GB1078870A - Process for the production of shaped articles from vinyl chloride polymer-ethylenically unsaturated monomer compositions - Google Patents
Process for the production of shaped articles from vinyl chloride polymer-ethylenically unsaturated monomer compositionsInfo
- Publication number
- GB1078870A GB1078870A GB28234/66A GB2823466A GB1078870A GB 1078870 A GB1078870 A GB 1078870A GB 28234/66 A GB28234/66 A GB 28234/66A GB 2823466 A GB2823466 A GB 2823466A GB 1078870 A GB1078870 A GB 1078870A
- Authority
- GB
- United Kingdom
- Prior art keywords
- vinyl chloride
- tert
- methyl
- chloride polymer
- ethylenically unsaturated
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 title abstract 3
- 239000000203 mixture Substances 0.000 title abstract 3
- 239000000178 monomer Substances 0.000 title abstract 3
- 229920000642 polymer Polymers 0.000 abstract 3
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical class C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract 2
- SQNZJJAZBFDUTD-UHFFFAOYSA-N durene Chemical compound CC1=CC(C)=C(C)C=C1C SQNZJJAZBFDUTD-UHFFFAOYSA-N 0.000 abstract 2
- 239000004744 fabric Substances 0.000 abstract 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract 2
- 150000003839 salts Chemical class 0.000 abstract 2
- DMWVYCCGCQPJEA-UHFFFAOYSA-N 2,5-bis(tert-butylperoxy)-2,5-dimethylhexane Chemical compound CC(C)(C)OOC(C)(C)CCC(C)(C)OOC(C)(C)C DMWVYCCGCQPJEA-UHFFFAOYSA-N 0.000 abstract 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 abstract 1
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 abstract 1
- 229920000742 Cotton Polymers 0.000 abstract 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 abstract 1
- 229920001944 Plastisol Polymers 0.000 abstract 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 abstract 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 abstract 1
- 229920002522 Wood fibre Polymers 0.000 abstract 1
- 125000000217 alkyl group Chemical class 0.000 abstract 1
- 239000003963 antioxidant agent Substances 0.000 abstract 1
- 239000001273 butane Substances 0.000 abstract 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 abstract 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 229920001577 copolymer Polymers 0.000 abstract 1
- -1 dicumyl peroxides Chemical class 0.000 abstract 1
- POULHZVOKOAJMA-UHFFFAOYSA-M dodecanoate Chemical compound CCCCCCCCCCCC([O-])=O POULHZVOKOAJMA-UHFFFAOYSA-M 0.000 abstract 1
- GMSCBRSQMRDRCD-UHFFFAOYSA-N dodecyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCCOC(=O)C(C)=C GMSCBRSQMRDRCD-UHFFFAOYSA-N 0.000 abstract 1
- 239000000975 dye Substances 0.000 abstract 1
- 150000002148 esters Chemical class 0.000 abstract 1
- 239000011521 glass Substances 0.000 abstract 1
- 239000003365 glass fiber Substances 0.000 abstract 1
- 229920000578 graft copolymer Polymers 0.000 abstract 1
- 229910052736 halogen Chemical class 0.000 abstract 1
- 150000002367 halogens Chemical class 0.000 abstract 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-M hexanoate Chemical compound CCCCCC([O-])=O FUZZWVXGSFPDMH-UHFFFAOYSA-M 0.000 abstract 1
- 229920001519 homopolymer Polymers 0.000 abstract 1
- 239000003112 inhibitor Substances 0.000 abstract 1
- 229940070765 laurate Drugs 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 230000002794 monomerizing effect Effects 0.000 abstract 1
- 125000005609 naphthenate group Chemical group 0.000 abstract 1
- 125000005474 octanoate group Chemical group 0.000 abstract 1
- 150000007524 organic acids Chemical class 0.000 abstract 1
- 150000001451 organic peroxides Chemical class 0.000 abstract 1
- 239000002245 particle Substances 0.000 abstract 1
- 150000002978 peroxides Chemical class 0.000 abstract 1
- 239000000049 pigment Substances 0.000 abstract 1
- 239000004999 plastisol Substances 0.000 abstract 1
- 230000000379 polymerizing effect Effects 0.000 abstract 1
- 239000003381 stabilizer Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F259/00—Macromolecular compounds obtained by polymerising monomers on to polymers of halogen containing monomers as defined in group C08F14/00
- C08F259/02—Macromolecular compounds obtained by polymerising monomers on to polymers of halogen containing monomers as defined in group C08F14/00 on to polymers containing chlorine
- C08F259/04—Macromolecular compounds obtained by polymerising monomers on to polymers of halogen containing monomers as defined in group C08F14/00 on to polymers containing chlorine on to polymers of vinyl chloride
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Graft Or Block Polymers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Graft polymers are obtained by dispersing a vinyl chloride polymer in an ethylenically unsaturated monomer and polymerizing the mixture in the presence of an organic peroxide catalyst and a stannous salt of an organic acid. The vinyl chloride polymer can be a homopolymer or a copolymer containing up to 15% by weight of vinyl acetate or propionate, methyl or butyl acrylate, methyl or lauryl methacrylate or vinylidene chloride and is preferably of plastisol grade particles. The monomer may be styrene or an alkyl and/or halogen derivative or a mixture thereof with an ester of fumaric or acrylic or methacrylic acid. Specified peroxides are ditert butyl and dicumyl peroxides, 1,4-bis(tert.-butyl peroxy methyl) durene, 2,5-dimethyl - 2,5 - di - (tert.-butyl peroxy)-hexane or -hexyne-3, and 2,2-bis-(tert.-butyl peroxy)-butane and specified stannous salts are naphthenate, octoate, caproate, and laurate. Reaction is effected at 120-180 DEG C. at which temperature the polymer is solvated. Pigments, stabilizers, dyes, antioxidants and inhibitors may be present, or materials to be impregnated, e.g. cloth, wood fibres, cotton linters, glass fibres, glass cloth, or paper.
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CA808724A CA808724A (en) | 1966-06-23 | Method and catalysts for converting vinyl chloride polymer monomer compositions to polymeric products | |
| GB28234/66A GB1078870A (en) | 1966-06-23 | 1966-06-23 | Process for the production of shaped articles from vinyl chloride polymer-ethylenically unsaturated monomer compositions |
| DE19661595513 DE1595513A1 (en) | 1966-06-23 | 1966-06-28 | Process for the production of shaped articles from compositions of vinyl chloride polymer and ethylenically unsaturated monomers |
| NL6609073A NL6609073A (en) | 1966-06-23 | 1966-06-29 |
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CA808724T | |||
| GB28234/66A GB1078870A (en) | 1966-06-23 | 1966-06-23 | Process for the production of shaped articles from vinyl chloride polymer-ethylenically unsaturated monomer compositions |
| DED0050418 | 1966-06-28 | ||
| NL6609073A NL6609073A (en) | 1966-06-23 | 1966-06-29 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1078870A true GB1078870A (en) | 1967-08-09 |
Family
ID=60922785
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB28234/66A Expired GB1078870A (en) | 1966-06-23 | 1966-06-23 | Process for the production of shaped articles from vinyl chloride polymer-ethylenically unsaturated monomer compositions |
Country Status (4)
| Country | Link |
|---|---|
| CA (1) | CA808724A (en) |
| DE (1) | DE1595513A1 (en) |
| GB (1) | GB1078870A (en) |
| NL (1) | NL6609073A (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0021703A1 (en) * | 1979-06-11 | 1981-01-07 | Union Carbide Corporation | Radiation curable dispersions containing high molecular weight nonpolymerizable vinyl resins |
| FR2471988A1 (en) * | 1979-12-21 | 1981-06-26 | Dart Ind Inc | CATALYSTS AND PROCESS FOR THE PREPARATION OF POLYMERS AND COPOLYMERS OF ETHYLENICALLY UNSATURATED MONOMERS |
| WO2002059171A3 (en) * | 2001-01-26 | 2003-08-21 | Univ Pennsylvania | Living radical graft copolymerization of vinyl monomers initiated from the structural defects of polyvinylchloride |
| US6838535B2 (en) | 2001-03-23 | 2005-01-04 | University Of Pennsylvania | Process for the living radical polymerization of chlorine containing monomers |
| US7026420B2 (en) | 2001-03-23 | 2006-04-11 | University Of Pennsylvania | Aqueous room temperature living radical polymerization of vinyl halides |
| US7345127B2 (en) | 2001-03-23 | 2008-03-18 | University Of Pennsylvania | Living radical polymerization of halogen-containing and acrylic monomers and the formation of block copolymers therefrom |
| WO2019180734A1 (en) * | 2018-03-20 | 2019-09-26 | Hindustan Petroleum Corporation Limited | Hydrocarbon-soluble formulation for thermal cracking process |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2520028C3 (en) * | 1975-05-06 | 1987-07-30 | Chemische Fabrik Stockhausen GmbH, 4150 Krefeld | Liquid, pumpable, stable water-in-oil dispersions and their use |
-
0
- CA CA808724A patent/CA808724A/en not_active Expired
-
1966
- 1966-06-23 GB GB28234/66A patent/GB1078870A/en not_active Expired
- 1966-06-28 DE DE19661595513 patent/DE1595513A1/en active Pending
- 1966-06-29 NL NL6609073A patent/NL6609073A/xx unknown
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0021703A1 (en) * | 1979-06-11 | 1981-01-07 | Union Carbide Corporation | Radiation curable dispersions containing high molecular weight nonpolymerizable vinyl resins |
| FR2471988A1 (en) * | 1979-12-21 | 1981-06-26 | Dart Ind Inc | CATALYSTS AND PROCESS FOR THE PREPARATION OF POLYMERS AND COPOLYMERS OF ETHYLENICALLY UNSATURATED MONOMERS |
| WO2002059171A3 (en) * | 2001-01-26 | 2003-08-21 | Univ Pennsylvania | Living radical graft copolymerization of vinyl monomers initiated from the structural defects of polyvinylchloride |
| US6838535B2 (en) | 2001-03-23 | 2005-01-04 | University Of Pennsylvania | Process for the living radical polymerization of chlorine containing monomers |
| US7026420B2 (en) | 2001-03-23 | 2006-04-11 | University Of Pennsylvania | Aqueous room temperature living radical polymerization of vinyl halides |
| US7345127B2 (en) | 2001-03-23 | 2008-03-18 | University Of Pennsylvania | Living radical polymerization of halogen-containing and acrylic monomers and the formation of block copolymers therefrom |
| US7470762B2 (en) | 2001-03-23 | 2008-12-30 | University Of Pennsylvania | Living radical polymerization of acrylic monomers and the formation of block copolymers therefrom |
| WO2019180734A1 (en) * | 2018-03-20 | 2019-09-26 | Hindustan Petroleum Corporation Limited | Hydrocarbon-soluble formulation for thermal cracking process |
Also Published As
| Publication number | Publication date |
|---|---|
| NL6609073A (en) | 1968-01-02 |
| DE1595513A1 (en) | 1970-04-30 |
| CA808724A (en) | 1969-03-18 |
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