GB1020298A - Process for rendering organic high molecular weight polymers resistant to electrostatic charge - Google Patents
Process for rendering organic high molecular weight polymers resistant to electrostatic chargeInfo
- Publication number
- GB1020298A GB1020298A GB3001763A GB3001763A GB1020298A GB 1020298 A GB1020298 A GB 1020298A GB 3001763 A GB3001763 A GB 3001763A GB 3001763 A GB3001763 A GB 3001763A GB 1020298 A GB1020298 A GB 1020298A
- Authority
- GB
- United Kingdom
- Prior art keywords
- amide
- oxalic acid
- alkyl
- ester
- substituted
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920006158 high molecular weight polymer Polymers 0.000 title 1
- 238000000034 method Methods 0.000 title 1
- 238000009877 rendering Methods 0.000 title 1
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract 4
- -1 amino, substituted amino, hydroxy Chemical group 0.000 abstract 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 abstract 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 abstract 3
- 125000000217 alkyl group Chemical group 0.000 abstract 3
- SOWBFZRMHSNYGE-UHFFFAOYSA-N oxamic acid Chemical class NC(=O)C(O)=O SOWBFZRMHSNYGE-UHFFFAOYSA-N 0.000 abstract 3
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 abstract 2
- 150000001408 amides Chemical class 0.000 abstract 2
- HGCIXCUEYOPUTN-UHFFFAOYSA-N cyclohexene Chemical compound C1CCC=CC1 HGCIXCUEYOPUTN-UHFFFAOYSA-N 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 abstract 2
- WFUGQJXVXHBTEM-UHFFFAOYSA-N 2-hydroperoxy-2-(2-hydroperoxybutan-2-ylperoxy)butane Chemical compound CCC(C)(OO)OOC(C)(CC)OO WFUGQJXVXHBTEM-UHFFFAOYSA-N 0.000 abstract 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 abstract 1
- NFYLVACBTKZXMW-UHFFFAOYSA-N CCCCCCCCCCCCCCCCCCNC.OC(C(O)=O)=O Chemical compound CCCCCCCCCCCCCCCCCCNC.OC(C(O)=O)=O NFYLVACBTKZXMW-UHFFFAOYSA-N 0.000 abstract 1
- 229930040373 Paraformaldehyde Natural products 0.000 abstract 1
- 239000004952 Polyamide Substances 0.000 abstract 1
- 239000004698 Polyethylene Substances 0.000 abstract 1
- 239000004743 Polypropylene Substances 0.000 abstract 1
- 239000004793 Polystyrene Substances 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 125000003545 alkoxy group Chemical group 0.000 abstract 1
- PBGVMIDTGGTBFS-UHFFFAOYSA-N but-3-enylbenzene Chemical compound C=CCCC1=CC=CC=C1 PBGVMIDTGGTBFS-UHFFFAOYSA-N 0.000 abstract 1
- 125000004181 carboxyalkyl group Chemical group 0.000 abstract 1
- 239000003153 chemical reaction reagent Substances 0.000 abstract 1
- 229920001577 copolymer Polymers 0.000 abstract 1
- 239000003822 epoxy resin Substances 0.000 abstract 1
- 150000002148 esters Chemical class 0.000 abstract 1
- 125000004494 ethyl ester group Chemical group 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 150000002367 halogens Chemical group 0.000 abstract 1
- 238000010348 incorporation Methods 0.000 abstract 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 abstract 1
- 125000005395 methacrylic acid group Chemical group 0.000 abstract 1
- YEZAGQUWHKQANM-UHFFFAOYSA-N methyl 2-(dodecylamino)-2-oxoacetate Chemical compound COC(C(=O)NCCCCCCCCCCCC)=O YEZAGQUWHKQANM-UHFFFAOYSA-N 0.000 abstract 1
- CLKWHNAOVCSSNW-UHFFFAOYSA-N n'-octadecyloxamide Chemical compound CCCCCCCCCCCCCCCCCCNC(=O)C(N)=O CLKWHNAOVCSSNW-UHFFFAOYSA-N 0.000 abstract 1
- TWIZJMJMFUHFQB-UHFFFAOYSA-N n,n'-dioctadecyloxamide Chemical compound CCCCCCCCCCCCCCCCCCNC(=O)C(=O)NCCCCCCCCCCCCCCCCCC TWIZJMJMFUHFQB-UHFFFAOYSA-N 0.000 abstract 1
- GEMHFKXPOCTAIP-UHFFFAOYSA-N n,n-dimethyl-n'-phenylcarbamimidoyl chloride Chemical compound CN(C)C(Cl)=NC1=CC=CC=C1 GEMHFKXPOCTAIP-UHFFFAOYSA-N 0.000 abstract 1
- KKFHAJHLJHVUDM-UHFFFAOYSA-N n-vinylcarbazole Chemical compound C1=CC=C2N(C=C)C3=CC=CC=C3C2=C1 KKFHAJHLJHVUDM-UHFFFAOYSA-N 0.000 abstract 1
- 229920000620 organic polymer Polymers 0.000 abstract 1
- 235000006408 oxalic acid Nutrition 0.000 abstract 1
- 229920002239 polyacrylonitrile Polymers 0.000 abstract 1
- 229920002647 polyamide Polymers 0.000 abstract 1
- 229920001748 polybutylene Polymers 0.000 abstract 1
- 239000004417 polycarbonate Substances 0.000 abstract 1
- 229920000515 polycarbonate Polymers 0.000 abstract 1
- 229920000647 polyepoxide Polymers 0.000 abstract 1
- 229920000728 polyester Polymers 0.000 abstract 1
- 229920000573 polyethylene Polymers 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 230000000379 polymerizing effect Effects 0.000 abstract 1
- 229920000098 polyolefin Polymers 0.000 abstract 1
- 229920006324 polyoxymethylene Polymers 0.000 abstract 1
- 229920001155 polypropylene Polymers 0.000 abstract 1
- 229920002223 polystyrene Polymers 0.000 abstract 1
- 229920002635 polyurethane Polymers 0.000 abstract 1
- 239000004814 polyurethane Substances 0.000 abstract 1
- 229920000915 polyvinyl chloride Polymers 0.000 abstract 1
- 239000004800 polyvinyl chloride Substances 0.000 abstract 1
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical compound CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 abstract 1
- 229920002554 vinyl polymer Polymers 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/20—Carboxylic acid amides
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Organic polymers are rendered resistant to electrostatic charge by incorporation of one or more substituted oxalic acid amides of formula <FORM:1020298/C3/1> where X is <FORM:1020298/C3/2> or-OR4, R is a C12- 24 alkyl, R1, R2 and R3 are H or a C1- 24 alkyl and R4 is a C1- 24 alkyl, the groups R, R1, R2, R3 and R4 may be substituted by halogens, amino, substituted amino, hydroxy, alkoxy or carboxyalkyl groups. The polymer may be polystyrene, a copolymer of styrene and butadiene, acrylonitrile and/or vinyl carbazole, polyvinyl chloride, a polyolefine, e.g. polyethylene, polypropylene, polybutene - (1), polyoctadecene - (1), poly - (4 - phenyl butene-1) or polyvinyl cyclohexene, polyacrylonitrile, poly-(acrylic or methacrylic) acid ester, polyoxymethylene, a polyterephthalate, a polycarbonate, a polyamide, a polyurethane, an epoxide resin hardened with a basic reagent, or a polyester, e.g. derived by condensing ethylene glycol, maleic anhydride and phthalic acid an then polymerizing with styrene in the presence of methyl ethyl ketone peroxide, cobalt naphthenate and the oxalic amide. The composition may contain 0.1-7% of the oxalic acid amide which may be oxalic acid N-methyl N-stearyl amide (amide or ethyl ester), oxalic acid N,N-disteryl amide butyl ester, oxalic acid N-lauryl amide methyl ester, oxalic acid N-stearyl amide amide or oxalic acid di-(N-stearyl amide). The compositions may be granulated and mouled into plates.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE1962F0037449 DE1243381B (en) | 1962-07-28 | 1962-07-28 | Antistatic equipment for high molecular weight compounds |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1020298A true GB1020298A (en) | 1966-02-16 |
Family
ID=7096890
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB3001763A Expired GB1020298A (en) | 1962-07-28 | 1963-07-29 | Process for rendering organic high molecular weight polymers resistant to electrostatic charge |
Country Status (5)
| Country | Link |
|---|---|
| AT (1) | AT250027B (en) |
| CH (1) | CH436702A (en) |
| DK (1) | DK104430C (en) |
| FI (1) | FI40585B (en) |
| GB (1) | GB1020298A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3388104A (en) * | 1964-12-31 | 1968-06-11 | Monsanto Co | Polycarbonamides having an improved antistatic property |
-
1963
- 1963-07-26 AT AT598863A patent/AT250027B/en active
- 1963-07-26 DK DK358763A patent/DK104430C/en active
- 1963-07-26 FI FI146963A patent/FI40585B/fi active
- 1963-07-26 CH CH933563A patent/CH436702A/en unknown
- 1963-07-29 GB GB3001763A patent/GB1020298A/en not_active Expired
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3388104A (en) * | 1964-12-31 | 1968-06-11 | Monsanto Co | Polycarbonamides having an improved antistatic property |
Also Published As
| Publication number | Publication date |
|---|---|
| FI40585B (en) | 1968-11-30 |
| DK104430C (en) | 1966-05-16 |
| CH436702A (en) | 1967-05-31 |
| AT250027B (en) | 1966-10-25 |
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