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GB1094215A - Derivatives of cyano-phenyl esters of phosphorus acids - Google Patents

Derivatives of cyano-phenyl esters of phosphorus acids

Info

Publication number
GB1094215A
GB1094215A GB4756664A GB4756664A GB1094215A GB 1094215 A GB1094215 A GB 1094215A GB 4756664 A GB4756664 A GB 4756664A GB 4756664 A GB4756664 A GB 4756664A GB 1094215 A GB1094215 A GB 1094215A
Authority
GB
United Kingdom
Prior art keywords
alkyl
compound
formula
compounds
phenyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB4756664A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Stauffer Chemical Co
Original Assignee
Stauffer Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Stauffer Chemical Co filed Critical Stauffer Chemical Co
Publication of GB1094215A publication Critical patent/GB1094215A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
    • C07F9/44—Amides thereof
    • C07F9/4434—Amides thereof the ester moiety containing a substituent or a structure which is considered as characteristic
    • C07F9/4449—Esters with hydroxyaryl compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/06—Phosphorus compounds without P—C bonds
    • C07F9/08—Esters of oxyacids of phosphorus
    • C07F9/09—Esters of phosphoric acids
    • C07F9/12—Esters of phosphoric acids with hydroxyaryl compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/06—Phosphorus compounds without P—C bonds
    • C07F9/16—Esters of thiophosphoric acids or thiophosphorous acids
    • C07F9/165—Esters of thiophosphoric acids
    • C07F9/18—Esters of thiophosphoric acids with hydroxyaryl compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/06—Phosphorus compounds without P—C bonds
    • C07F9/22—Amides of acids of phosphorus
    • C07F9/24—Esteramides
    • C07F9/2404—Esteramides the ester moiety containing a substituent or a structure which is considered as characteristic
    • C07F9/242—Esteramides the ester moiety containing a substituent or a structure which is considered as characteristic of hydroxyaryl compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/30—Phosphinic acids [R2P(=O)(OH)]; Thiophosphinic acids ; [R2P(=X1)(X2H) (X1, X2 are each independently O, S or Se)]
    • C07F9/32—Esters thereof
    • C07F9/3258—Esters thereof the ester moiety containing a substituent or a structure which is considered as characteristic
    • C07F9/3282—Esters with hydroxyaryl compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
    • C07F9/40—Esters thereof
    • C07F9/4071—Esters thereof the ester moiety containing a substituent or a structure which is considered as characteristic
    • C07F9/4084—Esters with hydroxyaryl compounds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention comprises compounds of the formula <FORM:1094215/C2/1> in which the CN is in the m- or p-position to the phosphorus containing group and in which R and R1, which may be the same or different, represent C1-C8 alkyl, chloro-substituted C1-C8 alkyl, C1-C8 alkoxy, phenyl or C1-C4 di-alkylamino groups and X represents O or S. They may be obtained by reacting a compound of the formula <FORM:1094215/C2/2> in which Hal is a halogen atom, with a compound of the formula <FORM:1094215/C2/3> in the presence of a hydrogen halide acceptor, such as a tertiary amine and an organic solvent, at a temperature between 0 DEG and 100 DEG C. Examples are given for the preparation of the compounds. The products are useful as pesticides (see Division A5). Reference has been directed by the Comptroller to Specification 1,033,265.ALSO:A compound or a mixture of compounds of the formula: <FORM:1094215/A5-A6/1> in which the CN is in m- or p-positions to the phosphorus containing group and in which R and R1, which may be the same or different, represent C1-C8 alkyl, chloro-substituted C1-C8 alkyl, C1-C8 alkoxy, phenyl or C1-4 dialkylamino groups, and X represents O or S (see Division C2); is used alone or in the form of an aqueous dispersion, aqueous or non-aqueous solutions, wettable powders, vapours, and dusts to combat pests. An example is given in which the compound is used in the form of an acetone solution which is suspended in water containing an emulsifying agent. Reference has been directed by the Comptroller to Specification 1,033,265.
GB4756664A 1963-12-06 1964-11-23 Derivatives of cyano-phenyl esters of phosphorus acids Expired GB1094215A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US32846363A 1963-12-06 1963-12-06

Publications (1)

Publication Number Publication Date
GB1094215A true GB1094215A (en) 1967-12-06

Family

ID=23281089

Family Applications (1)

Application Number Title Priority Date Filing Date
GB4756664A Expired GB1094215A (en) 1963-12-06 1964-11-23 Derivatives of cyano-phenyl esters of phosphorus acids

Country Status (5)

Country Link
BE (1) BE656673A (en)
DE (1) DE1693204A1 (en)
GB (1) GB1094215A (en)
IL (1) IL22447A (en)
NL (1) NL6414045A (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2833342A1 (en) * 1978-07-29 1980-02-14 Bayer Ag METHOD FOR PRODUCING NEUTRAL PHOSPHORIC ACID ESTERS BY THE PHASE SURFACE METHOD

Also Published As

Publication number Publication date
BE656673A (en) 1965-06-04
IL22447A (en) 1968-04-25
DE1693204A1 (en) 1971-09-30
NL6414045A (en) 1965-06-07

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