GB1094489A - Urethane polymers and process for making same - Google Patents
Urethane polymers and process for making sameInfo
- Publication number
- GB1094489A GB1094489A GB53236/65A GB5323665A GB1094489A GB 1094489 A GB1094489 A GB 1094489A GB 53236/65 A GB53236/65 A GB 53236/65A GB 5323665 A GB5323665 A GB 5323665A GB 1094489 A GB1094489 A GB 1094489A
- Authority
- GB
- United Kingdom
- Prior art keywords
- phosphate
- amount
- phosphorus compound
- acid
- making same
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 title 1
- 229920000642 polymer Polymers 0.000 title 1
- -1 phosphorus compound Chemical class 0.000 abstract 3
- 239000002253 acid Substances 0.000 abstract 2
- 229910052698 phosphorus Inorganic materials 0.000 abstract 2
- 239000011574 phosphorus Substances 0.000 abstract 2
- 229920005862 polyol Polymers 0.000 abstract 2
- 150000003077 polyols Chemical class 0.000 abstract 2
- 229910019142 PO4 Inorganic materials 0.000 abstract 1
- 239000004721 Polyphenylene oxide Substances 0.000 abstract 1
- 230000001413 cellular effect Effects 0.000 abstract 1
- 239000007795 chemical reaction product Substances 0.000 abstract 1
- VONWDASPFIQPDY-UHFFFAOYSA-N dimethyl methylphosphonate Chemical compound COP(C)(=O)OC VONWDASPFIQPDY-UHFFFAOYSA-N 0.000 abstract 1
- 239000003063 flame retardant Substances 0.000 abstract 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 abstract 1
- 239000010452 phosphate Substances 0.000 abstract 1
- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 abstract 1
- 229920000728 polyester Polymers 0.000 abstract 1
- 229920000570 polyether Polymers 0.000 abstract 1
- 229920001228 polyisocyanate Polymers 0.000 abstract 1
- 239000005056 polyisocyanate Substances 0.000 abstract 1
- 239000004814 polyurethane Substances 0.000 abstract 1
- 229920002635 polyurethane Polymers 0.000 abstract 1
- DQWPFSLDHJDLRL-UHFFFAOYSA-N triethyl phosphate Chemical compound CCOP(=O)(OCC)OCC DQWPFSLDHJDLRL-UHFFFAOYSA-N 0.000 abstract 1
- WVLBCYQITXONBZ-UHFFFAOYSA-N trimethyl phosphate Chemical compound COP(=O)(OC)OC WVLBCYQITXONBZ-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0014—Use of organic additives
- C08J9/0038—Use of organic additives containing phosphorus
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/38—Low-molecular-weight compounds having heteroatoms other than oxygen
- C08G18/3878—Low-molecular-weight compounds having heteroatoms other than oxygen having phosphorus
- C08G18/3882—Low-molecular-weight compounds having heteroatoms other than oxygen having phosphorus having phosphorus bound to oxygen only
- C08G18/3885—Phosphate compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/50—Polyethers having heteroatoms other than oxygen
- C08G18/5075—Polyethers having heteroatoms other than oxygen having phosphorus
- C08G18/5081—Polyethers having heteroatoms other than oxygen having phosphorus having phosphorus bound to oxygen only
- C08G18/5084—Phosphate compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/53—Phosphorus bound to oxygen bound to oxygen and to carbon only
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
- C08J2375/04—Polyurethanes
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Polyurethanes Or Polyureas (AREA)
Abstract
A cellular fire-retardant polyurethane is the reaction product of an organic polyisocyanate with a polyester and/or polyether polyol and, (1) a first phosphorus compound containing at least two active hydrogen atoms per molecule and being present in an amount of at least 5% by wt. of the polyol together with (2) a second phosphorus compound which is at least one trialkyl phosphate or phosphonate in an amount of from 10-90% by wt. of the total of (1) and (2). (1) may be an alkoxylated dialkylpyrophosphoric acid, e.g. propoxylated dibutylpyrophosphoric acid. Examples of (2) trimethyl phosphate, triethyl phosphate, dimethyl methylphosphonate and diethyl ethylphosphate.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB53236/65A GB1094489A (en) | 1959-04-20 | 1965-12-15 | Urethane polymers and process for making same |
| DE19651569428D DE1569428B1 (en) | 1959-04-20 | 1965-12-18 | Process for the production of flame-retardant, foamed polyurethanes |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US807328A US3525705A (en) | 1959-04-20 | 1959-04-20 | Flame-resistant polyurethanes prepared from certain phorphorus compounds |
| GB53236/65A GB1094489A (en) | 1959-04-20 | 1965-12-15 | Urethane polymers and process for making same |
| DES0101032 | 1965-12-18 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1094489A true GB1094489A (en) | 1967-12-13 |
Family
ID=7523461
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB53236/65A Expired GB1094489A (en) | 1959-04-20 | 1965-12-15 | Urethane polymers and process for making same |
Country Status (2)
| Country | Link |
|---|---|
| DE (1) | DE1569428B1 (en) |
| GB (1) | GB1094489A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1061095A1 (en) * | 1999-06-16 | 2000-12-20 | Clariant GmbH | Process for producing flame retardant soft polyurethane foams |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0108713B1 (en) * | 1982-10-12 | 1986-11-20 | Ciba-Geigy Ag | Fire-retarding compositions |
| WO2001068758A1 (en) * | 2000-03-17 | 2001-09-20 | Shell Internationale Research Maatschappij B.V. | Formulation for making polyurethane foams |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL126032C (en) * | 1959-08-11 |
-
1965
- 1965-12-15 GB GB53236/65A patent/GB1094489A/en not_active Expired
- 1965-12-18 DE DE19651569428D patent/DE1569428B1/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1061095A1 (en) * | 1999-06-16 | 2000-12-20 | Clariant GmbH | Process for producing flame retardant soft polyurethane foams |
| US6380273B1 (en) | 1999-06-16 | 2002-04-30 | Clariant Gmbh | Process for producing flame-retardant flexible polyurethane foams |
Also Published As
| Publication number | Publication date |
|---|---|
| DE1569428B1 (en) | 1970-02-12 |
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