GB1013394A - Laundering process and detergent composition therefor - Google Patents
Laundering process and detergent composition thereforInfo
- Publication number
- GB1013394A GB1013394A GB13011/63A GB1301163A GB1013394A GB 1013394 A GB1013394 A GB 1013394A GB 13011/63 A GB13011/63 A GB 13011/63A GB 1301163 A GB1301163 A GB 1301163A GB 1013394 A GB1013394 A GB 1013394A
- Authority
- GB
- United Kingdom
- Prior art keywords
- sodium
- potassium
- thiosulphate
- composition
- detergent composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003599 detergent Substances 0.000 title abstract 4
- 239000000203 mixture Substances 0.000 title abstract 4
- 238000004900 laundering Methods 0.000 title abstract 2
- 238000000034 method Methods 0.000 title 1
- 229910052708 sodium Inorganic materials 0.000 abstract 4
- 239000011734 sodium Substances 0.000 abstract 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical group C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 abstract 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 2
- 229920003090 carboxymethyl hydroxyethyl cellulose Polymers 0.000 abstract 2
- 150000003839 salts Chemical class 0.000 abstract 2
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 abstract 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 abstract 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 1
- PDQAZBWRQCGBEV-UHFFFAOYSA-N Ethylenethiourea Chemical compound S=C1NCCN1 PDQAZBWRQCGBEV-UHFFFAOYSA-N 0.000 abstract 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 abstract 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical group [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 abstract 1
- 239000004115 Sodium Silicate Substances 0.000 abstract 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 abstract 1
- VNAPCLKGECSPSO-UHFFFAOYSA-N [K].CC(=O)ON(OC(C)=O)CCN(OC(C)=O)OC(C)=O Chemical compound [K].CC(=O)ON(OC(C)=O)CCN(OC(C)=O)OC(C)=O VNAPCLKGECSPSO-UHFFFAOYSA-N 0.000 abstract 1
- FENRSEGZMITUEF-ATTCVCFYSA-E [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].OP(=O)([O-])O[C@@H]1[C@@H](OP(=O)([O-])[O-])[C@H](OP(=O)(O)[O-])[C@H](OP(=O)([O-])[O-])[C@H](OP(=O)(O)[O-])[C@H]1OP(=O)([O-])[O-] Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].OP(=O)([O-])O[C@@H]1[C@@H](OP(=O)([O-])[O-])[C@H](OP(=O)(O)[O-])[C@H](OP(=O)([O-])[O-])[C@H](OP(=O)(O)[O-])[C@H]1OP(=O)([O-])[O-] FENRSEGZMITUEF-ATTCVCFYSA-E 0.000 abstract 1
- 125000001931 aliphatic group Chemical group 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 150000001408 amides Chemical class 0.000 abstract 1
- 150000001412 amines Chemical class 0.000 abstract 1
- 125000000129 anionic group Chemical group 0.000 abstract 1
- JXLHNMVSKXFWAO-UHFFFAOYSA-N azane;7-fluoro-2,1,3-benzoxadiazole-4-sulfonic acid Chemical compound N.OS(=O)(=O)C1=CC=C(F)C2=NON=C12 JXLHNMVSKXFWAO-UHFFFAOYSA-N 0.000 abstract 1
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 abstract 1
- 239000012964 benzotriazole Substances 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- -1 colour Substances 0.000 abstract 1
- 150000002148 esters Chemical class 0.000 abstract 1
- 239000007850 fluorescent dye Substances 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 238000002156 mixing Methods 0.000 abstract 1
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 abstract 1
- 239000003605 opacifier Substances 0.000 abstract 1
- 239000002304 perfume Substances 0.000 abstract 1
- 239000011591 potassium Chemical group 0.000 abstract 1
- 229910052700 potassium Inorganic materials 0.000 abstract 1
- BGHJOVPDUCMEAT-UHFFFAOYSA-M potassium;phenylmethanesulfonate Chemical compound [K+].[O-]S(=O)(=O)CC1=CC=CC=C1 BGHJOVPDUCMEAT-UHFFFAOYSA-M 0.000 abstract 1
- 239000000843 powder Substances 0.000 abstract 1
- 239000003352 sequestering agent Substances 0.000 abstract 1
- 229940083982 sodium phytate Drugs 0.000 abstract 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 abstract 1
- 229910052911 sodium silicate Inorganic materials 0.000 abstract 1
- 235000019832 sodium triphosphate Nutrition 0.000 abstract 1
- 229910021653 sulphate ion Inorganic materials 0.000 abstract 1
- 239000003760 tallow Substances 0.000 abstract 1
- RYCLIXPGLDDLTM-UHFFFAOYSA-J tetrapotassium;phosphonato phosphate Chemical compound [K+].[K+].[K+].[K+].[O-]P([O-])(=O)OP([O-])([O-])=O RYCLIXPGLDDLTM-UHFFFAOYSA-J 0.000 abstract 1
- 239000002562 thickening agent Substances 0.000 abstract 1
- 150000003568 thioethers Chemical class 0.000 abstract 1
- DHCDFWKWKRSZHF-UHFFFAOYSA-L thiosulfate(2-) Chemical compound [O-]S([S-])(=O)=O DHCDFWKWKRSZHF-UHFFFAOYSA-L 0.000 abstract 1
- LWIHDJKSTIGBAC-UHFFFAOYSA-K tripotassium phosphate Chemical compound [K+].[K+].[K+].[O-]P([O-])([O-])=O LWIHDJKSTIGBAC-UHFFFAOYSA-K 0.000 abstract 1
- 238000005406 washing Methods 0.000 abstract 1
- 239000008096 xylene Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/002—Surface-active compounds containing sulfur
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0042—Reducing agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/34—Organic compounds containing sulfur
- C11D3/3463—Organic compounds containing sulfur containing thio sulfate or sulfite groups
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
A detergent composition which is especially suitable for low temperature laundering at 40-100 DEG F., preferably 60-90 DEG F., comprises (a) an aliphatic thiosulphate of formula <FORM:1013394/C4-C5/1> wherein R and R1 are each hydrogen or C1- 18-aliphatic radical (which may include such groups as carboxyl, ester, ether, thioether, amine, amide or hydroxyl), R and R1 together contain 10-20 carbon atoms, and M is sodium, potassium, ammonium or organic substituted ammonium cation, and (b) an inorganic alkaline builder salt, such as potassium pyrophosphate and sodium tripolyphosphate, and/or an organic alkaline sequestrant builder salt, such as sodium phytate and sodium and potassium ethylenediamine tetracetate and nitrilotriacetate; the weight ratio (a) : (b) being 5 : 1-1 : 12, preferably 1 : 1-1 : 10. (a) is suitably sodium 2-hydroxy-hexadecyl or -octadecyl thiosulphate or the 2-hydroxyalkyl thiosulphate in which the alkyl group is derived from tallow alcohol. Generally (a) comprises about 7-50% and (b) about 8-90% by weight of the composition, which is suitably used so as to provide a pH of 9.5-11.5 and a concentration of (a) not below 0.01% in the washing bath. The composition may also contain sodium and potassium orthophosphate, sodium silicate, carbonate, borate, sulphate, carboxymethyl- and carboxymethyl hydroxyethyl - cellulose, and xylene sulphonate, potassium toluene sulphonate, benzotriazole, ethylene thiourea, fluorescent dye, colour, thickeners, anionic or nonionic detergents, opacifiers, blending and viscosity control agents and perfume, and may be formulated as an aqueous liquid or as a granular powder. Specification 714,212 is referred to.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US18453762A | 1962-04-02 | 1962-04-02 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1013394A true GB1013394A (en) | 1965-12-15 |
Family
ID=22677312
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB13011/63A Expired GB1013394A (en) | 1962-04-02 | 1963-04-02 | Laundering process and detergent composition therefor |
Country Status (4)
| Country | Link |
|---|---|
| BE (1) | BE660644A (en) |
| FR (1) | FR1438173A (en) |
| GB (1) | GB1013394A (en) |
| NL (1) | NL290951A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2292725A1 (en) * | 2009-08-13 | 2011-03-09 | The Procter & Gamble Company | Method of laundering fabrics at low temperature |
| US8586521B2 (en) | 2009-08-13 | 2013-11-19 | The Procter & Gamble Company | Method of laundering fabrics at low temperature |
-
0
- NL NL290951D patent/NL290951A/xx unknown
-
1963
- 1963-04-01 FR FR930034A patent/FR1438173A/en not_active Expired
- 1963-04-02 GB GB13011/63A patent/GB1013394A/en not_active Expired
-
1965
- 1965-03-04 BE BE660644A patent/BE660644A/xx unknown
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2292725A1 (en) * | 2009-08-13 | 2011-03-09 | The Procter & Gamble Company | Method of laundering fabrics at low temperature |
| WO2011025615A3 (en) * | 2009-08-13 | 2011-04-28 | The Procter & Gamble Company | Method of laundering fabrics at low temperature |
| US8586521B2 (en) | 2009-08-13 | 2013-11-19 | The Procter & Gamble Company | Method of laundering fabrics at low temperature |
Also Published As
| Publication number | Publication date |
|---|---|
| FR1438173A (en) | 1966-05-13 |
| NL290951A (en) | |
| BE660644A (en) | 1965-09-06 |
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