GB1008115A - Improvements in or relating to peroxide initiator compositions - Google Patents
Improvements in or relating to peroxide initiator compositionsInfo
- Publication number
- GB1008115A GB1008115A GB28991/63A GB2899163A GB1008115A GB 1008115 A GB1008115 A GB 1008115A GB 28991/63 A GB28991/63 A GB 28991/63A GB 2899163 A GB2899163 A GB 2899163A GB 1008115 A GB1008115 A GB 1008115A
- Authority
- GB
- United Kingdom
- Prior art keywords
- life
- hour half
- peroxide
- type
- relating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003999 initiator Substances 0.000 title abstract 3
- 239000000203 mixture Substances 0.000 title abstract 3
- 150000002978 peroxides Chemical class 0.000 title abstract 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 1
- 239000005977 Ethylene Substances 0.000 abstract 1
- YIVJZNGAASQVEM-UHFFFAOYSA-N Lauroyl peroxide Chemical compound CCCCCCCCCCCC(=O)OOC(=O)CCCCCCCCCCC YIVJZNGAASQVEM-UHFFFAOYSA-N 0.000 abstract 1
- RHZIVIGKRFVETQ-UHFFFAOYSA-N butyl 2-methylpropaneperoxoate Chemical group CCCCOOC(=O)C(C)C RHZIVIGKRFVETQ-UHFFFAOYSA-N 0.000 abstract 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerization Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Ethylene is polymerized, e.g. at 15000 to 60000 p.s.i., with a peroxide initiator composition comprising at least 3 peroxides selected from at least two of the following three types: Type 1, having a 10-hour half-life at 110 DEG to 175 DEG F.; Type II, having a 10-hour half-life at 175 DEG to 250 DEG F.; and Type III, having a 10-hour half-life at 250 DEG to 320 DEG F. In examples the initiator composition comprises lauroyl peroxide and/or tertiary butyl peroxyisobutyrate, tertiary butyl peracetate and ditertiary butyl peroxide. Comonomers and/or chain transfer agents may be present and a continuous flow tubular reactor may be used. Specification 471,590 is referred to.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US21135562A | 1962-07-20 | 1962-07-20 | |
| BE640899 | 1963-12-06 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1008115A true GB1008115A (en) | 1965-10-27 |
Family
ID=25655602
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB28991/63A Expired GB1008115A (en) | 1962-07-20 | 1963-07-22 | Improvements in or relating to peroxide initiator compositions |
Country Status (5)
| Country | Link |
|---|---|
| BE (1) | BE640899A (en) |
| DE (1) | DE1520655B1 (en) |
| FR (1) | FR1383259A (en) |
| GB (1) | GB1008115A (en) |
| NL (1) | NL292959A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1948005A1 (en) * | 1969-09-23 | 1971-04-08 | Basf Ag | Process for the production of homo- or copolymers of ethylene |
| DE2643882A1 (en) * | 1975-10-01 | 1977-04-14 | Princeton Polymer Lab | POLYAETHYLENE WAXES |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB870043A (en) * | 1959-04-20 | 1961-06-07 | Union Carbide Corp | Improvements in and relating to polymerisation |
-
0
- NL NL292959D patent/NL292959A/xx unknown
-
1963
- 1963-05-24 DE DE19631520655D patent/DE1520655B1/en active Pending
- 1963-07-22 GB GB28991/63A patent/GB1008115A/en not_active Expired
- 1963-12-06 BE BE640899D patent/BE640899A/xx unknown
- 1963-12-06 FR FR956414A patent/FR1383259A/en not_active Expired
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1948005A1 (en) * | 1969-09-23 | 1971-04-08 | Basf Ag | Process for the production of homo- or copolymers of ethylene |
| US3714135A (en) * | 1969-09-23 | 1973-01-30 | Basf Ag | Production of homopolymers or copolymers of ethylene |
| DE2643882A1 (en) * | 1975-10-01 | 1977-04-14 | Princeton Polymer Lab | POLYAETHYLENE WAXES |
Also Published As
| Publication number | Publication date |
|---|---|
| FR1383259A (en) | 1964-12-24 |
| BE640899A (en) | 1964-04-01 |
| NL292959A (en) | |
| DE1520655B1 (en) | 1970-02-12 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| GB967334A (en) | ||
| FR1365581A (en) | Vulcanizable elastomeric copolymers of tetrafluoroethylene with other vinyl compounds | |
| ES2137275T3 (en) | GRAPED PROPYLENE COPOLYMERS. | |
| ES289253A1 (en) | PROCEDURE FOR PREPARATION OF GRAFTED MIXTURES | |
| GB1030001A (en) | Copolymers and their use in compositions | |
| GB620693A (en) | Improvements in and relating to methyl vinyl polysiloxane-methyl methacrylate copolymers | |
| GB1008115A (en) | Improvements in or relating to peroxide initiator compositions | |
| GB1014852A (en) | Improvements in or relating to linking and stacking units | |
| GB1039764A (en) | Coplymerisation processes | |
| ES2051993T3 (en) | THE USE OF AZOL ACCELERATORS IN ANAEROBIC COMPOSITIONS. | |
| JPS54129049A (en) | Composition for vulcanizing fluorine-containing elastomer | |
| GB973544A (en) | Polymeric composition | |
| GB1108375A (en) | Improvements in or relating to the manufacture of 2,6-dichloro-4-nitroaniline | |
| GB1021121A (en) | Polymerization of n-vinyl lactams | |
| GB932231A (en) | Polymerisation of ethylene | |
| IT1188642B (en) | POLYMERIZATION, WITH FREE RADICAL INITIATOR, OF POLYMERIZABLE ETHYLENE UNSATURATED MONOMER COMPONENT, IN THE PRESENCE OF HYDROGEN PEROXIDE | |
| GB942969A (en) | Resinous composition | |
| GB1000330A (en) | Copolymers | |
| FR1330387A (en) | Copolymers of vinylidene fluoride, fluorinated vinyl ethers and fluorinated ethylene derivatives | |
| GB1041878A (en) | Copolymer of ethylene with styrene and process for its production | |
| FR1317141A (en) | Process for the copolymerization of ethylene and alpha-olefins with fluorinated unsaturated monomers | |
| GB1026765A (en) | Ultraviolet-resistant terpolymer | |
| GB932134A (en) | Vinyl chloride, vinyl acetate copolymers | |
| CA627741A (en) | Polymerization of butadiene-1,3 | |
| GB781783A (en) | Improvements in or relating to the polymerisation of vinyl compounds |