GB1093628A - Treatment of shaped articles made from synthetic linear polyesters - Google Patents
Treatment of shaped articles made from synthetic linear polyestersInfo
- Publication number
- GB1093628A GB1093628A GB7930/65A GB793065A GB1093628A GB 1093628 A GB1093628 A GB 1093628A GB 7930/65 A GB7930/65 A GB 7930/65A GB 793065 A GB793065 A GB 793065A GB 1093628 A GB1093628 A GB 1093628A
- Authority
- GB
- United Kingdom
- Prior art keywords
- filaments
- polyalkylene glycol
- polyester
- temperature
- glycol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920000728 polyester Polymers 0.000 title abstract 8
- 229920001515 polyalkylene glycol Polymers 0.000 abstract 8
- 238000010438 heat treatment Methods 0.000 abstract 6
- 239000000243 solution Substances 0.000 abstract 5
- 239000003513 alkali Substances 0.000 abstract 4
- 229910001854 alkali hydroxide Inorganic materials 0.000 abstract 4
- 229910001860 alkaline earth metal hydroxide Inorganic materials 0.000 abstract 4
- 239000007864 aqueous solution Substances 0.000 abstract 4
- 238000005507 spraying Methods 0.000 abstract 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 4
- 239000002202 Polyethylene glycol Substances 0.000 abstract 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 abstract 3
- 229920001223 polyethylene glycol Polymers 0.000 abstract 3
- 239000000853 adhesive Substances 0.000 abstract 2
- 230000001070 adhesive effect Effects 0.000 abstract 2
- 229920001451 polypropylene glycol Polymers 0.000 abstract 2
- 239000007787 solid Substances 0.000 abstract 2
- 229920002125 Sokalan® Polymers 0.000 abstract 1
- 125000005456 glyceride group Chemical group 0.000 abstract 1
- 239000004584 polyacrylic acid Substances 0.000 abstract 1
- 230000007704 transition Effects 0.000 abstract 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/53—Polyethers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/38—Oxides or hydroxides of elements of Groups 1 or 11 of the Periodic Table
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/44—Oxides or hydroxides of elements of Groups 2 or 12 of the Periodic Table; Zincates; Cadmates
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Lining Or Joining Of Plastics Or The Like (AREA)
- Treatments Of Macromolecular Shaped Articles (AREA)
- Laminated Bodies (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Polyesters Or Polycarbonates (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Filaments made from a normally solid synthetic linear polyester are rendered antistatic by treating them with a polyalkylene glycol having a molecular weight above 200, then treating them with an aqueous solution of an alkali or alkaline earth metal hydroxide and then heating them to a temperature of 100 DEG C or higher but below the softening point of the polyester for a period of time sufficient to remove the water present. The polyalkylene glycol which may be a polyethylene glycol or polypropylene glycol may be applied to the filaments in concentrated form or as a 10-50% by weight aqueous solution by padding, spraying or by means of an applicator roll so that 0.1-2% by weight of the polyalkylene glycol is applied to the filaments. The polyalkylene glycol may be applied to the filaments prior to or after stretching. The concentration of the alkali or alkaline earth metal hydroxide solution may be 0.01 - 25% by weight and application may be effected by padding, spraying or by means of an applicator roll preferably at room temperature or below. In the case of unstretched polyester filaments the temperature of the hydroxide solution should not exceed the second order transition temperature although after stretching temperatures up to 100 DEG C may be used. After the application of the polyalkylene glycol and hydroxide solution the filaments may be heated at a temperature of 100 DEG C or higher but below the softening point of the polyester by means of a hot plate, hot roll, heating tube or radiant heating for from a fraction of a second up to 5 minutes until the water present has been removed. The treated filaments possess improved bonding by adhesives and sizes, e.g. polyacrylic acid. A polyethenoxylated glyceride may be applied together with the polyalkylene glycol.ALSO:Films made from a normally solid synthetic linear polyester are rendered antistatic by treating them with a polyalkylene glycol having a molecular weight above 200, then treating them with an aqueous solution of an alkali or alkaline earth metal hydroxide and then heating them to a temperature of 100 DEG C or higher but below the softening point of the polyester for a period of time sufficient to remove the water present. The polyalkylene glycol which may be a polyethylene glycol or polypropylene glycol may be applied to the films in concentrated form or as a 10 - 50% by weight aqueous solution by spraying or by means of an applicator roll. The concentration of the alkali or alkaline earth metal hydroxide solution may be 0.01 - 25% by weight and application may be effected by spraying or by means of an applicator roll preferably at room temperature or below. After the application of the polyethylene glycol and hydroxide solution the films may be heated at a temperature of 100 DEG C or higher but below the softening point of the polyester by means of a hot plate, hot roll, heating tube or radiant heating for from a fraction of a second up to 5 minutes until the water present has been removed. The treated films possess improved bonding by adhesives and sizes.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US347107A US3400187A (en) | 1964-02-25 | 1964-02-25 | Method of treating polyester structures with polyalkylene glycol and a metal hyderoxide |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1093628A true GB1093628A (en) | 1967-12-06 |
Family
ID=23362350
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB7930/65A Expired GB1093628A (en) | 1964-02-25 | 1965-02-24 | Treatment of shaped articles made from synthetic linear polyesters |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US3400187A (en) |
| AT (1) | AT267040B (en) |
| BE (1) | BE660123A (en) |
| ES (1) | ES309784A1 (en) |
| FR (1) | FR1425169A (en) |
| GB (1) | GB1093628A (en) |
| NL (1) | NL6502428A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5069847A (en) * | 1988-07-28 | 1991-12-03 | E. I. Du Pont De Nemours And Company | Improvements in process for preparing spun yarns |
| US5069844A (en) * | 1988-07-28 | 1991-12-03 | E. I. Du Pont De Nemours And Company | Improvements in process for preparing crystalline spin-oriented filaments |
| US5069846A (en) * | 1988-07-28 | 1991-12-03 | E. I. Du Pont De Nemours And Company | Process for preparing drawn filament yarns |
| US5069845A (en) * | 1988-07-28 | 1991-12-03 | E. I. Du Pont De Nemours And Company | Improvements in process for preparing spin-oriented feed yarns |
| US5088140A (en) * | 1988-07-28 | 1992-02-18 | E. I. Du Pont De Nemours And Company | Pillows of polyester fiberfill |
| US5145622A (en) * | 1986-11-21 | 1992-09-08 | E. I. Du Pont De Nemours And Company | Improvements in process for preparing water-dispersible polyester fiber |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3518067A (en) * | 1965-08-20 | 1970-06-30 | Union Carbide Corp | Method of plating polyarylene polyethers,polycarbonate or polyhydroxyethers and the resulting articles |
| US3544357A (en) * | 1966-05-27 | 1970-12-01 | Kuraray Co | Method of manufacturing soft and flexible sheet materials |
| US3928682A (en) * | 1971-10-27 | 1975-12-23 | Martin Processing Co Inc | Method for the surface treatment of polyester materials |
| US4054634A (en) * | 1975-09-29 | 1977-10-18 | Allied Chemical Corporation | Production of polyester tire yarn |
| DE3069270D1 (en) * | 1979-06-11 | 1984-10-31 | Teijin Ltd | Synthetic polyester pulp and process for preparing same |
| US4420514A (en) * | 1981-04-17 | 1983-12-13 | Mobil Oil Corporation | Polymer film treatment with organic impregnant |
| US4391939A (en) * | 1981-04-17 | 1983-07-05 | Mobil Oil Corporation | Polymer film treatment with organic impregnant |
| US4808188A (en) * | 1987-09-16 | 1989-02-28 | Ledford W Troy | Polyester fibers, yarns and fabrics with enhanced hydrophilicity and method of producing same with borohydride anions and lithium cations |
| US4803256A (en) * | 1988-02-01 | 1989-02-07 | Dow Corning Corporation | Method of altering the surface of a solid synthetic polymer |
| US5486210A (en) * | 1992-01-30 | 1996-01-23 | Reeves Brothers, Inc. | Air bag fabric containing graft polymer thereon |
| US5407728A (en) * | 1992-01-30 | 1995-04-18 | Reeves Brothers, Inc. | Fabric containing graft polymer thereon |
| US5958987A (en) | 1996-04-10 | 1999-09-28 | The Coca-Cola Company | Process for separating polyester from other materials |
| USH1987H1 (en) | 1998-04-23 | 2001-08-07 | Eastman Chemical Company | Non-volatile plasticizers and flow aids for polyesters |
| US7070624B2 (en) * | 2001-06-19 | 2006-07-04 | United Resource Recovery Corporation | Process for separating polyester from other materials |
| US7098299B1 (en) * | 2005-03-16 | 2006-08-29 | United Resource Recovery Corporation | Separation of contaminants from polyester materials |
| CN105431470B (en) * | 2013-06-27 | 2018-05-18 | 瑞来斯实业公司 | Hydrophilic polyester fibers |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1012583B (en) * | 1953-02-09 | 1957-07-25 | Raduner & Co Ag | Process for increasing the dyeability of threads, fibers or products made therefrom made of polyacrylonitrile or copolymers containing this |
| NL212981A (en) * | 1956-12-14 | |||
| US2955954A (en) * | 1959-02-09 | 1960-10-11 | Du Pont | Process for treating shaped articles prepared from synthetic linear polyesters |
| US2938811A (en) * | 1959-11-09 | 1960-05-31 | Martin Proc Company Inc | Method of conditioning polyester textile material and the resulting products |
| NL259354A (en) * | 1959-12-22 | |||
| NL263785A (en) * | 1960-04-28 | |||
| US3110617A (en) * | 1960-05-20 | 1963-11-12 | Du Pont | Textile |
| BE604582A (en) * | 1960-06-03 | 1900-01-01 |
-
1964
- 1964-02-25 US US347107A patent/US3400187A/en not_active Expired - Lifetime
-
1965
- 1965-02-23 BE BE660123D patent/BE660123A/xx unknown
- 1965-02-23 FR FR6732A patent/FR1425169A/en not_active Expired
- 1965-02-24 ES ES0309784A patent/ES309784A1/en not_active Expired
- 1965-02-24 GB GB7930/65A patent/GB1093628A/en not_active Expired
- 1965-02-25 NL NL6502428A patent/NL6502428A/xx unknown
- 1965-02-25 AT AT167965A patent/AT267040B/en active
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5145622A (en) * | 1986-11-21 | 1992-09-08 | E. I. Du Pont De Nemours And Company | Improvements in process for preparing water-dispersible polyester fiber |
| US5069847A (en) * | 1988-07-28 | 1991-12-03 | E. I. Du Pont De Nemours And Company | Improvements in process for preparing spun yarns |
| US5069844A (en) * | 1988-07-28 | 1991-12-03 | E. I. Du Pont De Nemours And Company | Improvements in process for preparing crystalline spin-oriented filaments |
| US5069846A (en) * | 1988-07-28 | 1991-12-03 | E. I. Du Pont De Nemours And Company | Process for preparing drawn filament yarns |
| US5069845A (en) * | 1988-07-28 | 1991-12-03 | E. I. Du Pont De Nemours And Company | Improvements in process for preparing spin-oriented feed yarns |
| US5088140A (en) * | 1988-07-28 | 1992-02-18 | E. I. Du Pont De Nemours And Company | Pillows of polyester fiberfill |
Also Published As
| Publication number | Publication date |
|---|---|
| BE660123A (en) | 1965-08-23 |
| ES309784A1 (en) | 1965-06-01 |
| NL6502428A (en) | 1965-08-26 |
| AT267040B (en) | 1968-12-10 |
| FR1425169A (en) | 1966-01-14 |
| US3400187A (en) | 1968-09-03 |
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