GB1064160A - Quaternization process - Google Patents
Quaternization processInfo
- Publication number
- GB1064160A GB1064160A GB977466A GB977466A GB1064160A GB 1064160 A GB1064160 A GB 1064160A GB 977466 A GB977466 A GB 977466A GB 977466 A GB977466 A GB 977466A GB 1064160 A GB1064160 A GB 1064160A
- Authority
- GB
- United Kingdom
- Prior art keywords
- chloride
- amine groups
- polyamine
- quaternized
- reaction
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000034 method Methods 0.000 title 1
- 238000005956 quaternization reaction Methods 0.000 title 1
- 229920000768 polyamine Polymers 0.000 abstract 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 abstract 2
- 125000003277 amino group Chemical group 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- 125000002924 primary amino group Chemical class [H]N([H])* 0.000 abstract 2
- 125000000467 secondary amino group Chemical group [H]N([*:1])[*:2] 0.000 abstract 2
- VFWCMGCRMGJXDK-UHFFFAOYSA-N 1-chlorobutane Chemical compound CCCCCl VFWCMGCRMGJXDK-UHFFFAOYSA-N 0.000 abstract 1
- ISXDOPCKEDRLAY-UHFFFAOYSA-N 1-chlorotridecylbenzene Chemical compound CCCCCCCCCCCCC(Cl)C1=CC=CC=C1 ISXDOPCKEDRLAY-UHFFFAOYSA-N 0.000 abstract 1
- SZIFAVKTNFCBPC-UHFFFAOYSA-N 2-chloroethanol Chemical compound OCCCl SZIFAVKTNFCBPC-UHFFFAOYSA-N 0.000 abstract 1
- OSDWBNJEKMUWAV-UHFFFAOYSA-N Allyl chloride Chemical compound ClCC=C OSDWBNJEKMUWAV-UHFFFAOYSA-N 0.000 abstract 1
- ZNSMNVMLTJELDZ-UHFFFAOYSA-N Bis(2-chloroethyl)ether Chemical compound ClCCOCCCl ZNSMNVMLTJELDZ-UHFFFAOYSA-N 0.000 abstract 1
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 abstract 1
- 125000002947 alkylene group Chemical group 0.000 abstract 1
- 150000001412 amines Chemical class 0.000 abstract 1
- 229910021529 ammonia Inorganic materials 0.000 abstract 1
- KCXMKQUNVWSEMD-UHFFFAOYSA-N benzyl chloride Chemical compound ClCC1=CC=CC=C1 KCXMKQUNVWSEMD-UHFFFAOYSA-N 0.000 abstract 1
- 229940073608 benzyl chloride Drugs 0.000 abstract 1
- VEZXCJBBBCKRPI-UHFFFAOYSA-N beta-propiolactone Chemical compound O=C1CCO1 VEZXCJBBBCKRPI-UHFFFAOYSA-N 0.000 abstract 1
- NEHMKBQYUWJMIP-NJFSPNSNSA-N chloro(114C)methane Chemical compound [14CH3]Cl NEHMKBQYUWJMIP-NJFSPNSNSA-N 0.000 abstract 1
- HRYZWHHZPQKTII-UHFFFAOYSA-N chloroethane Chemical compound CCCl HRYZWHHZPQKTII-UHFFFAOYSA-N 0.000 abstract 1
- VAYGXNSJCAHWJZ-UHFFFAOYSA-N dimethyl sulfate Chemical compound COS(=O)(=O)OC VAYGXNSJCAHWJZ-UHFFFAOYSA-N 0.000 abstract 1
- 229960003750 ethyl chloride Drugs 0.000 abstract 1
- SNMVRZFUUCLYTO-UHFFFAOYSA-N n-propyl chloride Chemical compound CCCCl SNMVRZFUUCLYTO-UHFFFAOYSA-N 0.000 abstract 1
- -1 polyoxyethylene chloride Polymers 0.000 abstract 1
- 125000001302 tertiary amino group Chemical group 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
- C08G73/02—Polyamines
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
- Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
Abstract
Polymeric polyamines are quaternized by reaction with a quaternizing agent at a temperature from room temperature to 90 DEG C. while maintaining the pH of the reaction at 7.5 to 9.0. If the polyamine contains primary and/or secondary amine groups these are reacted first to substitute fully the amine groups, preferably in the above temperature range and at a pH of 7.5 to 12, and then the polyamine is quaternized as above; the same compound may be used to convert the primary and secondary amine groups to tertiary amine groups as is used to form the final quaternary product. The polyamine may have a molecular weight from 300 to 50,000 and may be obtained by reacting alkylene dihalides with ammonia or amines. The compounds used to substitute the amine groups and to quaternize the polyamines may be methyl chloride, dimethyl sulphate, ethyl chloride, propyl chloride, benzyl chloride, dodecyl benzyl chloride, epichlorohydrin, dichloroethylether, allyl chloride, n-butyl chloride, 2-chloroethanol, b -propiolactone and polyoxyethylene chloride. An example is given.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US44484365A | 1965-04-01 | 1965-04-01 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1064160A true GB1064160A (en) | 1967-04-05 |
Family
ID=23766583
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB977466A Expired GB1064160A (en) | 1965-04-01 | 1966-03-07 | Quaternization process |
Country Status (3)
| Country | Link |
|---|---|
| DE (1) | DE1645067A1 (en) |
| ES (1) | ES324974A1 (en) |
| GB (1) | GB1064160A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4071478A (en) * | 1976-06-07 | 1978-01-31 | Merck & Co., Inc. | Controlled partially cross-linked 3,3-ionenes |
-
1966
- 1966-03-07 GB GB977466A patent/GB1064160A/en not_active Expired
- 1966-03-16 DE DE19661645067 patent/DE1645067A1/en active Pending
- 1966-03-31 ES ES0324974A patent/ES324974A1/en not_active Expired
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4071478A (en) * | 1976-06-07 | 1978-01-31 | Merck & Co., Inc. | Controlled partially cross-linked 3,3-ionenes |
Also Published As
| Publication number | Publication date |
|---|---|
| ES324974A1 (en) | 1967-02-16 |
| DE1645067A1 (en) | 1970-10-22 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| KR850001159A (en) | Method for preparing quaternary amine carbamate or urea compound based on isopropenyl-α, α-dimethylbenzyl isocyanate | |
| GB1066488A (en) | A process for the production of elastic synthetic polyurethanes | |
| GB1088625A (en) | Improvements in or relating to a process for making a cationic thermosetting resin | |
| GB1521047A (en) | Microbiocidal agents | |
| DE3064043D1 (en) | Use of nitrogen containing condensation products as retention agent, flocculating agent and drainage accelerator in paper production | |
| MX9206289A (en) | CATIONIC POLYURETHANE COMPOSITIONS, QUATERNARY MONIUM SALTS AND METHODS FOR ITS PREPARATION. | |
| NL181203C (en) | PROCESS FOR THE PREPARATION OF NITROGEN CONTAINING CONDENSATION PRODUCTS FOR USE AS A RETENTION AND FLOCKING AGENT. | |
| DE3262451D1 (en) | Process for the treatment of wood and wooden materials with aqueous treatment agents | |
| JPS57181044A (en) | Manufacture of quaternary ammonium compound, spun textile softening and antistatic method and fungous repulsion | |
| FI811186L (en) | FOERFARANDE FOER FRAMSTAELLNING AV KVARTAERISKA AMMONIUMFOERENINGAR INNEHAOLLANDE EN HALOHYDRINGRUPP | |
| EP0095156A3 (en) | Process for preparing quaternary ammonium-functional silicon compounds, products prepared thereof and use of the same | |
| GB1064160A (en) | Quaternization process | |
| SE7611127L (en) | METHOD OF PRODUCING CATHINGIC ADHESIVE FOR PAPER | |
| SE8403075L (en) | POLYAMIDOAMINPOLYAMINER | |
| KR900006439A (en) | Coating composition | |
| GB1096964A (en) | Water-soluble polymers and process for preparing same | |
| GB1525286A (en) | Polymers and their use in antistatic coating of photographic elements | |
| GB1118594A (en) | Quaternary amines | |
| DE3365113D1 (en) | Process for preparing quaternary ammonium-functional silicon compounds, products prepared thereof and use of the same | |
| GB892413A (en) | Poly-onium neuromuscular blocking agents | |
| ATE3048T1 (en) | LATENT HARDENER FOR AMINOPLASTIC RESINS, PROCESS FOR ITS PRODUCTION AND THE AMINOPLASTIC RESINS CONTAINING THE HARDENER. | |
| GB833008A (en) | Improvements in and relating to diquaternary compounds | |
| GB1150278A (en) | Improvements in or relating to Quaternary Ammonium Compounds | |
| GB953496A (en) | Novel quaternary ammonium compounds and liquid cationic textile softener compositions containing them | |
| GB1044306A (en) | Process for preparing hardenable aminoplasts |