GB1092225A - Improvements in or relating to the extrusion of chemically crossed linked polymer or copolymers - Google Patents
Improvements in or relating to the extrusion of chemically crossed linked polymer or copolymersInfo
- Publication number
- GB1092225A GB1092225A GB47662/65A GB4766265A GB1092225A GB 1092225 A GB1092225 A GB 1092225A GB 47662/65 A GB47662/65 A GB 47662/65A GB 4766265 A GB4766265 A GB 4766265A GB 1092225 A GB1092225 A GB 1092225A
- Authority
- GB
- United Kingdom
- Prior art keywords
- curing agent
- butyl
- polymer
- further curing
- curing agents
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920000642 polymer Polymers 0.000 title abstract 3
- 238000001125 extrusion Methods 0.000 title abstract 2
- 229920001577 copolymer Polymers 0.000 title 1
- 239000003795 chemical substances by application Substances 0.000 abstract 10
- -1 polyethylene Polymers 0.000 abstract 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 2
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 abstract 2
- 238000010438 heat treatment Methods 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- LLZHXQRNOOAOFF-UHFFFAOYSA-N 1,3-dihydrobenzimidazole-2-thione;zinc Chemical compound [Zn].C1=CC=C2NC(S)=NC2=C1 LLZHXQRNOOAOFF-UHFFFAOYSA-N 0.000 abstract 1
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 abstract 1
- PMAAOHONJPSASX-UHFFFAOYSA-N 2-butylperoxypropan-2-ylbenzene Chemical compound CCCCOOC(C)(C)C1=CC=CC=C1 PMAAOHONJPSASX-UHFFFAOYSA-N 0.000 abstract 1
- 125000000242 4-chlorobenzoyl group Chemical group ClC1=CC=C(C(=O)*)C=C1 0.000 abstract 1
- 239000004698 Polyethylene Substances 0.000 abstract 1
- 239000003963 antioxidant agent Substances 0.000 abstract 1
- 235000006708 antioxidants Nutrition 0.000 abstract 1
- 125000003236 benzoyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C(*)=O 0.000 abstract 1
- 239000001273 butane Substances 0.000 abstract 1
- UPIWXMRIPODGLE-UHFFFAOYSA-N butyl benzenecarboperoxoate Chemical compound CCCCOOC(=O)C1=CC=CC=C1 UPIWXMRIPODGLE-UHFFFAOYSA-N 0.000 abstract 1
- 239000006229 carbon black Substances 0.000 abstract 1
- 229920006037 cross link polymer Polymers 0.000 abstract 1
- 238000004132 cross linking Methods 0.000 abstract 1
- 238000000354 decomposition reaction Methods 0.000 abstract 1
- 239000000945 filler Substances 0.000 abstract 1
- 125000000400 lauroyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 238000002156 mixing Methods 0.000 abstract 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 abstract 1
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 abstract 1
- SRSFOMHQIATOFV-UHFFFAOYSA-N octanoyl octaneperoxoate Chemical class CCCCCCCC(=O)OOC(=O)CCCCCCC SRSFOMHQIATOFV-UHFFFAOYSA-N 0.000 abstract 1
- 229920000573 polyethylene Polymers 0.000 abstract 1
- 229920000098 polyolefin Polymers 0.000 abstract 1
- 239000000377 silicon dioxide Substances 0.000 abstract 1
- BOXSVZNGTQTENJ-UHFFFAOYSA-L zinc dibutyldithiocarbamate Chemical compound [Zn+2].CCCCN(C([S-])=S)CCCC.CCCCN(C([S-])=S)CCCC BOXSVZNGTQTENJ-UHFFFAOYSA-L 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/24—Crosslinking, e.g. vulcanising, of macromolecules
- C08J3/243—Two or more independent types of crosslinking for one or more polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/022—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the choice of material
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/14—Peroxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
- B29C48/05—Filamentary, e.g. strands
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2101/00—Use of unspecified macromolecular compounds as moulding material
- B29K2101/10—Thermosetting resins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2301/00—Use of unspecified macromolecular compounds as reinforcement
- B29K2301/10—Thermosetting resins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Organic Insulating Materials (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
Abstract
A process for producing cross-linked olefin polymer extrudates comprises blending the polymer with a predetermined mixture of a minor proportion of a curing agent and a major proportion of a further curing agent, said curing agents decomposing at different temperatures, heating the blend at least to a temperature at which the curing agent present in minor proportion will decompose quickly but below that at which the further curing agent will decompose such that a controlled proportion of cross-linking occurs either prior to or during extrusion, extruding the partially cross-linked polymer at a temperature below that at which the further curing agent decomposes and heating the extrudate to the decomposition temperature of the further curing agent. The preferred polymer is polyethylene. Many suitable curing agents are listed including lauroyl, benzoyl, p-chlorobenzoyl, 2,4-dichlorobenzoyl and octanoyl peroxides as minor curing agents, and t. butyl perbenzoate, t. butyl peracetate, di-t. butyl diperphthalate, dicumyl peroxide, 2,2-bis (t. butylperoxy) butane and t. butyl cumyl peroxide as further curing agents. Fillers, e.g. silica and carbon black, and anti-oxidants, e.g. zinc mercaptobenzimidazole, 2,2,4 - trimethyl - 2 - dihydroquinoline and nickel dibutyl dithiocarbamate, may be present and the products may be used for insulating high-voltage cables.
Priority Applications (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB47662/65A GB1092225A (en) | 1965-11-10 | 1965-11-10 | Improvements in or relating to the extrusion of chemically crossed linked polymer or copolymers |
| ES0333120A ES333120A1 (en) | 1965-11-10 | 1966-11-05 | Improvements in or referring to the extrusion of polymers or copolymers quimically entrelazados. (Machine-translation by Google Translate, not legally binding) |
| FR83278A FR1499714A (en) | 1965-11-10 | 1966-11-10 | Advanced process for extruding crosslinked polymers |
| BE689539D BE689539A (en) | 1965-11-10 | 1966-11-10 | |
| NL6615853A NL6615853A (en) | 1965-11-10 | 1966-11-10 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB47662/65A GB1092225A (en) | 1965-11-10 | 1965-11-10 | Improvements in or relating to the extrusion of chemically crossed linked polymer or copolymers |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1092225A true GB1092225A (en) | 1967-11-22 |
Family
ID=10445819
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB47662/65A Expired GB1092225A (en) | 1965-11-10 | 1965-11-10 | Improvements in or relating to the extrusion of chemically crossed linked polymer or copolymers |
Country Status (5)
| Country | Link |
|---|---|
| BE (1) | BE689539A (en) |
| ES (1) | ES333120A1 (en) |
| FR (1) | FR1499714A (en) |
| GB (1) | GB1092225A (en) |
| NL (1) | NL6615853A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4202790A (en) | 1978-06-26 | 1980-05-13 | Hercules Incorporated | Peroxide blends |
| US7214724B2 (en) | 2001-12-17 | 2007-05-08 | Henkel Kommanditgesellschaft Auf Aktien | Method for cross-linking a foamable plastic |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA1047200A (en) * | 1974-11-27 | 1979-01-23 | Donald L. Schober | Compositions with peroxides and process for avoiding scorching of ethylene polymer composition |
| FR2416106A1 (en) * | 1978-02-02 | 1979-08-31 | Silec Liaisons Elec | METHOD AND DEVICE FOR EXTRUSION OF A CROSS-LINKED PRODUCT |
-
1965
- 1965-11-10 GB GB47662/65A patent/GB1092225A/en not_active Expired
-
1966
- 1966-11-05 ES ES0333120A patent/ES333120A1/en not_active Expired
- 1966-11-10 FR FR83278A patent/FR1499714A/en not_active Expired
- 1966-11-10 BE BE689539D patent/BE689539A/nl unknown
- 1966-11-10 NL NL6615853A patent/NL6615853A/xx unknown
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4202790A (en) | 1978-06-26 | 1980-05-13 | Hercules Incorporated | Peroxide blends |
| US7214724B2 (en) | 2001-12-17 | 2007-05-08 | Henkel Kommanditgesellschaft Auf Aktien | Method for cross-linking a foamable plastic |
Also Published As
| Publication number | Publication date |
|---|---|
| ES333120A1 (en) | 1967-09-16 |
| FR1499714A (en) | 1967-10-27 |
| NL6615853A (en) | 1967-05-11 |
| BE689539A (en) | 1967-05-10 |
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