GB1031487A - Stabilized halogen-containing resins - Google Patents
Stabilized halogen-containing resinsInfo
- Publication number
- GB1031487A GB1031487A GB1256763A GB1256763A GB1031487A GB 1031487 A GB1031487 A GB 1031487A GB 1256763 A GB1256763 A GB 1256763A GB 1256763 A GB1256763 A GB 1256763A GB 1031487 A GB1031487 A GB 1031487A
- Authority
- GB
- United Kingdom
- Prior art keywords
- sulphide
- dilauryl
- dibutyl tin
- vinyl
- tin maleate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229910052736 halogen Inorganic materials 0.000 title abstract 2
- 150000002367 halogens Chemical class 0.000 title abstract 2
- 229920005989 resin Polymers 0.000 title 1
- 239000011347 resin Substances 0.000 title 1
- 229920000642 polymer Polymers 0.000 abstract 5
- ZBBLRPRYYSJUCZ-GRHBHMESSA-L (z)-but-2-enedioate;dibutyltin(2+) Chemical compound [O-]C(=O)\C=C/C([O-])=O.CCCC[Sn+2]CCCC ZBBLRPRYYSJUCZ-GRHBHMESSA-L 0.000 abstract 3
- 239000000203 mixture Substances 0.000 abstract 3
- 239000003381 stabilizer Substances 0.000 abstract 3
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 abstract 2
- HJIAMFHSAAEUKR-UHFFFAOYSA-N (2-hydroxyphenyl)-phenylmethanone Chemical class OC1=CC=CC=C1C(=O)C1=CC=CC=C1 HJIAMFHSAAEUKR-UHFFFAOYSA-N 0.000 abstract 1
- NOVDFJALTKXOLA-UHFFFAOYSA-N (Z)-1-dodecylsulfanyloctadec-9-ene Chemical compound C(CCCCCCCCCCC)SCCCCCCCCC=C/CCCCCCCC NOVDFJALTKXOLA-UHFFFAOYSA-N 0.000 abstract 1
- GAYUSSOCODCSNF-UHFFFAOYSA-N 1-(dodecyldisulfanyl)dodecane Chemical compound CCCCCCCCCCCCSSCCCCCCCCCCCC GAYUSSOCODCSNF-UHFFFAOYSA-N 0.000 abstract 1
- KUUNNVBBPBDFJZ-UHFFFAOYSA-N 1-dodecylselanyldodecane Chemical compound CCCCCCCCCCCC[Se]CCCCCCCCCCCC KUUNNVBBPBDFJZ-UHFFFAOYSA-N 0.000 abstract 1
- UPYPTOCXMIWHSG-UHFFFAOYSA-N 1-dodecylsulfanyldodecane Chemical compound CCCCCCCCCCCCSCCCCCCCCCCCC UPYPTOCXMIWHSG-UHFFFAOYSA-N 0.000 abstract 1
- BPZXAXPNZGKTQU-UHFFFAOYSA-N 1-dodecylsulfanyloctadecane Chemical compound CCCCCCCCCCCCCCCCCCSCCCCCCCCCCCC BPZXAXPNZGKTQU-UHFFFAOYSA-N 0.000 abstract 1
- PZKDFFVFMXTDIP-UHFFFAOYSA-N 1-dodecylsulfinyldodecane Chemical compound CCCCCCCCCCCCS(=O)CCCCCCCCCCCC PZKDFFVFMXTDIP-UHFFFAOYSA-N 0.000 abstract 1
- IHWDIGHWDQPQMQ-UHFFFAOYSA-N 1-octadecylsulfanyloctadecane Chemical compound CCCCCCCCCCCCCCCCCCSCCCCCCCCCCCCCCCCCC IHWDIGHWDQPQMQ-UHFFFAOYSA-N 0.000 abstract 1
- BYVQSTPBZLHLCF-UHFFFAOYSA-N 1-tert-butylsulfanyldodecane Chemical compound CCCCCCCCCCCCSC(C)(C)C BYVQSTPBZLHLCF-UHFFFAOYSA-N 0.000 abstract 1
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 abstract 1
- 239000004709 Chlorinated polyethylene Substances 0.000 abstract 1
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 abstract 1
- 244000068988 Glycine max Species 0.000 abstract 1
- 235000010469 Glycine max Nutrition 0.000 abstract 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 1
- 239000005864 Sulphur Substances 0.000 abstract 1
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical class C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 abstract 1
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 abstract 1
- INLLPKCGLOXCIV-UHFFFAOYSA-N bromoethene Chemical compound BrC=C INLLPKCGLOXCIV-UHFFFAOYSA-N 0.000 abstract 1
- PZGVVCOOWYSSGB-UHFFFAOYSA-L but-2-enedioate;dioctyltin(2+) Chemical compound CCCCCCCC[Sn]1(CCCCCCCC)OC(=O)C=CC(=O)O1 PZGVVCOOWYSSGB-UHFFFAOYSA-L 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 229920001577 copolymer Polymers 0.000 abstract 1
- LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical compound C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 abstract 1
- AYOHIQLKSOJJQH-UHFFFAOYSA-N dibutyltin Chemical compound CCCC[Sn]CCCC AYOHIQLKSOJJQH-UHFFFAOYSA-N 0.000 abstract 1
- HGQSXVKHVMGQRG-UHFFFAOYSA-N dioctyltin Chemical compound CCCCCCCC[Sn]CCCCCCCC HGQSXVKHVMGQRG-UHFFFAOYSA-N 0.000 abstract 1
- 239000003822 epoxy resin Substances 0.000 abstract 1
- 239000000945 filler Substances 0.000 abstract 1
- XUCNUKMRBVNAPB-UHFFFAOYSA-N fluoroethene Chemical compound FC=C XUCNUKMRBVNAPB-UHFFFAOYSA-N 0.000 abstract 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 abstract 1
- DXGLGDHPHMLXJC-UHFFFAOYSA-N oxybenzone Chemical compound OC1=CC(OC)=CC=C1C(=O)C1=CC=CC=C1 DXGLGDHPHMLXJC-UHFFFAOYSA-N 0.000 abstract 1
- 239000000049 pigment Substances 0.000 abstract 1
- 239000004014 plasticizer Substances 0.000 abstract 1
- 229920000647 polyepoxide Polymers 0.000 abstract 1
- 229920000915 polyvinyl chloride Polymers 0.000 abstract 1
- 239000004800 polyvinyl chloride Substances 0.000 abstract 1
- 150000003346 selenoethers Chemical class 0.000 abstract 1
- 150000003568 thioethers Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/37—Thiols
- C08K5/372—Sulfides, e.g. R-(S)x-R'
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/56—Organo-metallic compounds, i.e. organic compounds containing a metal-to-carbon bond
- C08K5/57—Organo-tin compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Compositions comprise a halogen-containing polymer and as stabilizers 0.01 to 10 weight per cent based on the polymer of at least one sulphur free organotin compound and 0.01 to 5 weight per cent based on the polymer of at least one thioether. Specified polymers are polymers of vinyl chloride, vinyl bromide, vinyl fluoride and vinylidene chloride, and chlorinated polyethylene. The compositions may also comprise plasticizers, fillers, pigments and dyestuffs, and further stabilizers, e.g. organic sulphoxides, disulphides and selenides, epoxy resins, hydroxybenzophenones and benztriazoles. Many suitable stabilizer components are listed and examples describe compositions comprising polyvinyl chloride, and (1) dibutyl tin maleate, dilauryl sulphide and dilauryl disulphide; (2) dibutyl tin maleate, lauryloleyl sulphide and dilauryl sulphoxide; (3) dioctyl phthalate, dibutyl tin crotonate and laurylstearyl sulphide; (5) dibutyl tin maleate and lauryl tert-butyl sulphide, and (6) dioctyl tin di-(butylmaleate), distearyl sulphide, epoxidized soya bean oil and 2-hydroxy-4-methoxy benzophenone; and comprising (4) a vinyl chloride/vinyl acetate copolymer, dioctyl tin maleate, dilaurylthiopropionate and dilauryl selenide.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE1962D0038602 DE1296798B (en) | 1962-04-06 | 1962-04-06 | Stabilizing halogen-containing polymers |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1031487A true GB1031487A (en) | 1966-06-02 |
Family
ID=7044217
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB1256763A Expired GB1031487A (en) | 1962-04-06 | 1963-03-29 | Stabilized halogen-containing resins |
Country Status (6)
| Country | Link |
|---|---|
| AT (1) | AT248125B (en) |
| BE (1) | BE630458A (en) |
| CH (1) | CH436701A (en) |
| DE (1) | DE1296798B (en) |
| GB (1) | GB1031487A (en) |
| NL (2) | NL133872C (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4611012A (en) * | 1979-02-22 | 1986-09-09 | Ciba-Geigy Corporation | Mixtures of organo-tin compounds |
| EP1004625A1 (en) * | 1998-11-25 | 2000-05-31 | Rohm And Haas Company | Stabilizers for improved weatherability of clear polyvinyl chloride compositions |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB827393A (en) * | 1955-11-07 | 1960-02-03 | Metal & Thermit Corp | Stabilized vinyl chloride polymers |
-
0
- NL NL291199D patent/NL291199A/xx unknown
- NL NL133872D patent/NL133872C/xx active
- BE BE630458D patent/BE630458A/xx unknown
-
1962
- 1962-04-06 DE DE1962D0038602 patent/DE1296798B/en active Pending
-
1963
- 1963-03-29 GB GB1256763A patent/GB1031487A/en not_active Expired
- 1963-04-01 AT AT261163A patent/AT248125B/en active
- 1963-04-02 CH CH414663A patent/CH436701A/en unknown
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4611012A (en) * | 1979-02-22 | 1986-09-09 | Ciba-Geigy Corporation | Mixtures of organo-tin compounds |
| US4698368A (en) * | 1979-02-22 | 1987-10-06 | Ciba-Geigy Corporation | Mixtures of organo-tin compounds |
| EP1004625A1 (en) * | 1998-11-25 | 2000-05-31 | Rohm And Haas Company | Stabilizers for improved weatherability of clear polyvinyl chloride compositions |
| US6258880B1 (en) | 1998-11-25 | 2001-07-10 | Morton International, Inc. | Stabilizers for improved weatherability of clear polyvinyl chloride compositions |
| SG87855A1 (en) * | 1998-11-25 | 2002-04-16 | Rohm & Haas | Stabilizers for improved weatherability of clear polyvinyl chloride compositions |
Also Published As
| Publication number | Publication date |
|---|---|
| DE1296798B (en) | 1969-06-04 |
| NL291199A (en) | |
| BE630458A (en) | |
| AT248125B (en) | 1966-07-11 |
| NL133872C (en) | |
| CH436701A (en) | 1967-05-31 |
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