-29 | 1983-12-20 | Union Carbide Corporation | Electrically conductive compositions comprising an ethylene polymer, a mineral filler and an oiled, electrically conductive carbon black |
| US4510078A (en) * | 1980-12-29 | 1985-04-09 | Union Carbide Corp. | Oiled, electrically conductive carbon black |
| DE3633883A1 (en) * | 1986-10-04 | 1988-04-14 | Minnesota Mining & Mfg | Mouldable plastic composition for the production of electroconductive, elastomeric plastic articles |
-
1968
- 1968-04-10 GB GB17404/68A patent/GB1158974A/en not_active Expired
- 1968-04-11 NL NL6805209A patent/NL6805209A/xx unknown
- 1968-04-12 FR FR1564164D patent/FR1564164A/fr not_active Expired
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4421678A (en) | 1980-12-29 | 1983-12-20 | Union Carbide Corporation | Electrically conductive compositions comprising an ethylene polymer, a mineral filler and an oiled, electrically conductive carbon black |
| US4510078A (en) * | 1980-12-29 | 1985-04-09 | Union Carbide Corp. | Oiled, electrically conductive carbon black |
| DE3633883A1 (en) * | 1986-10-04 | 1988-04-14 | Minnesota Mining & Mfg | Mouldable plastic composition for the production of electroconductive, elastomeric plastic articles |
Also Published As
| Publication number | Publication date |
|---|---|
| NL6805209A (en) | 1968-10-15 |
| DE1769142B2 (en) | 1976-06-10 |
| FR1564164A (en) | 1969-04-18 |
| DE1769142A1 (en) | 1971-09-16 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US3671492A (en) | 1:1 alternating copolymers of carbonyl or thiocarbonyl-containing non-conjugated compounds and conjugated compounds and method of preparation | |
| US3440237A (en) | Production of polyethylene with water-modified ziegler catalyst | |
| US3478002A (en) | Copolymers of substituted norbornenes and olefins and process for producing the same | |
| GB972543A (en) | Improvements relating to hydrocarbon copolymers | |
| GB1158974A (en) | Oil and Black Loaded Ethylene-Rich EODM Polymers. | |
| GB851062A (en) | Unsaturated sulfonamides of chlorosulfonated olefin polymers | |
| US3814734A (en) | Multicomponent interpolymers having alternating sequential structure | |
| US3328366A (en) | Polymerization of ethylene and an alpha-olefin in the presence of an alkyl aluminum halide, a vanadium compound and an organic compound containing sulfur, oxygen and a halogen | |
| US3166538A (en) | Copolymerization process | |
| US3153023A (en) | Copolymers of ethylene and propylene | |
| US3317499A (en) | Ziegler-natta type olefin polymerization catalyst modified with organic acid halides or sulfur containing organic acid halides | |
| US3506627A (en) | Copolymerization of alpha olefins in the presence of vinylidene aromatic hydrocarbons | |
| US3431245A (en) | Production of novel polymers and polymerization process therefor | |
| GB1338684A (en) | Continuous process for the production of ethylene copolymers | |
| US2447610A (en) | Solid halogen derivatives of polymerized methyl pentadiene | |
| DE2110189A1 (en) | Olefin acrylic acid ester copolymers which can be crosslinked with sulfur and process for their production | |
| US2356130A (en) | Olefin-diolefin copolymers | |
| US2456354A (en) | Copolymers of iso-olefins with thiophene sulfones and process for making same | |
| US3631007A (en) | Removal of vanadium residues from ethylene copolymers | |
| Lal | Polymerization of olefin oxides and of olefin sulfides | |
| US2418912A (en) | Interpolymer of isoolefine and polyolefine | |
| GB1161955A (en) | Fluorocarbon Polymers comprising Carbonyl Groups | |
| GB1230888A (en) | ||
| GB1108387A (en) | Improvements relating to elastomeric polymers | |
| GB834302A (en) | Polymers |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed | ||
| PCNP | Patent ceased through non-payment of renewal fee |