GB1008475A - Production of hydrogen fractions enriched in deuterium - Google Patents
Production of hydrogen fractions enriched in deuteriumInfo
- Publication number
- GB1008475A GB1008475A GB2407563A GB2407563A GB1008475A GB 1008475 A GB1008475 A GB 1008475A GB 2407563 A GB2407563 A GB 2407563A GB 2407563 A GB2407563 A GB 2407563A GB 1008475 A GB1008475 A GB 1008475A
- Authority
- GB
- United Kingdom
- Prior art keywords
- deuterium
- hydrogen
- fraction
- gas
- recovered
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- YZCKVEUIGOORGS-OUBTZVSYSA-N Deuterium Chemical compound [2H] YZCKVEUIGOORGS-OUBTZVSYSA-N 0.000 title abstract 5
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title abstract 5
- 229910052805 deuterium Inorganic materials 0.000 title abstract 5
- 229910052739 hydrogen Inorganic materials 0.000 title abstract 5
- 239000001257 hydrogen Substances 0.000 title abstract 5
- 238000006243 chemical reaction Methods 0.000 abstract 4
- 239000007789 gas Substances 0.000 abstract 4
- 239000003054 catalyst Substances 0.000 abstract 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 2
- QDOXWKRWXJOMAK-UHFFFAOYSA-N dichromium trioxide Chemical compound O=[Cr]O[Cr]=O QDOXWKRWXJOMAK-UHFFFAOYSA-N 0.000 abstract 2
- 239000003463 adsorbent Substances 0.000 abstract 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 1
- 230000001174 ascending effect Effects 0.000 abstract 1
- 230000003197 catalytic effect Effects 0.000 abstract 1
- 238000003795 desorption Methods 0.000 abstract 1
- 239000011261 inert gas Substances 0.000 abstract 1
- 229910052742 iron Inorganic materials 0.000 abstract 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 abstract 1
- 229910052759 nickel Inorganic materials 0.000 abstract 1
- 230000001737 promoting effect Effects 0.000 abstract 1
- 238000004064 recycling Methods 0.000 abstract 1
- 238000010992 reflux Methods 0.000 abstract 1
- 239000000377 silicon dioxide Substances 0.000 abstract 1
- 238000001179 sorption measurement Methods 0.000 abstract 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 abstract 1
- 229910052721 tungsten Inorganic materials 0.000 abstract 1
- 239000010937 tungsten Substances 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D59/00—Separation of different isotopes of the same chemical element
- B01D59/22—Separation by extracting
- B01D59/26—Separation by extracting by sorption, i.e. absorption, adsorption, persorption
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D59/00—Separation of different isotopes of the same chemical element
- B01D59/28—Separation by chemical exchange
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B4/00—Hydrogen isotopes; Inorganic compounds thereof prepared by isotope exchange, e.g. NH3 + D2 → NH2D + HD
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Inorganic Chemistry (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Catalysts (AREA)
Abstract
<PICT:1008475/C1/1> A deuterium - enriched hydrogen fraction is produced from elementary hydrogen by subjecting the latter at temperatures below - 100 DEG C. to the reaction 2HD = H2+D2 by contact with a composition capable of both catalytically promoting the isotope exchange reaction and preferentially adsorbing either deuterium or hydrogen at the reaction temperature. The adsorbed fraction may be recovered by desorption. By continuously recycling one fraction pure D2 may be recovered. Suitable adsorbing catalysts include metallic iron, nickel or tungsten of surface area at least 1 m2/gm., prepared by reduction of the corresponding oxide; silica or alumina may be used in addition to the catalytic adsorbent. Vertical adorption column 1 has catalyst inlet 2 and outlet 6, feed-gas inlet 3 and overhead gas outlet 4, desorbed gas outlet 5. In an example a Co-conversion catalyst consisting of 96% Fe2O3, 4% Cr2O3 was reduced with dry H2, cooled in an inert gas (He, A) to - 150 DEG C. and introduced into section A of column 1 together with hydrogen containing 0.015% deuterium. Adsorption, rectifying and stripping sections A, B, C were maintained at - 195 DEG , - 195 DEG , - 150 DEG C. respectively. The reflux ratio of the ascending gas was such as to produce 0.15% deuterium in the bottom product. (This may be fed into other columns for further enrichment.)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IL1768762 | 1962-07-22 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1008475A true GB1008475A (en) | 1965-10-27 |
Family
ID=11043225
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB2407563A Expired GB1008475A (en) | 1962-07-22 | 1963-06-17 | Production of hydrogen fractions enriched in deuterium |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB1008475A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3505017A (en) * | 1966-08-09 | 1970-04-07 | Commissariat Energie Atomique | Process for removing protium and tritium from heavy water |
| RU2148426C1 (en) * | 1998-04-21 | 2000-05-10 | Петербургский институт ядерной физики им. Б.П. Константинова РАН | Hydrogen isotope separation method |
| EP3441129A1 (en) * | 2017-08-09 | 2019-02-13 | Karlsruher Institut für Technologie | Method and device for enriching or depleting at least one hydrogen isotope in a gas stream |
| CN114737180A (en) * | 2022-04-21 | 2022-07-12 | 苏州金宏气体股份有限公司 | Treatment process for high-purity deuterium gas storage steel cylinder |
-
1963
- 1963-06-17 GB GB2407563A patent/GB1008475A/en not_active Expired
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3505017A (en) * | 1966-08-09 | 1970-04-07 | Commissariat Energie Atomique | Process for removing protium and tritium from heavy water |
| RU2148426C1 (en) * | 1998-04-21 | 2000-05-10 | Петербургский институт ядерной физики им. Б.П. Константинова РАН | Hydrogen isotope separation method |
| EP3441129A1 (en) * | 2017-08-09 | 2019-02-13 | Karlsruher Institut für Technologie | Method and device for enriching or depleting at least one hydrogen isotope in a gas stream |
| CN114737180A (en) * | 2022-04-21 | 2022-07-12 | 苏州金宏气体股份有限公司 | Treatment process for high-purity deuterium gas storage steel cylinder |
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