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GB1031130A - Preparation of ashless lubricant additives, additives thus prepared and lubricants containing them - Google Patents

Preparation of ashless lubricant additives, additives thus prepared and lubricants containing them

Info

Publication number
GB1031130A
GB1031130A GB11372/65A GB1137265A GB1031130A GB 1031130 A GB1031130 A GB 1031130A GB 11372/65 A GB11372/65 A GB 11372/65A GB 1137265 A GB1137265 A GB 1137265A GB 1031130 A GB1031130 A GB 1031130A
Authority
GB
United Kingdom
Prior art keywords
groups
lubricating
succinic
aminomethane
hydroxymethyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB11372/65A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SHELL INT RESEARCH
Shell Internationale Research Maatschappij BV
Original Assignee
SHELL INT RESEARCH
Shell Internationale Research Maatschappij BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SHELL INT RESEARCH, Shell Internationale Research Maatschappij BV filed Critical SHELL INT RESEARCH
Publication of GB1031130A publication Critical patent/GB1031130A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M1/00—Liquid compositions essentially based on mineral lubricating oils or fatty oils; Their use as lubricants
    • C10M1/08—Liquid compositions essentially based on mineral lubricating oils or fatty oils; Their use as lubricants with additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/30—Introducing nitrogen atoms or nitrogen-containing groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2800/00—Copolymer characterised by the proportions of the comonomers expressed
    • C08F2800/10—Copolymer characterised by the proportions of the comonomers expressed as molar percentages
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/40—Fatty vegetable or animal oils
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/40—Fatty vegetable or animal oils
    • C10M2207/404—Fatty vegetable or animal oils obtained from genetically modified species
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2215/042—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Alkoxylated derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
    • C10M2215/08—Amides [having hydrocarbon substituents containing less than thirty carbon atoms]
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
    • C10M2215/08—Amides [having hydrocarbon substituents containing less than thirty carbon atoms]
    • C10M2215/082—Amides [having hydrocarbon substituents containing less than thirty carbon atoms] containing hydroxyl groups; Alkoxylated derivatives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
    • C10M2215/086—Imides [having hydrocarbon substituents containing less than thirty carbon atoms]
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
    • C10M2215/12—Partial amides of polycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
    • C10M2215/24—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions having hydrocarbon substituents containing thirty or more carbon atoms, e.g. nitrogen derivatives of substituted succinic acid
    • C10M2215/28—Amides; Imides
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/04—Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2217/042—Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds between the nitrogen-containing monomer and an aldehyde or ketone
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/04—Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2217/043—Mannich bases
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2050/00—Form in which the lubricant is applied to the material being lubricated
    • C10N2050/10—Form in which the lubricant is applied to the material being lubricated semi-solid; greasy
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2070/00—Specific manufacturing methods for lubricant compositions
    • C10N2070/02—Concentrating of additives
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02B—INTERNAL-COMBUSTION PISTON ENGINES; COMBUSTION ENGINES IN GENERAL
    • F02B3/00—Engines characterised by air compression and subsequent fuel addition
    • F02B3/06—Engines characterised by air compression and subsequent fuel addition with compression ignition

Landscapes

  • Chemical & Material Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Lubricants (AREA)

Abstract

Ashless lubricating additives containing an oleophilic hydrocarbon chain and at least two polar groups and prepared by reacting a polyolefine which carries as substituents at least two succinic acid groups, succinic anhydride groups or succinic halide groups with an aliphatic amine which has at least one alkyl group of which at least one hydrogen atom has been replaced by an hydroxyl group, may be added to mineral or synthetic lubricating oils or to lubricating oils containing fatty oils or to lubricating greases. The amine preferably contains at least three hydroxyl groups and may be a primary, secondary or tertiary amine. In the examples lubricating additives (a) and (b) are tested in a gasoline engine and a diesel engine, the base oil being a paraffinic lubricating oil distillate of viscosity 11.5 cS. at 98.9 DEG C. in the diesel engine, and of the same type but of viscosity 7.2 cS. at 98.9 DEG C. in the gasoline engine. Additive (a) is obtained by treating a chlorinated ethylene-propylene rubber with maleic anhydride and then treating the product with tris-(hydroxymethyl)-aminomethane and additive (b) is obtained by treating an isobutene-isoprene rubber with maleic anhydride and then with tris-(hydroxymethyl)-aminomethane.ALSO:Ashless lubricating additives containing an oleophilic hydrocarbon chain and at least two polar groups are obtained by reacting a polyolefine which carries as substituents at least two succinic acid groups, succinic anhydride groups or succinic halide groups, with an aliphatic amine which has at least one alkyl group of which at least one hydrogen atom has been replaced by a hydroxyl group. The amine preferably contains at least three hydroxyl groups and may be a primary, secondary or tertiary amine. In the Examples: (1) a chlorinated ethylene-propylene rubber is treated with maleic anhydride and then with tris-(hydroxymethyl) aminomethane; (2) an isobutene-isoprene rubber is treated with maleic anhydride and then with tris-(hydroxymethyl)-aminomethane.
GB11372/65A 1964-03-19 1965-03-17 Preparation of ashless lubricant additives, additives thus prepared and lubricants containing them Expired GB1031130A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
NL646402969A NL142429B (en) 1964-03-19 1964-03-19 PROCESS FOR PREPARING AN ASH-FREE COMPOUND SUITABLE AS A LUBRICANT ADDITIVE.

Publications (1)

Publication Number Publication Date
GB1031130A true GB1031130A (en) 1966-05-25

Family

ID=19789610

Family Applications (1)

Application Number Title Priority Date Filing Date
GB11372/65A Expired GB1031130A (en) 1964-03-19 1965-03-17 Preparation of ashless lubricant additives, additives thus prepared and lubricants containing them

Country Status (4)

Country Link
DE (1) DE1645260A1 (en)
FR (1) FR1432014A (en)
GB (1) GB1031130A (en)
NL (1) NL142429B (en)

Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2512201A1 (en) * 1974-03-27 1975-10-09 Exxon Research Engineering Co DICARBONIC ACID DERIVATIVES, PROCESS FOR THEIR MANUFACTURING AND LUBRICANTS AND FUELS CONTAINING THESE ADDITIVES
FR2319703A1 (en) * 1975-08-01 1977-02-25 Mobil Oil NEW LUBRICATING COMPOSITIONS WITH IMPROVED ANTI-WEAR PROPERTIES
US4368133A (en) 1979-04-02 1983-01-11 The Lubrizol Corporation Aqueous systems containing nitrogen-containing, phosphorous-free carboxylic solubilizer/surfactant additives
US4435297A (en) 1978-09-27 1984-03-06 The Lubrizol Corporation Carboxylic acid derivatives of alkanol tertiary monoamines
US4447348A (en) * 1981-02-25 1984-05-08 The Lubrizol Corporation Carboxylic solubilizer/surfactant combinations and aqueous compositions containing same
US4448703A (en) * 1981-02-25 1984-05-15 The Lubrizol Corporation Carboxylic solubilizer/surfactant combinations and aqueous compositions containing same
US4666620A (en) * 1978-09-27 1987-05-19 The Lubrizol Corporation Carboxylic solubilizer/surfactant combinations and aqueous compositions containing same
US4708753A (en) * 1985-12-06 1987-11-24 The Lubrizol Corporation Water-in-oil emulsions
US4770803A (en) * 1986-07-03 1988-09-13 The Lubrizol Corporation Aqueous compositions containing carboxylic salts
US4828633A (en) 1987-12-23 1989-05-09 The Lubrizol Corporation Salt compositions for explosives
US4840687A (en) * 1986-11-14 1989-06-20 The Lubrizol Corporation Explosive compositions
US4844756A (en) 1985-12-06 1989-07-04 The Lubrizol Corporation Water-in-oil emulsions
US4863534A (en) * 1987-12-23 1989-09-05 The Lubrizol Corporation Explosive compositions using a combination of emulsifying salts
US5047175A (en) 1987-12-23 1991-09-10 The Lubrizol Corporation Salt composition and explosives using same
EP0490454A1 (en) * 1990-12-12 1992-06-17 Shell Internationale Researchmaatschappij B.V. Alkenyl succinimides as luboil additives
USRE36479E (en) * 1986-07-03 2000-01-04 The Lubrizol Corporation Aqueous compositions containing nitrogen-containing salts

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2437242A1 (en) * 1978-09-27 1980-04-25 Lubrizol Corp CARBOXYLIC SOLUBILIZER / SURFACTANT AGENT COMBINATIONS AND COMPOSITIONS CONTAINING THEM
US4632962A (en) * 1984-12-24 1986-12-30 General Electric Company Hydroxyl group graft modified polyolefins
US4966947A (en) * 1988-05-20 1990-10-30 Eastman Kodak Company Modified chlorinated polyolefins

Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2512201A1 (en) * 1974-03-27 1975-10-09 Exxon Research Engineering Co DICARBONIC ACID DERIVATIVES, PROCESS FOR THEIR MANUFACTURING AND LUBRICANTS AND FUELS CONTAINING THESE ADDITIVES
FR2319703A1 (en) * 1975-08-01 1977-02-25 Mobil Oil NEW LUBRICATING COMPOSITIONS WITH IMPROVED ANTI-WEAR PROPERTIES
US4435297A (en) 1978-09-27 1984-03-06 The Lubrizol Corporation Carboxylic acid derivatives of alkanol tertiary monoamines
US4666620A (en) * 1978-09-27 1987-05-19 The Lubrizol Corporation Carboxylic solubilizer/surfactant combinations and aqueous compositions containing same
US4368133A (en) 1979-04-02 1983-01-11 The Lubrizol Corporation Aqueous systems containing nitrogen-containing, phosphorous-free carboxylic solubilizer/surfactant additives
US4447348A (en) * 1981-02-25 1984-05-08 The Lubrizol Corporation Carboxylic solubilizer/surfactant combinations and aqueous compositions containing same
US4448703A (en) * 1981-02-25 1984-05-15 The Lubrizol Corporation Carboxylic solubilizer/surfactant combinations and aqueous compositions containing same
US4844756A (en) 1985-12-06 1989-07-04 The Lubrizol Corporation Water-in-oil emulsions
US4708753A (en) * 1985-12-06 1987-11-24 The Lubrizol Corporation Water-in-oil emulsions
US4770803A (en) * 1986-07-03 1988-09-13 The Lubrizol Corporation Aqueous compositions containing carboxylic salts
USRE36479E (en) * 1986-07-03 2000-01-04 The Lubrizol Corporation Aqueous compositions containing nitrogen-containing salts
US4840687A (en) * 1986-11-14 1989-06-20 The Lubrizol Corporation Explosive compositions
US4828633A (en) 1987-12-23 1989-05-09 The Lubrizol Corporation Salt compositions for explosives
US4863534A (en) * 1987-12-23 1989-09-05 The Lubrizol Corporation Explosive compositions using a combination of emulsifying salts
US5047175A (en) 1987-12-23 1991-09-10 The Lubrizol Corporation Salt composition and explosives using same
EP0490454A1 (en) * 1990-12-12 1992-06-17 Shell Internationale Researchmaatschappij B.V. Alkenyl succinimides as luboil additives

Also Published As

Publication number Publication date
DE1645260A1 (en) 1970-05-14
NL142429B (en) 1974-06-17
FR1432014A (en) 1966-03-18
NL6402969A (en) 1965-09-20

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