GB1066667A - Preparation of random copolymers - Google Patents
Preparation of random copolymersInfo
- Publication number
- GB1066667A GB1066667A GB2013965A GB2013965A GB1066667A GB 1066667 A GB1066667 A GB 1066667A GB 2013965 A GB2013965 A GB 2013965A GB 2013965 A GB2013965 A GB 2013965A GB 1066667 A GB1066667 A GB 1066667A
- Authority
- GB
- United Kingdom
- Prior art keywords
- tert
- poly
- formula
- organo
- butadiene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920005604 random copolymer Polymers 0.000 title abstract 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 abstract 4
- 229920000570 polyether Polymers 0.000 abstract 3
- 238000006116 polymerization reaction Methods 0.000 abstract 3
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 abstract 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract 2
- 125000004432 carbon atom Chemical group C* 0.000 abstract 2
- VKYKSIONXSXAKP-UHFFFAOYSA-N hexamethylenetetramine Chemical compound C1N(C2)CN3CN1CN2C3 VKYKSIONXSXAKP-UHFFFAOYSA-N 0.000 abstract 2
- 229910052739 hydrogen Inorganic materials 0.000 abstract 2
- 239000000463 material Substances 0.000 abstract 2
- 125000001979 organolithium group Chemical group 0.000 abstract 2
- PMJHHCWVYXUKFD-SNAWJCMRSA-N (E)-1,3-pentadiene Chemical group C\C=C\C=C PMJHHCWVYXUKFD-SNAWJCMRSA-N 0.000 abstract 1
- 239000004215 Carbon black (E152) Substances 0.000 abstract 1
- 239000004721 Polyphenylene oxide Substances 0.000 abstract 1
- 125000001931 aliphatic group Chemical group 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 abstract 1
- 125000004429 atom Chemical group 0.000 abstract 1
- 238000009835 boiling Methods 0.000 abstract 1
- 229910052799 carbon Inorganic materials 0.000 abstract 1
- 229920001577 copolymer Polymers 0.000 abstract 1
- 239000003085 diluting agent Substances 0.000 abstract 1
- 150000002170 ethers Chemical class 0.000 abstract 1
- 235000010299 hexamethylene tetramine Nutrition 0.000 abstract 1
- 239000004312 hexamethylene tetramine Substances 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 150000002430 hydrocarbons Chemical class 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 1
- 239000003999 initiator Substances 0.000 abstract 1
- 229960004011 methenamine Drugs 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 239000000178 monomer Substances 0.000 abstract 1
- PMJHHCWVYXUKFD-UHFFFAOYSA-N piperylene Natural products CC=CC=C PMJHHCWVYXUKFD-UHFFFAOYSA-N 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 239000003505 polymerization initiator Substances 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
Abstract
Random copolymers are obtained by contacting at least two monomeric materials selected from 1,3-butadiene, isoprene, piperylene and vinyl-substituted aromatic hydrocarbons with an organo-lithium polymerization initiator under polymerization conditions in a hydrocarbon diluent and in the presence of a polyether or a poly-tert-amine having at least 3 atoms other than C or H, a molecular weight of at least 130 and a boiling point of at least 150 DEG C. The organo-lithium initiator preferably has the formula RLix, where R is an aliphatic, cycloaliphatic or aromatic hydrocarbon radical having 1 to 20 carbon atoms and x is an integer from 1 to 4. The preferred polyethers have the formula <FORM:1066667/C3/1> and the preferred poly-tert-amines have the formula <FORM:1066667/C3/2> wherein each R is an alkyl group having 1 to 4 carbon atoms, each R1 is hydrogen or methyl and n is an integer of 2 to 6. Many other polyethers and poly-tert-amines are mentioned including polymers of ethers and oxides, and hexamethylene tetramine. An embodiment is illustrated in which after short-stopping a batch polymerization reaction, the polymerization mixture is passed into a flash separator and a portion of the solvent is flashed overhead together with any monomer that remains. This portion may be condensed and re-used. The material remaining in the separator is then treated by conventional processes to recover the rubbery copolymer. In the examples, styrene is copolyerized with 1,3-butadiene.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US37336464A | 1964-06-08 | 1964-06-08 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1066667A true GB1066667A (en) | 1967-04-26 |
Family
ID=23472107
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB2013965A Expired GB1066667A (en) | 1964-06-08 | 1965-05-12 | Preparation of random copolymers |
Country Status (4)
| Country | Link |
|---|---|
| JP (1) | JPS4841038B1 (en) |
| BE (1) | BE663879A (en) |
| ES (1) | ES313668A1 (en) |
| GB (1) | GB1066667A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5336737A (en) * | 1989-08-16 | 1994-08-09 | Shell Oil Company | Process for the preparation of random copolymers of conjugated dienes and vinyl aromatic compounds |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS54154644U (en) * | 1978-04-19 | 1979-10-27 | ||
| JPS60224816A (en) * | 1984-04-20 | 1985-11-09 | Nikkiso Co Ltd | Gas-phase production of carbon fiber |
-
1965
- 1965-05-12 GB GB2013965A patent/GB1066667A/en not_active Expired
- 1965-05-13 BE BE663879D patent/BE663879A/xx unknown
- 1965-05-31 JP JP3174265A patent/JPS4841038B1/ja active Pending
- 1965-06-01 ES ES0313668A patent/ES313668A1/en not_active Expired
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5336737A (en) * | 1989-08-16 | 1994-08-09 | Shell Oil Company | Process for the preparation of random copolymers of conjugated dienes and vinyl aromatic compounds |
Also Published As
| Publication number | Publication date |
|---|---|
| ES313668A1 (en) | 1966-02-16 |
| JPS4841038B1 (en) | 1973-12-04 |
| BE663879A (en) | 1965-11-16 |
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