GB1065418A - Improvements in or relating to stiffener material - Google Patents
Improvements in or relating to stiffener materialInfo
- Publication number
- GB1065418A GB1065418A GB1964364A GB1964364A GB1065418A GB 1065418 A GB1065418 A GB 1065418A GB 1964364 A GB1964364 A GB 1964364A GB 1964364 A GB1964364 A GB 1964364A GB 1065418 A GB1065418 A GB 1065418A
- Authority
- GB
- United Kingdom
- Prior art keywords
- fibres
- layer
- sheet
- particles
- copolymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000463 material Substances 0.000 title abstract 5
- 239000003351 stiffener Substances 0.000 title 1
- 239000004744 fabric Substances 0.000 abstract 13
- 239000002245 particle Substances 0.000 abstract 12
- 229920001577 copolymer Polymers 0.000 abstract 11
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract 6
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 abstract 6
- 239000011230 binding agent Substances 0.000 abstract 6
- 229920000642 polymer Polymers 0.000 abstract 6
- 229920000742 Cotton Polymers 0.000 abstract 5
- 239000000853 adhesive Substances 0.000 abstract 5
- 230000001070 adhesive effect Effects 0.000 abstract 5
- 239000002131 composite material Substances 0.000 abstract 5
- 239000006185 dispersion Substances 0.000 abstract 5
- 239000000057 synthetic resin Substances 0.000 abstract 5
- 229920003002 synthetic resin Polymers 0.000 abstract 5
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 abstract 4
- 239000002655 kraft paper Substances 0.000 abstract 4
- 239000000203 mixture Substances 0.000 abstract 4
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 abstract 4
- 229920001169 thermoplastic Polymers 0.000 abstract 4
- 239000004416 thermosoftening plastic Substances 0.000 abstract 4
- 229920000126 latex Polymers 0.000 abstract 3
- 229920005989 resin Polymers 0.000 abstract 3
- 239000011347 resin Substances 0.000 abstract 3
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 abstract 2
- IRIAEXORFWYRCZ-UHFFFAOYSA-N Butylbenzyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCC1=CC=CC=C1 IRIAEXORFWYRCZ-UHFFFAOYSA-N 0.000 abstract 2
- 244000025254 Cannabis sativa Species 0.000 abstract 2
- 235000012766 Cannabis sativa ssp. sativa var. sativa Nutrition 0.000 abstract 2
- 235000012765 Cannabis sativa ssp. sativa var. spontanea Nutrition 0.000 abstract 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 2
- 239000005977 Ethylene Substances 0.000 abstract 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 abstract 2
- 239000004677 Nylon Substances 0.000 abstract 2
- 239000004793 Polystyrene Substances 0.000 abstract 2
- 125000005250 alkyl acrylate group Chemical group 0.000 abstract 2
- 239000010425 asbestos Substances 0.000 abstract 2
- 235000009120 camo Nutrition 0.000 abstract 2
- 235000005607 chanvre indien Nutrition 0.000 abstract 2
- 239000000839 emulsion Substances 0.000 abstract 2
- 210000004209 hair Anatomy 0.000 abstract 2
- 239000011487 hemp Substances 0.000 abstract 2
- 238000005470 impregnation Methods 0.000 abstract 2
- 239000010985 leather Substances 0.000 abstract 2
- 150000002734 metacrylic acid derivatives Chemical class 0.000 abstract 2
- 229920001778 nylon Polymers 0.000 abstract 2
- 229920002223 polystyrene Polymers 0.000 abstract 2
- 230000003014 reinforcing effect Effects 0.000 abstract 2
- 229910052895 riebeckite Inorganic materials 0.000 abstract 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 abstract 2
- 239000012815 thermoplastic material Substances 0.000 abstract 2
- 210000002268 wool Anatomy 0.000 abstract 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 abstract 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 abstract 1
- 239000013032 Hydrocarbon resin Substances 0.000 abstract 1
- 239000004952 Polyamide Substances 0.000 abstract 1
- 239000004698 Polyethylene Substances 0.000 abstract 1
- 229920000297 Rayon Polymers 0.000 abstract 1
- 230000001464 adherent effect Effects 0.000 abstract 1
- 239000011324 bead Substances 0.000 abstract 1
- 239000008199 coating composition Substances 0.000 abstract 1
- 239000000835 fiber Substances 0.000 abstract 1
- 238000007757 hot melt coating Methods 0.000 abstract 1
- 229920006270 hydrocarbon resin Polymers 0.000 abstract 1
- 239000004816 latex Substances 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 abstract 1
- 239000003208 petroleum Substances 0.000 abstract 1
- 229920002647 polyamide Polymers 0.000 abstract 1
- 229920000728 polyester Polymers 0.000 abstract 1
- 229920006149 polyester-amide block copolymer Polymers 0.000 abstract 1
- -1 polyethylene Polymers 0.000 abstract 1
- 229920000573 polyethylene Polymers 0.000 abstract 1
- 239000002964 rayon Substances 0.000 abstract 1
- 229920002554 vinyl polymer Polymers 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
- B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
- B29C70/06—Fibrous reinforcements only
- B29C70/10—Fibrous reinforcements only characterised by the structure of fibrous reinforcements, e.g. hollow fibres
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B23/00—Uppers; Boot legs; Stiffeners; Other single parts of footwear
- A43B23/08—Heel stiffeners; Toe stiffeners
- A43B23/16—Heel stiffeners; Toe stiffeners made of impregnated fabrics, plastics or the like
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N7/00—Flexible sheet materials not otherwise provided for, e.g. textile threads, filaments, yarns or tow, glued on macromolecular material
- D06N7/0005—Floor covering on textile basis comprising a fibrous substrate being coated with at least one layer of a polymer on the top surface
- D06N7/0039—Floor covering on textile basis comprising a fibrous substrate being coated with at least one layer of a polymer on the top surface characterised by the physical or chemical aspects of the layers
- D06N7/0052—Compounding ingredients, e.g. rigid elements
- D06N7/0055—Particulate material such as cork, rubber particles, reclaimed resin particles, magnetic particles, metal particles, glass beads
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2201/00—Chemical constitution of the fibres, threads or yarns
- D06N2201/02—Synthetic macromolecular fibres
- D06N2201/0263—Polyamide fibres
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2201/00—Chemical constitution of the fibres, threads or yarns
- D06N2201/04—Vegetal fibres
- D06N2201/042—Cellulose fibres, e.g. cotton
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2211/00—Specially adapted uses
- D06N2211/10—Clothing
- D06N2211/106—Footwear
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Composite Materials (AREA)
- Mechanical Engineering (AREA)
- Textile Engineering (AREA)
- Laminated Bodies (AREA)
Abstract
Sheet material from which blanks suitable for use in stiffening end portions of shoe uppers can be cut out comprises a water-laid layer of heat-fusible synthetic resin particles and fibres the ratio of particles to fibres being 0.5-5:1 by weight, the layer having on at least one side thereof a layer of thermoplastic adhesive fusible at temperatures which soften the particles. The fibres may be cellulosic and may include cotton, nylon, hemp, hair, wool, leather, asbestos, kraft or sulphite pulp fibres. The heat-fusible synthetic resin particles may be any polymer or copolymer of syrene, vinyl toluene, vinyl acetate, and the C1-4 alkyl acrylates and methacrylates. A fibrous fabric sheet may be provided on one side of the water-laidlayer. This composite sheet may be impregnated from the reinforcing fabric side with an aqueous dispersion of a binder. The latter be a thermoplastic material. Specified binder compositions are latices of styrene polymers and copolymers and polymers of C1-4 alkyl acrylates. After impregnation the sheet is dried, and the adhesive material is applied. The water-laid layer may be formed by straining papermaking furnish containing dispersed thermoplastic particles through a fibrous fabric sheet. Such a sheet may be held to the water-laid fibrous layer deposited from the furnish by an interspersion and entanglement of the fibres of the layer with the fibres of the fabric. In an example, an aqueous dispersion of kraft fibres and beads of a copolymer of vinyl toluene and ethyl hexyl acrylate was introduced into the flow box of a cylinder-type papermaking machine, on the screen of which was laid a woven cotton cloth. The dispersion was applied to the cloth on the cylinder screen to form a layer of fibre and resin particles, which after being passed through rolls to squeeze water from it, was adherent to the cloth. The composite sheet was dried and impregnated with a binder liquid consisting of an aqueous dispersion of acrylate modified polystyrene latex and butyl benzyl phthalate. The impregnated sheet was dried, rolled, and coated on both sides with a resin emulsion comprising a copolymer of vinyl acetate and a C6 or higher alkyl acrylate.ALSO:Sheet material from which blanks suitable for use in stiffening end portions of shoe uppers can be cut out comprises a water-laid layer of heat-fusible synthetic resin particles and fibres, the ratio of particles to fibres being 0.5-5:1 by weight, the layer having on at least one side thereof a layer of thermoplastic adhesive fusible at temperatures which soften the particles. The fibres may comprise cellulosic fibres and may include cotton, nylon, hemp, hair, wool, leather, asbestos, kraft or sulphite pulp fibres. The heat-fusible synthetic resin particles may be any polymer or copolymer of styrene, vinyltoluene, vinyl acetate, and the C1-4 alkyl acrylates and methacrylates. The thermoplastic adhesive may be polyvinyl actetate, a polyamide, a polyester, a polyester amide resin, polyethylene, a copolymer of ethylene with vinyl acetate and methyl acrylate or ethyl acrylate, or a mixture thereof. A fibrous fabric sheet may be provided on one side of the layer of heat-fusible synthetic resin particles and fibres. The fabric may be open woven or non-woven fibrous fabric. It may be made of cotton or rayon. The composite sheet of water-laid layer and fibrous fabric sheet may be impregnated from the reinforcing fabric side with an aqueous dispersion of a binder, which may be a thermoplastic material. Specified binder compositions are latices of styrene polymers and copolymers and polymers of C1-4 alkyl acrylates. After impregnation, the sheet is dried, and the adhesive material is applied. In examples, a water-laid layer of kraft fibres and particles of a co-polymer of vinyl toluene and ethyl hexyl acrylate are held on a woven cotton cloth, the composite being impregnated with a binder composition comprising acrylate-modified polystyrene and coated on both sides with an emulsion comprising a copolymer of vinyl acetate and C6 or higher alkyl acrylate. Alternatively, the composite is impregnated with a butadiene-styrene copolymer and coated on both sides with a hot melt coating composition comprising a copolymer of ethylene and vinyl acetate, petroleum refinery wax, and a hydrocarbon resin.
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US77652558A | 1958-11-26 | 1958-11-26 | |
| US81719159 US3021240A (en) | 1959-06-01 | 1959-06-01 | Flocked solvent activatable stiffener sheet material |
| US84755059 US3102836A (en) | 1959-10-20 | 1959-10-20 | Sheet material comprising fibers and plastic particles |
| US28023563A | 1963-05-14 | 1963-05-14 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1065418A true GB1065418A (en) | 1967-04-12 |
Family
ID=27501271
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB1964364A Expired GB1065418A (en) | 1958-11-26 | 1964-05-12 | Improvements in or relating to stiffener material |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB1065418A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2127863A (en) * | 1982-09-30 | 1984-04-18 | Vortex Ind Prod | Cohesive fibrous material and method of forming same |
| US6391380B1 (en) * | 2000-08-03 | 2002-05-21 | Stanbee Company, Inc. | Stiffener material with self adhesive properties |
| US7528080B2 (en) | 2005-12-15 | 2009-05-05 | Dow Global Technologies, Inc. | Aqueous polyolefin dispersions for textile impregnation |
-
1964
- 1964-05-12 GB GB1964364A patent/GB1065418A/en not_active Expired
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2127863A (en) * | 1982-09-30 | 1984-04-18 | Vortex Ind Prod | Cohesive fibrous material and method of forming same |
| US6391380B1 (en) * | 2000-08-03 | 2002-05-21 | Stanbee Company, Inc. | Stiffener material with self adhesive properties |
| US6475619B2 (en) | 2000-08-03 | 2002-11-05 | Stanbee Company, Inc. | Stiffener material with self adhesive properties |
| US7528080B2 (en) | 2005-12-15 | 2009-05-05 | Dow Global Technologies, Inc. | Aqueous polyolefin dispersions for textile impregnation |
| US7998531B2 (en) | 2005-12-15 | 2011-08-16 | Dow Global Technologies Llc | Aqueous polyolefin dispersions for textile impregnation |
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