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GB1027023A - Reinforced polymers and process of producing same - Google Patents

Reinforced polymers and process of producing same

Info

Publication number
GB1027023A
GB1027023A GB913163A GB913163A GB1027023A GB 1027023 A GB1027023 A GB 1027023A GB 913163 A GB913163 A GB 913163A GB 913163 A GB913163 A GB 913163A GB 1027023 A GB1027023 A GB 1027023A
Authority
GB
United Kingdom
Prior art keywords
butylperoxy
dimethyl
mix
glass fibre
contain
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB913163A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Technology and Engineering Co
Original Assignee
Exxon Research and Engineering Co
Esso Research and Engineering Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxon Research and Engineering Co, Esso Research and Engineering Co filed Critical Exxon Research and Engineering Co
Publication of GB1027023A publication Critical patent/GB1027023A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/54—Silicon-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F279/00—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
    • C08F279/02—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/14—Peroxides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/54—Silicon-containing compounds
    • C08K5/541—Silicon-containing compounds containing oxygen
    • C08K5/5425—Silicon-containing compounds containing oxygen containing at least one C=C bond

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Polymerisation Methods In General (AREA)

Abstract

A shaped article is prepared by combining a filler or reinforcing element and a polymeric mix comprising a normally liquid polymer prepared from 75 to 100% of a C4 to C6 conjugated diolefin and 25 to 0% of a monovinyl monomer and curing the combination at a temperature of from 330 DEG to 550 DEG F. in the presence of a polyperoxide catalyst having a half-life of at least 2 minutes at 300 DEG F. The filler may be a silica (precipitated, ground or quartz), clay, alumina or calcium carbonate. The reinforcing element may be glass fibre, asbestos, mica, vegetable fibre, silk, hair, nylon, or a metallic material such as iron, aluminium or copper. The exemplified peroxides are 2,5-dimethyl-2,5-di-(t - butylperoxy) - hexane, 2,5 - dimethyl - 2,5 - di - (t - butylperoxy) - hexyne, di - t - butyldiperoxyphthalate or 2,5 - dimethylhexane-2,5-di-(peroxybenzoate). The liquid polymer may be mixed with rubbers, such as natural rubber, butyl rubber, or SBR, or polymers such as polyethylene, polypropylene, EPR, or polyisobutylene. The mix may contain up to 2% of a polymerizable monomer, e.g. vinyl tris-(2-methoxyethoxy)-silane or diethylamino-ethyl methacrylate as a size for the glass fibre or to aid dispersion of the filler. Small amounts of solvent may be used for the same purpose.ALSO:A glass fibre reinforcement is coated with a composition comprising a normally liquid copolymer prepared from 75 to 100% of a conjugated diene and 25 to 0% of a monovinyl compound and a polyperoxide catalyst which has a half-life of at least 2 minutes at 300 DEG F. The assembly is then cured at a temperature of from 330 to 550 DEG F. Peroxides specified are 2, 5-dimethyl-2, 5-di(t-butylperoxy)-hexane, 2, 5-dimethyl-2, 5-di(t-butylperoxy)-hexane, di-t-butyl diperoxyphthalate, and 2, 5-dimethylhexane-2, 5-di(peroxy-benzoate. The mix may also contain other polymeric ingredients, e.g. natural rubber, butyl rubber, SBR, polyethylene, polypropylene, ethylene-propylene rubber, or polyisoeutylene. The mix may also contain a small proportion of a polymerizable monomer such as vinyl tris(2-methoxyethoxy) silane and diethyl-aminoethyl methacrylate. The glass fibre may also be treated with an unsaturated silane monomer. The composition may contain fillers, e.g. silica, chalk, whiting and alumina, and antioxidants, e.g. di-t-butyl p-cresol.
GB913163A 1962-03-21 1963-03-07 Reinforced polymers and process of producing same Expired GB1027023A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US18145762A 1962-03-21 1962-03-21

Publications (1)

Publication Number Publication Date
GB1027023A true GB1027023A (en) 1966-04-20

Family

ID=22664358

Family Applications (1)

Application Number Title Priority Date Filing Date
GB913163A Expired GB1027023A (en) 1962-03-21 1963-03-07 Reinforced polymers and process of producing same

Country Status (3)

Country Link
DE (1) DE1544812A1 (en)
GB (1) GB1027023A (en)
NL (1) NL290449A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1963571A1 (en) * 1968-12-20 1970-10-29 Midland Siliconas Ltd Process for crosslinking polyolefins

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1963571A1 (en) * 1968-12-20 1970-10-29 Midland Siliconas Ltd Process for crosslinking polyolefins

Also Published As

Publication number Publication date
DE1544812A1 (en) 1970-01-29
NL290449A (en)

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