GB1017341A - Process for the production of barium salts - Google Patents
Process for the production of barium saltsInfo
- Publication number
- GB1017341A GB1017341A GB15289/62A GB1528962A GB1017341A GB 1017341 A GB1017341 A GB 1017341A GB 15289/62 A GB15289/62 A GB 15289/62A GB 1528962 A GB1528962 A GB 1528962A GB 1017341 A GB1017341 A GB 1017341A
- Authority
- GB
- United Kingdom
- Prior art keywords
- barium
- exchange resin
- resin
- solution
- anion
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 159000000009 barium salts Chemical class 0.000 title abstract 9
- 239000011347 resin Substances 0.000 abstract 9
- 229920005989 resin Polymers 0.000 abstract 9
- 239000000243 solution Substances 0.000 abstract 7
- 239000003957 anion exchange resin Substances 0.000 abstract 6
- 150000001450 anions Chemical class 0.000 abstract 5
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 abstract 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract 4
- 239000007864 aqueous solution Substances 0.000 abstract 4
- CJDPJFRMHVXWPT-UHFFFAOYSA-N barium sulfide Chemical compound [S-2].[Ba+2] CJDPJFRMHVXWPT-UHFFFAOYSA-N 0.000 abstract 4
- 239000003729 cation exchange resin Substances 0.000 abstract 4
- 229910052708 sodium Inorganic materials 0.000 abstract 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 4
- ITHZDDVSAWDQPZ-UHFFFAOYSA-L barium acetate Chemical compound [Ba+2].CC([O-])=O.CC([O-])=O ITHZDDVSAWDQPZ-UHFFFAOYSA-L 0.000 abstract 3
- 239000011734 sodium Substances 0.000 abstract 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical group [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 abstract 2
- 230000002378 acidificating effect Effects 0.000 abstract 2
- 239000006286 aqueous extract Substances 0.000 abstract 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 abstract 2
- 239000000571 coke Substances 0.000 abstract 2
- SCVFZCLFOSHCOH-UHFFFAOYSA-M potassium acetate Chemical compound [K+].CC([O-])=O SCVFZCLFOSHCOH-UHFFFAOYSA-M 0.000 abstract 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 abstract 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical group CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 abstract 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 abstract 1
- 229910002651 NO3 Inorganic materials 0.000 abstract 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 abstract 1
- 235000011056 potassium acetate Nutrition 0.000 abstract 1
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 abstract 1
- 239000001632 sodium acetate Substances 0.000 abstract 1
- 235000017281 sodium acetate Nutrition 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F11/00—Compounds of calcium, strontium, or barium
- C01F11/02—Oxides or hydroxides
- C01F11/10—Oxides or hydroxides from sulfides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J39/00—Cation exchange; Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
- B01J39/04—Processes using organic exchangers
- B01J39/05—Processes using organic exchangers in the strongly acidic form
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J47/00—Ion-exchange processes in general; Apparatus therefor
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F11/00—Compounds of calcium, strontium, or barium
- C01F11/005—Preparation involving liquid-liquid extraction, absorption or ion-exchange
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F11/00—Compounds of calcium, strontium, or barium
- C01F11/02—Oxides or hydroxides
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
- Treatment Of Water By Ion Exchange (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Manufacture And Refinement Of Metals (AREA)
Abstract
Water soluble barium salts (e.g. acetate) are prepared by contacting an aqueous solution of barium sulphide either with a strongly acidic cation exchange resin in the sodium or potassium form or a strongly basic anion exchange resin in acetate form (the solution isolated from the anion exchange resin being one containing the barium acetate), and thereafter contacting the isolated exchange resin with an aqueous solution (e.g. hot) containing a sodium or potassium acetate to regenerate the resin at least partially and simultaneously insofar as the cation exchange resin is concerned, yield a solution containing the required barium acetate. The barium sulphide solution may be passed through a column or bed of the resin, may comprise an aqueous extract of clinker produced by coke or like reduction of barytes, and may be used at 50-100 DEG C. If the hydroxide form of the anion exchange resin is initially used, the required barium salt is obtained after the first cycle. Barium acetate is prepared in Example 4.ALSO:Water soluble barium salts (e.g. chloride, nitrate) are prepared by contacting an aqueous solution of barium sulphide either with a strongly acidic cation exchange resin in the sodium or potassium form or a strongly basic anion exchange resin whose anion corresponds to the anion of the barium salt required, the solution and resin being employed in amounts such that, at least in the case of the anion resin, the resin does not become exhausted (the solution isolated from the anion exchange resin being one containing the desired barium salt), and thereafter contacting the isolated exchange resin with an aqueous solution (e.g. hot) containing a sodium or potassium salt (whose anion corresponds to the anion of the barium salt required) to regenerate the resin at least partially and simultaneously insofar as the cation exchange resin is concerned, yield a solution containing the required barium salt. The barium sulphide solution may be passed through a column or bed of the resin, may comprise an aqueous extract of clinker produced by coke or like reduction of barytes, and may be used at 50-100 DEG C. If the hydroxide form of the anion exchange resin is initially used, the required barium salt is obtained after the first cycle.
Priority Applications (9)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB36791/60A GB992793A (en) | 1962-04-19 | 1960-10-26 | A process for the production of barium hydroxide |
| DEL40283A DE1206872B (en) | 1962-04-19 | 1961-10-23 | Process for the production of barium hydroxide of high purity through ion exchange |
| FR876961A FR1304465A (en) | 1962-04-19 | 1961-10-25 | Process for preparing barium hydroxide |
| GB15289/62A GB1017341A (en) | 1962-04-19 | 1962-04-19 | Process for the production of barium salts |
| GB15288/62A GB1013711A (en) | 1962-04-19 | 1962-04-19 | Process for the production of barium hydroxide |
| FR932022A FR83479E (en) | 1962-04-19 | 1963-04-19 | Process for preparing barium hydroxide |
| DE19631467272 DE1467272A1 (en) | 1962-04-19 | 1963-04-19 | Process for the production of water-soluble barium salts |
| GB41859/63A GB1119831A (en) | 1962-04-19 | 1963-10-23 | Process for the production of barium hydroxide |
| US334924A US3366449A (en) | 1962-04-19 | 1963-12-31 | Process for the production of barium hydroxide |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB15289/62A GB1017341A (en) | 1962-04-19 | 1962-04-19 | Process for the production of barium salts |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1017341A true GB1017341A (en) | 1966-01-19 |
Family
ID=10056429
Family Applications (4)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB36791/60A Expired GB992793A (en) | 1960-10-26 | 1960-10-26 | A process for the production of barium hydroxide |
| GB15289/62A Expired GB1017341A (en) | 1962-04-19 | 1962-04-19 | Process for the production of barium salts |
| GB15288/62A Expired GB1013711A (en) | 1962-04-19 | 1962-04-19 | Process for the production of barium hydroxide |
| GB41859/63A Expired GB1119831A (en) | 1962-04-19 | 1963-10-23 | Process for the production of barium hydroxide |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB36791/60A Expired GB992793A (en) | 1960-10-26 | 1960-10-26 | A process for the production of barium hydroxide |
Family Applications After (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB15288/62A Expired GB1013711A (en) | 1962-04-19 | 1962-04-19 | Process for the production of barium hydroxide |
| GB41859/63A Expired GB1119831A (en) | 1962-04-19 | 1963-10-23 | Process for the production of barium hydroxide |
Country Status (3)
| Country | Link |
|---|---|
| DE (2) | DE1206872B (en) |
| FR (2) | FR1304465A (en) |
| GB (4) | GB992793A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2183586C2 (en) * | 1999-12-23 | 2002-06-20 | Открытое акционерное общество "Сода" | Method of producing barium chloride from slime after leaching of barium sulfide fusion cake |
| ITRM20120370A1 (en) * | 2012-07-30 | 2014-01-31 | Uni Degli Studi Dell Aquila | PROCEDURE FOR THE SYNTHESIS OF NANO PARTICELLE DI CA (OH) 2 THROUGH IONIC EXCHANGE RESINS. |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2244714B1 (en) * | 1973-09-25 | 1976-11-19 | Ugine Kuhlmann | |
| FR2595089B1 (en) * | 1986-02-28 | 1990-11-02 | Rhone Poulenc Chimie | PROCESS FOR THE PURIFICATION OF A BARIUM SALT |
| US7186855B2 (en) | 2001-06-11 | 2007-03-06 | Xenoport, Inc. | Prodrugs of GABA analogs, compositions and uses thereof |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2409861A (en) * | 1942-02-02 | 1946-10-22 | Dow Chemical Co | Process and agents for the recovery of magnesium ions from brine |
| GB662314A (en) * | 1948-12-29 | 1951-12-05 | Dow Chemical Co | Improved method of producing alkali metal hydroxides |
-
1960
- 1960-10-26 GB GB36791/60A patent/GB992793A/en not_active Expired
-
1961
- 1961-10-23 DE DEL40283A patent/DE1206872B/en active Pending
- 1961-10-25 FR FR876961A patent/FR1304465A/en not_active Expired
-
1962
- 1962-04-19 GB GB15289/62A patent/GB1017341A/en not_active Expired
- 1962-04-19 GB GB15288/62A patent/GB1013711A/en not_active Expired
-
1963
- 1963-04-19 DE DE19631467272 patent/DE1467272A1/en active Pending
- 1963-04-19 FR FR932022A patent/FR83479E/en not_active Expired
- 1963-10-23 GB GB41859/63A patent/GB1119831A/en not_active Expired
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2183586C2 (en) * | 1999-12-23 | 2002-06-20 | Открытое акционерное общество "Сода" | Method of producing barium chloride from slime after leaching of barium sulfide fusion cake |
| ITRM20120370A1 (en) * | 2012-07-30 | 2014-01-31 | Uni Degli Studi Dell Aquila | PROCEDURE FOR THE SYNTHESIS OF NANO PARTICELLE DI CA (OH) 2 THROUGH IONIC EXCHANGE RESINS. |
| WO2014020515A1 (en) * | 2012-07-30 | 2014-02-06 | Università Degli Studi Dell'aquila | A process for the synthesis of ca (oh) 2 nanoparticles by means of ionic exchange resins |
Also Published As
| Publication number | Publication date |
|---|---|
| FR1304465A (en) | 1962-09-21 |
| FR83479E (en) | 1964-08-21 |
| DE1206872B (en) | 1965-12-16 |
| DE1467272A1 (en) | 1969-03-13 |
| GB1119831A (en) | 1968-07-17 |
| GB992793A (en) | 1965-05-19 |
| GB1013711A (en) | 1965-12-22 |
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