GB1008403A - Polymeric compounds containing silicon-nitrogen bonds - Google Patents
Polymeric compounds containing silicon-nitrogen bondsInfo
- Publication number
- GB1008403A GB1008403A GB2178/61A GB217861A GB1008403A GB 1008403 A GB1008403 A GB 1008403A GB 2178/61 A GB2178/61 A GB 2178/61A GB 217861 A GB217861 A GB 217861A GB 1008403 A GB1008403 A GB 1008403A
- Authority
- GB
- United Kingdom
- Prior art keywords
- methylamine
- ultra
- polymers
- methyldisilylamine
- silylene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920000642 polymer Polymers 0.000 title abstract 5
- BAVYZALUXZFZLV-UHFFFAOYSA-N Methylamine Chemical compound NC BAVYZALUXZFZLV-UHFFFAOYSA-N 0.000 abstract 6
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 abstract 2
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 abstract 2
- HQABUPZFAYXKJW-UHFFFAOYSA-N butan-1-amine Chemical compound CCCCN HQABUPZFAYXKJW-UHFFFAOYSA-N 0.000 abstract 2
- 125000004432 carbon atom Chemical group C* 0.000 abstract 2
- AIHCVGFMFDEUMO-UHFFFAOYSA-N diiodosilane Chemical compound I[SiH2]I AIHCVGFMFDEUMO-UHFFFAOYSA-N 0.000 abstract 2
- HCZCGHSBNHRSLG-UHFFFAOYSA-N n,n-disilylmethanamine Chemical compound CN([SiH3])[SiH3] HCZCGHSBNHRSLG-UHFFFAOYSA-N 0.000 abstract 2
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 abstract 2
- 150000003141 primary amines Chemical class 0.000 abstract 2
- 230000005855 radiation Effects 0.000 abstract 2
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 abstract 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- 239000012442 inert solvent Substances 0.000 abstract 1
- 229910052740 iodine Inorganic materials 0.000 abstract 1
- 239000011630 iodine Substances 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- OOXOBWDOWJBZHX-UHFFFAOYSA-N n-(dimethylaminosilyl)-n-methylmethanamine Chemical compound CN(C)[SiH2]N(C)C OOXOBWDOWJBZHX-UHFFFAOYSA-N 0.000 abstract 1
- 238000000197 pyrolysis Methods 0.000 abstract 1
- 239000000376 reactant Substances 0.000 abstract 1
- 229910000077 silane Inorganic materials 0.000 abstract 1
- 125000003808 silyl group Chemical group [H][Si]([H])([H])[*] 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/60—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule in which all the silicon atoms are connected by linkages other than oxygen atoms
- C08G77/62—Nitrogen atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Silicon Polymers (AREA)
Abstract
Polymers with a repeating unit SiH2-NR-, in which R is an alkyl group with not more than 5 carbon atoms or an aryl group with not more than 7 carbon atoms are prepared (a) by reacting 1 mol of silylene iodide with 3 to 3.05 mols of primary amine at a reduced temperature and in presence of a non-coordinating inert solvent for the reactants, or (b) by reacting substantially equimolecular amounts of a bis-(dialkylamine) silane with a primary amine at normal or raised temperature, or (c) by subjecting an alkyldisilylamine vapour to ultra-violet radiation, or to pyrolysis at 400-600 DEG C. Polymers with terminal silyl groups may be further polymerized by ultra-violet radiation. In Examples (1) methylamine is reacted with silylene iodide in n-hexane at low temperature. Traces of iodine may be removed from the polymer produced by treatment with dimethylamine. Aniline or n-butylamine may be used in place of methylamine; (2) bis-(dimethylamino)-silane is reacted with methylamine, or n-butylamine; (3) methyldisilylamine was irradiated with ultra-violet light; (4) methyldisilylamine was pyrolized to produce a liquid mixture of polymers.
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB2178/61A GB1008403A (en) | 1961-01-19 | 1961-01-19 | Polymeric compounds containing silicon-nitrogen bonds |
| GB9443/65A GB1123252A (en) | 1961-01-19 | 1965-03-05 | Processes for the manufacture of polymeric compounds containing nitrogen and silicon |
| US552721A US3318823A (en) | 1961-01-19 | 1966-05-25 | Polymeric compounds containing silicon-nitrogen bonds |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB2178/61A GB1008403A (en) | 1961-01-19 | 1961-01-19 | Polymeric compounds containing silicon-nitrogen bonds |
| GB9443/65A GB1123252A (en) | 1961-01-19 | 1965-03-05 | Processes for the manufacture of polymeric compounds containing nitrogen and silicon |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1008403A true GB1008403A (en) | 1965-10-27 |
Family
ID=26237342
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB2178/61A Expired GB1008403A (en) | 1961-01-19 | 1961-01-19 | Polymeric compounds containing silicon-nitrogen bonds |
| GB9443/65A Expired GB1123252A (en) | 1961-01-19 | 1965-03-05 | Processes for the manufacture of polymeric compounds containing nitrogen and silicon |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB9443/65A Expired GB1123252A (en) | 1961-01-19 | 1965-03-05 | Processes for the manufacture of polymeric compounds containing nitrogen and silicon |
Country Status (1)
| Country | Link |
|---|---|
| GB (2) | GB1008403A (en) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7875556B2 (en) * | 2005-05-16 | 2011-01-25 | Air Products And Chemicals, Inc. | Precursors for CVD silicon carbo-nitride and silicon nitride films |
| US7875312B2 (en) | 2006-05-23 | 2011-01-25 | Air Products And Chemicals, Inc. | Process for producing silicon oxide films for organoaminosilane precursors |
| US8530361B2 (en) | 2006-05-23 | 2013-09-10 | Air Products And Chemicals, Inc. | Process for producing silicon and oxide films from organoaminosilane precursors |
| US8912353B2 (en) | 2010-06-02 | 2014-12-16 | Air Products And Chemicals, Inc. | Organoaminosilane precursors and methods for depositing films comprising same |
| US8771807B2 (en) | 2011-05-24 | 2014-07-08 | Air Products And Chemicals, Inc. | Organoaminosilane precursors and methods for making and using same |
-
1961
- 1961-01-19 GB GB2178/61A patent/GB1008403A/en not_active Expired
-
1965
- 1965-03-05 GB GB9443/65A patent/GB1123252A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| GB1123252A (en) | 1968-08-14 |
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